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1,2-Ethanediol

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Enthalpy of combustion of liquid at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Deltacliquid (kcal/mol) Method Reference Comment
-283.13 ± 0.67CcrKnauth and Sabbah, 1990see Knauth and Sabbah, 1989; Corresponding «DELTA»fliquid = -109.9 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-284.14 ± 0.16CcbGardner and Hussain, 1972Corresponding «DELTA»fliquid = -108.91 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-284.47CmParks and Manchester, 1952From heat of solution; Corresponding «DELTA»fliquid = -108.58 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-284.1 ± 0.2CcbMcClaine, 1947Corresponding «DELTA»fliquid = -108.9 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-284.32 ± 0.17CcbParks, West, et al., 1946Corresponding «DELTA»fliquid = -108.73 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-287.43 ± 0.29CcbJung and Dahmlos, 1942Reanalyzed by Cox and Pilcher, 1970, Original value = -287.1 kcal/mol; Corresponding «DELTA»fliquid = -105.62 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
-284.75 ± 0.29CcbMoureu and Dode, 1937Reanalyzed by Cox and Pilcher, 1970, Original value = -285.0 kcal/mol; Corresponding «DELTA»fliquid = -108.30 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS

References

Go To: Top, Enthalpy of combustion of liquid at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Knauth and Sabbah, 1990
Knauth, P.; Sabbah, R., Energetics of intra- and intermolecular bonds in «omega»-alkanediols (II) Thermochemical study of 1,2-ethanediol, 1,3-propanediol, 1,4-butanediol, and 1,5-pentanediol at 298.15K, Struct. Chem., 1990, 1, 43-46. [all data]

Knauth and Sabbah, 1989
Knauth, P.; Sabbah, R., Combustion calorimetry on milligram samples of liquid substances with a CRMT rocking bomb calorimeter. Application to the study of «omega»-alkanediol at 298.15 K, J. Chem. Thermodyn., 1989, 21, 203-210. [all data]

Gardner and Hussain, 1972
Gardner, P.J.; Hussain, K.S., The standard enthalpies of formation of some aliphatic diols, J. Chem. Thermodyn., 1972, 4, 819-827. [all data]

Parks and Manchester, 1952
Parks, G.S.; Manchester, K.E., The heats of solution of erythritol, mannitol and dulcitol; combustion values for liquid polyhydroxy alcohols, J. Am. Chem. Soc., 1952, 74, 3435-34. [all data]

McClaine, 1947
McClaine, L.A., Thermodynamic data for some compounds containing carbon, hydrogen and oxygen, Ph.D. Thesis for Stanford University, 1947, 1-57. [all data]

Parks, West, et al., 1946
Parks, G.S.; West, T.J.; Naylor, B.F.; Fujii, P.S.; McClaine, L.A., Thermal data on organic compounds. XXIII. Modern combustion data for fourteen hydrocarbons and five polyhydroxy alcohols, J. Am. Chem. Soc., 1946, 68, 2524-2527. [all data]

Jung and Dahmlos, 1942
Jung, G.; Dahmlos, J., Thermochemische untersuchungen zur frage der drehbarkeit um C-C-bindunge, Z. Phys. Chem., 1942, 190, 230-240. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Moureu and Dode, 1937
Moureu, H.; Dode, M., Chaleurs de formation de l'oxyde d'ethylene, de l'ethanediol et de quelques homologues, Bull. Soc. Chim. France, 1937, 4, 637-647. [all data]


Notes

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