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m-Chloroaniline

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil503.2KN/AWeast and Grasselli, 1989BS
Tboil503.15KN/APawlowski and Wieckowska, 1980Uncertainty assigned by TRC = 1.5 K; TRC
Tboil503.7KN/ASidgwick and Rubie, 1921Uncertainty assigned by TRC = 2. K; TRC
Tboil509.65KN/APerkin, 1896Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Tfus263.15KN/APawlowski and Wieckowska, 1980Uncertainty assigned by TRC = 0.5 K; TRC
Tfus262.9KN/ADreisbach, 1955Uncertainty assigned by TRC = 0.02 K; TRC
Tfus262.8KN/ASidgwick and Rubie, 1921Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Deltavap61.1 ± 2.8kJ/molCRibeiro da Silva, Gomes, et al., 2005AC
Deltavap60.2 ± 0.1kJ/molGSVerevkin and Schick, 2003Based on data from 291. - 340. K.; AC
Deltavap54.0 ± 0.2kJ/molVZalikin, Kochetkov, et al., 1965ALS

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
368.70.015Aldrich Chemical Company Inc., 1990BS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
53.6413.AStephenson and Malanowski, 1987Based on data from 398. - 573. K. See also Dykyj, 1972.; AC
60.3 ± 0.6319.TE,MEPiacente, Scardala, et al., 1985Based on data from 292. - 346. K.; AC
61.0 ± 0.8323.TE,MEPiacente, Scardala, et al., 1985Based on data from 304. - 342. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
334. - 398.0.71365296.999-257.467Zalikin, Kochetkov, et al., 1965Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
12.263.Khanna, Khetarpal, et al., 1983AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Pawlowski and Wieckowska, 1980
Pawlowski, W.; Wieckowska, E., Distribution Studies on Ternary System Water--Benzene--Chloro- or Nitroaniline, Pol. J. Chem., 1980, 54, 543. [all data]

Sidgwick and Rubie, 1921
Sidgwick, N.V.; Rubie, H.E., The solubility and volatility of the chloro- and nitro-anilines and of their acetyl derivatives, J. Chem. Soc., 1921, 119, 1013-24. [all data]

Perkin, 1896
Perkin, W.H., LXIX. On Magnetic Rotatory Power, especially of Aromatic Compounds, J. Chem. Soc., 1896, 69, 1025-1257. [all data]

Dreisbach, 1955
Dreisbach, R.R., Physical Properties of Chemical Compounds, Advances in Chemistry Series No. 15, Am. Chem. Soc.: Washington, D. C., 1955. [all data]

Ribeiro da Silva, Gomes, et al., 2005
Ribeiro da Silva, Manuel A.V.; Gomes, José R.B.; Ferreira, Ana I.M.C.L., Experimental and Computational Investigation of the Energetics of the Three Isomers of Monochloroaniline, J. Phys. Chem. B, 2005, 109, 27, 13356-13362, https://doi.org/10.1021/jp0519565 . [all data]

Verevkin and Schick, 2003
Verevkin, Sergey P.; Schick, Christoph, Determination of vapor pressures, enthalpies of sublimation, enthalpies of vaporization, and enthalpies of fusion of a series of chloro-aminobenzenes and chloro-nitrobenzenes, Fluid Phase Equilibria, 2003, 211, 2, 161-177, https://doi.org/10.1016/S0378-3812(03)00181-X . [all data]

Zalikin, Kochetkov, et al., 1965
Zalikin, A.A.; Kochetkov, V.L.; Strepikheev, Yu.A., Some physical and physicochemical constants of m- and p-chloroaniline and of m- and p-chlorophenyl isocyanate, Khim. Prom. (Moscow), 1965, 41, 338. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Dykyj, 1972
Dykyj, J., Petrochemia, 1972, 12, 1, 13. [all data]

Piacente, Scardala, et al., 1985
Piacente, V.; Scardala, P.; Ferro, D.; Gigli, R., Vaporization study of o-, m-, and p-chloroaniline by torsion-weighing effusion vapor pressure measurements, J. Chem. Eng. Data, 1985, 30, 4, 372-376, https://doi.org/10.1021/je00042a002 . [all data]

Khanna, Khetarpal, et al., 1983
Khanna, M.S.; Khetarpal, S.C.; Lal, K.; Bhatnagar, H.L., Thermodynamic studies on melting of some o-, m-, and p-halogen derivatives of aniline, Indian J. Pure Appl. Phys., 1983, 20, 6, 503. [all data]


Notes

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