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Maleic anhydride

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil473.2KN/AAldrich Chemical Company Inc., 1990BS
Quantity Value Units Method Reference Comment
Tfus326.0 ± 0.9KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple325.72KN/ADe Wit, De Kruif, et al., 1983Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Deltasub17.kcal/molN/AVilcu, Perisanu, et al., 1978AC

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
11.7351.AStephenson and Malanowski, 1987Based on data from 336. - 475. K.; AC
13.1325.8VWinstrom and Kulp, 1949ALS
13.1326. - 350.N/AWinstrom and Kulp, 1949, 2AC
13.6332.N/AStull, 1947Based on data from 317. - 475. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
317. - 475.3.793451431.009-101.093Stull, 1947Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

DeltasubH (kcal/mol) Temperature (K) Method Reference Comment
20.4317.N/AStephenson and Malanowski, 1987Based on data from 308. - 326. K.; AC
16.4258.TE,MEDe Wit, Van Miltenburg, et al., 1983AC
17.1 ± 1.2308. - 325.N/AWinstrom and Kulp, 1949, 2See also Cox and Pilcher, 1970.; AC

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Reference Comment
3.2385325.72DeWit, DeKruif, et al., 1983DH
3.2620326.00Mastrangelo, 1957DH
3.2505325.3DeWit, Offringa, et al., 1983DH
2.930325.7Domalski and Hearing, 1996AC
3.0903325.Spengler and Tamplin, 1952DH
2.9302325.64Marchidan and Ciopec, 1978DH

Entropy of fusion

DeltafusS (cal/mol*K) Temperature (K) Reference Comment
9.94325.72DeWit, DeKruif, et al., 1983DH
9.99325.3DeWit, Offringa, et al., 1983DH
9.51325.Spengler and Tamplin, 1952DH
8.99325.64Marchidan and Ciopec, 1978DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

De Wit, De Kruif, et al., 1983
De Wit, H.G.M.; De Kruif, C.G.; Van Miltenburg, J.C., Thermodynamic properties of molecular organic crystals containing nitrogen, oxygen, and sulfur II. Molar heat capacities of eight compounds by adiabatic calorimetry, J. Chem. Thermodyn., 1983, 15, 9, 891, https://doi.org/10.1016/0021-9614(83)90095-2 . [all data]

Vilcu, Perisanu, et al., 1978
Vilcu, R.; Perisanu, S.; Ciocazanu, I., The thermochemical properties of some organic anhydrides, Bull. Inst. Politeh. Gheorghe Gheorghiu-Dej, Bucur., Ser. Chim.-Metal., 1978, 40, 2, 9. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Winstrom and Kulp, 1949
Winstrom, L.O.; Kulp, L., Vapor pressure of maleic anhydride, Ind. Eng. Chem., 1949, 41, 1584-25. [all data]

Winstrom and Kulp, 1949, 2
Winstrom, Leon O.; Kulp, Laurence, Vapor Pressure of Maleic Anhydride - Temperature Range from 35° to 77°, Ind. Eng. Chem., 1949, 41, 11, 2584-2586, https://doi.org/10.1021/ie50479a044 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

De Wit, Van Miltenburg, et al., 1983
De Wit, H.G.M.; Van Miltenburg, J.C.; De Kruif, C.G., Thermodynamic properties of molecular organic crystals containing nitrogen, oxygen, and sulphur 1. Vapour pressures and enthalpies of sublimation, The Journal of Chemical Thermodynamics, 1983, 15, 7, 651-663, https://doi.org/10.1016/0021-9614(83)90079-4 . [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press Inc., London, 1970, 643. [all data]

DeWit, DeKruif, et al., 1983
DeWit, H.G.M.; DeKruif, C.G.; Van Miltenburg, J.C., Thermodynamic properties of molecular organic crystals containing organic crystals containing nitrogen, oxygen, and sulfur. II. Molar heat capacities of eight compounds by adiabatic calorimetry, J. Chem. Thermodynam., 1983, 15, 891-902. [all data]

Mastrangelo, 1957
Mastrangelo, S.V.R., Adiabatic calorimeter for determination of cryoscopic data, Anal. Chem., 1957, 29(5), 841-845. [all data]

DeWit, Offringa, et al., 1983
DeWit, H.G.M.; Offringa, J.C.A.; De Kruif, C.G.; Van Miltenburg, J.C., Thermodynamic properties of molecular organic crystals containing nitrogen, oxygen and sulfur. III. Molar heat capacities measured by differential scanning calorimetry, Thermochim. Acta, 1983, 65, 43-51. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Spengler and Tamplin, 1952
Spengler, H.T.; Tamplin, W.S., Procedures in ice calorimetry, Anal. Chem., 1952, 24, 941-944. [all data]

Marchidan and Ciopec, 1978
Marchidan, D.I.; Ciopec, M., Thermodynamic properties of maleic, trimellitic and pyromellitic anhydrides, Rev. Roum. Chim., 1978, 23, 19-29. [all data]


Notes

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