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Benzene, 1,3,5-trichloro-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil481.2KN/AAldrich Chemical Company Inc., 1990BS
Quantity Value Units Method Reference Comment
Tfus334.45KN/ADonnelly, Drewes, et al., 1990Uncertainty assigned by TRC = 0.2 K; TRC
Tfus336.3KN/AMiller, Ghodbane, et al., 1984Uncertainty assigned by TRC = 0.2 K; TRC
Tfus336.7KN/APlato and Glasgow, 1969Uncertainty assigned by TRC = 0.1 K; TRC
Tfus336.2KN/ADiepen and Scheffer, 1948Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Deltavap59.kJ/molGCSpieksma, Luijk, et al., 1994Based on data from 413. - 453. K.; AC
Quantity Value Units Method Reference Comment
Deltasub72.7 ± 0.5kJ/molCYan, Gu, et al., 1987ALS
Deltasub54.02kJ/molEPlatonov and Simulin, 1985ALS
Deltasub72.7 ± 0.5kJ/molN/AYan, Gu, et al., 1985See also Yan, Gu, et al., 1987, 2.; AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
50.3 ± 0.1375.DMBlok, van Genderen, et al., 2001Based on data from 338. - 415. K.; AC
51.7337.N/ARohác, Ruzicka, et al., 1999AC
48.8351.AStephenson and Malanowski, 1987Based on data from 336. - 482. K. See also Stull, 1947.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
336.9 - 481.64.607092067.313-32.267Stull, 1947Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
56.5291.RGSears and Hopke, 1949Based on data from 282. - 301. K. See also Jones, 1960.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
17.56335.9van der Linde, van Miltenburg, et al., 2005AC
18.2336.7Acree, 1991AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Donnelly, Drewes, et al., 1990
Donnelly, J.R.; Drewes, L.A.; Johnson, R.L.; Munslow, W.D.; Knapp, K.K.; Sovocool, G.W., Purity and heat of fusion data for environmental standards as determined by differential scanning calorimetry, Thermochim. Acta, 1990, 167, 2, 155, https://doi.org/10.1016/0040-6031(90)80476-F . [all data]

Miller, Ghodbane, et al., 1984
Miller, M.M.; Ghodbane, S.; Wasik, S.P.; Tewari, Y.B.; Martire, D.E., Aqueous Solubilities, Octanol/Water Partition Coefficients, and Entropies of Melting of Chlorinated Benzenes and Biphenyls, J. Chem. Eng. Data, 1984, 29, 184-190. [all data]

Plato and Glasgow, 1969
Plato, C.; Glasgow, A.R., Jr., Differential scanning calorimetry as a general method for determining the purity and heat of fusion of high-purity organic chemicals. Application to 95 compounds, Anal. Chem., 1969, 41, 2, 330, https://doi.org/10.1021/ac60271a041 . [all data]

Diepen and Scheffer, 1948
Diepen, G.A.M.; Scheffer, F.E.C., On Critical Phenomena of Saturated Solutions in Binary Systems, J. Am. Chem. Soc., 1948, 70, 4081. [all data]

Spieksma, Luijk, et al., 1994
Spieksma, Walter; Luijk, Ronald; Govers, Harrie A.J., Determination of the liquid vapour pressure of low-volatility compounds from the Kováts retention index, Journal of Chromatography A, 1994, 672, 1-2, 141-148, https://doi.org/10.1016/0021-9673(94)80602-0 . [all data]

Yan, Gu, et al., 1987
Yan, H.; Gu, J.; An, X.; Hu, R., Standard enthalpies of formation and enthlpies of isomerization of trichlorobenzenes, Huaxue Xuebao, 1987, 45, 1184-1187. [all data]

Platonov and Simulin, 1985
Platonov, V.A.; Simulin, Yu.N., Determination of the standard enthalpies of formation of polychlorobenzenes. III. The standard enthalpies of formation of mono-1,2,4- and 1,3,5-tri-, and 1,2,3,4- and 1,2,3,5-tetrachlorobenzenes, Russ. J. Phys. Chem. (Engl. Transl.), 1985, 59, 179-181. [all data]

Yan, Gu, et al., 1985
Yan, Haike; Gu, Jiangou; Hu, Rihen, Sublimation Calorimeter and the Measurement of Enthalpies of Vaporization and Sublimation of Trichlorobenzenes, Acta Phys. Chim. Sin., 1985, 1, 6, 543-546, https://doi.org/10.3866/PKU.WHXB19850607 . [all data]

Yan, Gu, et al., 1987, 2
Yan, H.; Gu, J.; An, X.; Hu, R.-H., Huaxue Xuebao, 1987, 45, 1184. [all data]

Blok, van Genderen, et al., 2001
Blok, Jacobus G.; van Genderen, Aad C.G.; van der Linde, Peter R.; Oonk, Harry A.J., Vapour pressures of crystalline 1,2,4,5-tetrachlorobenzene, and crystalline and liquid 1,3,5-trichlorobenzene and 1,2,4,5-tetramethylbenzene, The Journal of Chemical Thermodynamics, 2001, 33, 9, 1097-1106, https://doi.org/10.1006/jcht.2000.0819 . [all data]

Rohác, Ruzicka, et al., 1999
Rohác, Vladislav; Ruzicka, Vlastimil; Ruzicka, Kvetoslav; Polednicek, Milos; Aim, Karel; Jose, Jacques; Zábranský, Milan, Recommended vapour and sublimation pressures and related thermal data for chlorobenzenes, Fluid Phase Equilibria, 1999, 157, 1, 121-142, https://doi.org/10.1016/S0378-3812(99)00003-5 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Sears and Hopke, 1949
Sears, G.W.; Hopke, E.R., Vapor Pressures of the Isomeric Trichlorobenzenes in the Low Pressure Region, J. Am. Chem. Soc., 1949, 71, 7, 2575-2576, https://doi.org/10.1021/ja01175a094 . [all data]

Jones, 1960
Jones, A.H., Sublimation Pressure Data for Organic Compounds., J. Chem. Eng. Data, 1960, 5, 2, 196-200, https://doi.org/10.1021/je60006a019 . [all data]

van der Linde, van Miltenburg, et al., 2005
van der Linde, Peter R.; van Miltenburg, J. Cees; van den Berg, Gerrit J.K.; Oonk, Harry A.J., Low-Temperature Heat Capacities and Derived Thermodynamic Functions of 1,4-Dichlorobenzene, 1,4-Dibromobenzene, 1,3,5-Trichlorobenzene, and 1,3,5-Tribromobenzene, J. Chem. Eng. Data, 2005, 50, 1, 164-172, https://doi.org/10.1021/je049762q . [all data]

Acree, 1991
Acree, William E., Thermodynamic properties of organic compounds: enthalpy of fusion and melting point temperature compilation, Thermochimica Acta, 1991, 189, 1, 37-56, https://doi.org/10.1016/0040-6031(91)87098-H . [all data]


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