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Diisopropyl mercury


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas91.2 ± 4.6kJ/molReviewMartinho Simões 
Deltafgas36.9 ± 6.2kJ/molReviewMartinho SimõesSelected data

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafliquid37.6 ± 4.3kJ/molReviewMartinho Simões 
Deltafliquid-16.7 ± 6.0kJ/molReviewMartinho SimõesSelected data
Quantity Value Units Method Reference Comment
Deltacliquid-4399.5 ± 4.2kJ/molCC-SBJones, Evans, et al., 1935Please also see Cox and Pilcher, 1970.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltavap53.6 ± 1.7kJ/molCC-SBTees, 1952 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C6H14Hg (l) + Cl2Hg (cr) = 2C3H7ClHg (cr)

By formula: C6H14Hg (l) + Cl2Hg (cr) = 2C3H7ClHg (cr)

Quantity Value Units Method Reference Comment
Deltar-94.3 ± 2.1kJ/molRSCMortimer, Pritchard, et al., 1952Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS

C6H14Hg (l) + Mercury(II) bromide (cr) = 2C3H7BrHg (cr)

By formula: C6H14Hg (l) + Br2Hg (cr) = 2C3H7BrHg (cr)

Quantity Value Units Method Reference Comment
Deltar-88.8 ± 1.5kJ/molRSCMortimer, Pritchard, et al., 1952Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS

C6H14Hg (l) + Mercury diiodide (cr) = 2C3H7HgI (cr)

By formula: C6H14Hg (l) + HgI2 (cr) = 2C3H7HgI (cr)

Quantity Value Units Method Reference Comment
Deltar-65.3 ± 1.7kJ/molRSCMortimer, Pritchard, et al., 1952Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS

2Propane, 2-iodo- + Mercury diiodide = C6H14Hg + 2Iodine

By formula: 2C3H7I + HgI2 = C6H14Hg + 2I2

Quantity Value Units Method Reference Comment
Deltar242.3 ± 1.9kJ/molCmMortimer, Pritchard, et al., 1952, 2liquid phase; ALS

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
7.6 ± 0.1EIGowenlock, Haynes, et al., 1962RDSH
8.03PEFehlner, Ulman, et al., 1976Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C3H7+9.7 ± 0.1?EIGowenlock, Haynes, et al., 1962RDSH
C3H7Hg+9.1 ± 0.1C3H7EIGowenlock, Haynes, et al., 1962RDSH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Jones, Evans, et al., 1935
Jones, W.J.; Evans, D.P.; Gulwell, T.; Griffiths, D.C., J. Chem. Soc., 1935, 39.. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Tees, 1952
Tees, T.F.S., Trans. Faraday Soc., 1952, 48, 227. [all data]

Mortimer, Pritchard, et al., 1952
Mortimer, C.T.; Pritchard, H.O.; Skinner, H.A., Thermochemistry of metallic alkyls. Part V.?Mercury di-propyl and mercury di-isopropyl, Trans. Faraday Soc., 1952, 48, 220, https://doi.org/10.1039/tf9524800220 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Mortimer, Pritchard, et al., 1952, 2
Mortimer, C.T.; Pritchard, H.O.; Skinner, H.A., Thermochemistry of metallic alkyls. Part V - Mercury di-propyl and mercury di-isopropyl, Trans. Faraday Soc., 1952, 48, 220-229. [all data]

Gowenlock, Haynes, et al., 1962
Gowenlock, B.G.; Haynes, R.M.; Majer, J.R., Electron impact measurement on some organomercury compounds, J. Chem. Soc. Faraday Trans., 1962, 58, 1905. [all data]

Fehlner, Ulman, et al., 1976
Fehlner, T.P.; Ulman, J.; Nugent, W.A.; Kochi, J.K., Effect of alkyl substituents on the first ionization potential and on 5d10 ionization in dialkylmercury compounds, Inorg. Chem., 1976, 15, 2544. [all data]


Notes

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