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Methyl Isobutyl Ketone

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Deltafgas-291.2 ± 1.4kJ/molCcbDubois and Herzog, 1972ALS

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
180.50 ± 0.27394.30von Geiseler G., 1973GT
182.26 ± 0.27399.44
184.31 ± 0.28405.15
186.06 ± 0.28410.70
187.90 ± 0.28415.75

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DH - Eugene S. Domalski and Elizabeth D. Hearing
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafsolid-381.5kJ/molCcbTavernier and Lamouroux, 1956Author's hf298_condensed=-94.26 kcal/mol; ALS
Quantity Value Units Method Reference Comment
Deltacsolid-3694.6kJ/molCcbTavernier and Lamouroux, 1956Author's hf298_condensed=-94.26 kcal/mol; Corresponding «DELTA»fsolid = -381.5 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
211.9298.15Vesely, Barcal, et al., 1989T = 298.15 to 318.15 K.; DH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dubois and Herzog, 1972
Dubois, J.-E.; Herzog, H., Heats of formation of aliphatic ketones: Structure correlation based on environment treatment, J. Chem. Soc. Chem. Commun., 1972, 932-933. [all data]

von Geiseler G., 1973
von Geiseler G., The heat capacity and the heat of vaporization of isomeric butylmethylketones and propylacetates, Z. Phys. Chem. (Leipzig), 1973, 252, 170-176. [all data]

Tavernier and Lamouroux, 1956
Tavernier, P.; Lamouroux, M., Determinations calorimetriques relatives a vingt-six substances organiques, Mem. Poudres, 1956, 38, 65-88. [all data]

Vesely, Barcal, et al., 1989
Vesely, F.; Barcal, P.; Zabransky, M.; Svoboda, V., Heat capacities of 4-methyl-2-pentanone, 2,6-dimethyl-4-heptanone, 1-hexanol, 1-heptanol, and 1-octanol in the temperature range 298-318 K, Collect. Czech. Chem. Commun., 1989, 54, 602-607. [all data]


Notes

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