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F2C=C radical anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: J.E. Bartmess

Quantity Value Units Method Reference Comment
Deltafgas-75. ± 50.kJ/molEIAEHeni and Illenberger, 1986From F2C=CHF
Deltafgas<14.6kJ/molIMRBDawson and Jennings, 1976O- + CH2=CF2 ->. G3MP2B3 calculations indicate a HOF(A-) of -22 kcal/mol.
Deltafgas-649. ± 59.kJ/molEIAEHarland and Thynne, 1975From CF3CHO. G3MP2B3 calculations indicate an EA of ca. 2.3 eV, and HOF(A-) of -22 kcal/mol.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Heni and Illenberger, 1986
Heni, M.; Illenberger, E., The Unimolecular Decompositions of the Fluoroethylene Radical Anions formed by Electron Attachment, J. Electron Spectros. Rel. Phenom., 1986, 41, 2, 453, https://doi.org/10.1016/0368-2048(86)85022-8 . [all data]

Dawson and Jennings, 1976
Dawson, J.H.J.; Jennings, K.R., Production of gas phase radical anions by reaction of O-. Ions with organic substrates, J. Chem. Soc. Faraday Trans. 2, 1976, 72, 700. [all data]

Harland and Thynne, 1975
Harland, P.W.; Thynne, J.C.J., Dissociative eElectron cCapture in tTrifluoroacetaldehyde, pentafluoropropionaldehyde, and heptafluorobutyraldehyde, Int. J. Mass Spectrom. Ion Phys., 1975, 18, 73. [all data]


Notes

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