Sarin


Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-1SE-54SE-54SE-54DB-1
Column length (m) 15.25.25.25.15.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.320.320.320.320.53
Phase thickness (μm) 0.250.250.250.25 
Tstart (C) 50.40.40.40.50.
Tend (C) 280.280.280.280. 
Heat rate (K/min) 10.10.10.10.10.
Initial hold (min) 2.1.1.1.2.
Final hold (min) 10.10.   
I 792.820.818.37819.25789.
ReferenceKostiainen, 2000Kostiainen, 2000Kaipainen, Kostiainen, et al., 1992Kaipainen, Kostiainen, et al., 1992Hancock and Peters, 1991
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillary
Active phase DB-5DB-1DB-5
Column length (m) 15.15.15.
Carrier gas HeHeHe
Substrate    
Column diameter (mm) 0.530.320.32
Phase thickness (μm)  0.250.25
Tstart (C) 50.50.50.
Tend (C)  300.300.
Heat rate (K/min) 10.10.10.
Initial hold (min) 2.2.2.
Final hold (min)  5. 
I 817.791.8823.8
ReferenceHancock and Peters, 1991D'Agostino and Provost, 1985D'Agostino and Provost, 1985
Comment MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kostiainen, 2000
Kostiainen, O., Gas Chromatography in Screening of Chemicals Related to the Chemical Weapons Convention in Encyclopedia of Analytical Chemistry, Meyers, R.A., ed(s)., John Wiley Sons Ltd, Chichester, 2000, 963-979. [all data]

Kaipainen, Kostiainen, et al., 1992
Kaipainen, A.; Kostiainen, O.; Riekkola, M.-L., Identification of chemical warfare agents in air samples using capillary column gas chromatography with three simultaneous detectors, J. Microcolumn Sep., 1992, 4, 3, 245-251, https://doi.org/10.1002/mcs.1220040311 . [all data]

Hancock and Peters, 1991
Hancock, J.R.; Peters, G.R., Retention index monitoring of compounds of chemical defence interest using thermal desorption gas chromatography, J. Chromatogr., 1991, 538, 2, 249-257, https://doi.org/10.1016/S0021-9673(01)88845-2 . [all data]

D'Agostino and Provost, 1985
D'Agostino, P.A.; Provost, L.R., Gas chromatographic retention indices of chemical warfare agents and simulants, J. Chromatogr., 1985, 331, 47-54, https://doi.org/10.1016/0021-9673(85)80005-4 . [all data]


Notes

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