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Resorcinol

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid-370.7 ± 1.1kJ/molCcrSabbah and Buluku, 1991«DELTA»Hfusion =15.25±0.52 kJ/mol; ALS
Deltafsolid-368.0 ± 0.50kJ/molCcbDesai, Wilhoit, et al., 1968crystal phase; ALS
Deltafsolid-351.2kJ/molCcbPushin, 1954Author's hf298_condensed=-85.6 kcal/mol; ALS
Quantity Value Units Method Reference Comment
Deltacsolid-2847.9 ± 1.1kJ/molCcrSabbah and Buluku, 1991«DELTA»Hfusion =15.25±0.52 kJ/mol; Corresponding «DELTA»fsolid = -370.7 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-2850.6 ± 0.42kJ/molCcbDesai, Wilhoit, et al., 1968crystal phase; Corresponding «DELTA»fsolid = -368.0 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-2867.kJ/molCcbPushin, 1954Author's hf298_condensed=-85.6 kcal/mol; Corresponding «DELTA»fsolid = -351. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-2861.kJ/molCcbBarker, 1925Author was aware that data differs from previously reported values; Corresponding «DELTA»fsolid = -357. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
135.53298.15Bret-Dibat and Lichanot, 1989T = 200 to 500 K. Cp(c) = 126.876 + 0.3316t + 5.6228x10-4t2 + 9.5321x10-6t3 J/mol*K (t/°C). Cp value caluclated from equation.; DH
139.3298.15Ueberreiter and Orthmann, 1950T = 293 to 368 K. Equation only.; DH
151.0323.Satoh and Sogabe, 1941T = 0 to 100°C. Mean value.; DH
131.0298.Andrews, Lynn, et al., 1926T = 22 to 200°C.; DH
131.4297.9Andrews, 1926T = 110 to 344 K. Value is unsmoothed experimental datum.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sabbah and Buluku, 1991
Sabbah, R.; Buluku, E.N.L.E., Thermodynamic study of three isomers of dihydroxybenzene, Can. J. Chem., 1991, 69, 481-488. [all data]

Desai, Wilhoit, et al., 1968
Desai, P.D.; Wilhoit, R.C.; Zwolinski, B.J., Heat of combustion of resorcinol and enthalpies of isomerization of dihydroxybenzenes, J. Chem. Eng. Data, 1968, 13, 334-335. [all data]

Pushin, 1954
Pushin, N.A., Heats of combustion and heats of formation of isomeric organic compounds, Bull. Soc. Chim. Belgrade, 1954, 19, 531-547. [all data]

Barker, 1925
Barker, M.F., Calorific value and constitution, J. Phys. Chem., 1925, 29, 1345-1363. [all data]

Bret-Dibat and Lichanot, 1989
Bret-Dibat, P.; Lichanot, A., Thermodynamic properties of positional isomers of disubstituted benzene in condensed phase, Thermochim. Acta, 1989, 147(2), 261-271. [all data]

Ueberreiter and Orthmann, 1950
Ueberreiter, K.; Orthmann, H.-J., Specifische Wärme, spezifisches Volumen, Temperatur- und Wärme-leittähigkeit einiger disubstituierter Benzole und polycyclischer Systeme, Z. Natursforsch. 5a, 1950, 101-108. [all data]

Satoh and Sogabe, 1941
Satoh, S.; Sogabe, T., The heat capacities of some organic compounds containing nitrogen and the atomic heat of nitrogen. (3), Sci., Pap. Inst. Phys. Chem. Res. (Tokyo), 1941, 38, 238-245. [all data]

Andrews, Lynn, et al., 1926
Andrews, D.H.; Lynn, G.; Johnston, J., The heat capacities and heat of crystallization of some isomeric aromatic compounds, J. Am. Chem. Soc., 1926, 48, 1274-1287. [all data]

Andrews, 1926
Andrews, D.H., The specific heats of some isomers of the type ortho, meta and para C6H4XY from 110 to 340K, J. Am. Chem. Soc., 1926, 48, 1287-1298. [all data]


Notes

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