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N,N-Dimethylaminoethanol

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Phase change data

Go To: Top, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil407.2KN/AWeast and Grasselli, 1989BS
Tboil406.88KN/AQuitzsch, Hofmann, et al., 1970Uncertainty assigned by TRC = 0.2 K; TRC
Tboil407.75KN/AAnonymous, 1968TRC
Quantity Value Units Method Reference Comment
Tfus214.15KN/AAnonymous, 1968TRC
Quantity Value Units Method Reference Comment
Deltavap46.5 ± 0.4kJ/molGSKapteina, Slowik, et al., 2005Based on data from 278. - 316. K.; AC
Deltavap47.9kJ/molN/ATouhara, Okazaki, et al., 1982Based on data from 298. - 308. K. See also Kapteina, Slowik, et al., 2005.; AC
Deltavap47.6kJ/molEBQuitzsch, Hofmann, et al., 1970Based on data from 333. - 423. K. See also Kapteina, Slowik, et al., 2005.; AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
43.2365.AStephenson and Malanowski, 1987Based on data from 350. - 387. K.; AC
42.7338.AStephenson and Malanowski, 1987Based on data from 323. - 408. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

Go To: Top, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
8.80PEOhno, Imai, et al., 1985Vertical value; LBLHLM
8.82PEWieczorek, Koenig, et al., 1975Vertical value; LLK
8.85 ± 0.04PELeavell, Steichen, et al., 1973Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C3H8N+8.68CH2OHEILossing, Lam, et al., 1981LLK

IR Spectrum

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes

Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Mass spectrum (electron ionization)

Go To: Top, Phase change data, Gas phase ion energetics data, IR Spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 1998.
NIST MS number 291405

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Phase change data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Quitzsch, Hofmann, et al., 1970
Quitzsch, K.; Hofmann, H.P.; Hering, D.; Salzer, R.; Geiseler, G., Z. Phys. Chem. (Leipzig), 1970, 243, 5-6, 321. [all data]

Anonymous, 1968
Anonymous, X., Chemicals and Plastics Physical Properties, 1968, Union Carbide Corp., product bulletin, 1968. [all data]

Kapteina, Slowik, et al., 2005
Kapteina, Simon; Slowik, Krzysztof; Verevkin, Sergey P.; Heintz, Andreas, Vapor Pressures and Vaporization Enthalpies of a Series of Ethanolamines, J. Chem. Eng. Data, 2005, 50, 2, 398-402, https://doi.org/10.1021/je049761y . [all data]

Touhara, Okazaki, et al., 1982
Touhara, H.; Okazaki, S.; Okino, F.; Tanaka, H.; Ikari, K.; Nakanishi, K., Thermodynamic properties of aqueous mixtures of hydrophilic compounds 2. Aminoethanol and its methyl derivatives, The Journal of Chemical Thermodynamics, 1982, 14, 2, 145-156, https://doi.org/10.1016/0021-9614(82)90026-X . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Ohno, Imai, et al., 1985
Ohno, K.; Imai, K.; Harada, Y., Variations in reactivity of lone-pair electrons due to intramolecular hydrogen bonding as observed by penning ionization electron spectroscopy, J. Am. Chem. Soc., 1985, 107, 8078. [all data]

Wieczorek, Koenig, et al., 1975
Wieczorek, J.S.; Koenig, T.; Balle, T., The He(I) photoelectron spectra of amine n-oxides, J. Electron Spectrosc. Relat. Phenom., 1975, 6, 215. [all data]

Leavell, Steichen, et al., 1973
Leavell, S.; Steichen, J.; Franklin, J.L., Photoelectron spectra of intramolecularly hydrogen bonded compounds, J. Chem. Phys., 1973, 59, 4343. [all data]

Lossing, Lam, et al., 1981
Lossing, F.P.; Lam, Y.-T.; Maccoll, A., Gas phase heats of formation of alkyl immonium ions, Can. J. Chem., 1981, 59, 2228. [all data]


Notes

Go To: Top, Phase change data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References