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1,3-Butanediol

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil480. ± 3.KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Deltavap72.6 ± 0.3kJ/molGSVerevkin, 2007Based on data from 288. - 332. K.; AC
Deltavap72.8 ± 0.6kJ/molCErmelinda Eusébio, Lopes Jesus, et al., 2003AC
Deltavap74.5 ± 1.0kJ/molEBSteele, Chirico, et al., 1996Based on data from 365. - 518. K.; AC
Deltavap68.0kJ/molN/AGardner and Hussain, 1972DRB

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
72.3 ± 0.8320.EBSteele, Chirico, et al., 1996Based on data from 365. - 518. K.; AC
68.3 ± 0.7360.EBSteele, Chirico, et al., 1996Based on data from 365. - 518. K.; AC
64.1 ± 0.6400.EBSteele, Chirico, et al., 1996Based on data from 365. - 518. K.; AC
59.5 ± 0.5440.EBSteele, Chirico, et al., 1996Based on data from 365. - 518. K.; AC
54.4 ± 0.6480.EBSteele, Chirico, et al., 1996Based on data from 365. - 518. K.; AC
67.6377.AStephenson and Malanowski, 1987Based on data from 362. - 483. K.; AC
68. ± 2.373.VGardner and Hussain, 1972ALS
59.7398.N/ASchierholtz and Staples, 1935Based on data from 373. - 423. K.; AC
58.1451.N/ASchierholtz and Staples, 1935Based on data from 423. - 480. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
295.4 - 479.78.580876105.167230.59Stull, 1947Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Verevkin, 2007
Verevkin, Sergey P., Vapor Pressures and Enthalpies of Vaporization of a Series of the 1,3-Alkanediols, J. Chem. Eng. Data, 2007, 52, 1, 301-308, https://doi.org/10.1021/je060419q . [all data]

Ermelinda Eusébio, Lopes Jesus, et al., 2003
Ermelinda Eusébio, M.; Lopes Jesus, A.J.; Cruz, Mafalda S.C.; Leitão, M. Luisa P.; Simões Redinha, J., Enthalpy of vaporisation of butanediol isomers, The Journal of Chemical Thermodynamics, 2003, 35, 1, 123-129, https://doi.org/10.1016/S0021-9614(02)00306-3 . [all data]

Steele, Chirico, et al., 1996
Steele, W.V.; Chirico, R.D.; Knipmeyer, S.E.; Nguyen, A., Vapor Pressure of Acetophenone, (±)-1,2-Butanediol, (±)-1,3-Butanediol, Diethylene Glycol Monopropyl Ether, 1,3-Dimethyladamantane, 2-Ethoxyethyl Acetate, Ethyl Octyl Sulfide, and Pentyl Acetate, J. Chem. Eng. Data, 1996, 41, 6, 1255-1268, https://doi.org/10.1021/je9601117 . [all data]

Gardner and Hussain, 1972
Gardner, P.J.; Hussain, K.S., The standard enthalpies of formation of some aliphatic diols, J. Chem. Thermodyn., 1972, 4, 819-827. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Schierholtz and Staples, 1935
Schierholtz, O.J.; Staples, M.L., Vapor Pressures of Certain Glycols, J. Am. Chem. Soc., 1935, 57, 12, 2709-2711, https://doi.org/10.1021/ja01315a106 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]


Notes

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