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Propylene Carbonate

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-146.6 ± 0.3kcal/molCcbVasil'eva, Zhil'tosova, et al., 1972ALS
Deltafliquid-151.01 ± 0.50kcal/molCcbChoi and Joncich, 1971Pedley's value is off by 4.46kcal/mol; ALS
Quantity Value Units Method Reference Comment
Deltacliquid-434.6 ± 0.3kcal/molCcbVasil'eva, Zhil'tosova, et al., 1972Corresponding «DELTA»fliquid = -146.5 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-430.14 ± 0.50kcal/molCcbChoi and Joncich, 1971Pedley's value is off by 4.46kcal/mol; Corresponding «DELTA»fliquid = -151.01 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid52.25cal/mol*KN/AVasil'ev, Korkhov, et al., 1976DH
liquid52.383cal/mol*KN/AVasil'ev and Korkhov, 1974DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
41.8298.Masood, Pethrick, et al., 1976T = 200 to 325 K. Data graphically only. Value estimated from graph.; DH
40.01298.15Vasil'ev, Korkhov, et al., 1976T = 5 to 415 K.; DH
40.057298.15Vasil'ev and Korkhov, 1974T = 80 to 310 K. Cp(c) = 2.9899 + 91.0386(T/100) - 35.8262(T/100)2 + 7.2335(T/100)3 J/mol*K (55 to 224.5 K).; DH
44.00323.15Peppel, 1958DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Vasil'eva, Zhil'tosova, et al., 1972
Vasil'eva, T.F.; Zhil'tosova, E.N.; Vvedenski, A.A., Enthalpies of combustion of alkylene carbonates, Russ. J. Phys. Chem. (Engl. Transl.), 1972, 46, 316. [all data]

Choi and Joncich, 1971
Choi, J.K.; Joncich, M.J., Heats of combustion, heats of formation and vapor pressures of some organic carbonates. Estimation of carbonate group contribution to heat of formation, J. Chem. Eng. Data, 1971, 16, 87-90. [all data]

Vasil'ev, Korkhov, et al., 1976
Vasil'ev, I.A.; Korkhov, A.D.; Minkin, D.M.; Rabinovich, I.B.; Sheiman, M.S.; Nistratov, V.P., Heat capacity and thermodynamic functions for propylene carbonate. Termodin. Org. Soedin., 1976, 21-26. [all data]

Vasil'ev and Korkhov, 1974
Vasil'ev, I.A.; Korkhov, A.D., Thermodynamic properties of alkylene carbonates at low temperatures, Tr. Khim. Khim. Tekhnol., Gor'kii, 1974, 36, 103-105. [all data]

Masood, Pethrick, et al., 1976
Masood, A.K.M.; Pethrick, R.A.; Swinton, F.L., Physicochemical studies of super-cooled liquids. Cyclic carbonates and a-«beta»-unsaturated aldehydes, J. Chem. Soc. Faraday Trans. I, 1976, 72, 20-28. [all data]

Peppel, 1958
Peppel, W.J., Preparation and properties of the alkylene carbonates, Ind. Eng. Chem., 1958, 50, 767-770. [all data]


Notes

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