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Propanenitrile

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis

Quantity Value Units Method Reference Comment
Tboil370. ± 1.KAVGN/AAverage of 31 out of 35 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus180. ± 7.KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple180.37KN/AWeber and Kilpatrick, 1962Crystal phase 1 phase; Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Tc561.3KN/ACastillo-Lopez and Trejo Rodriguez, 1987Uncertainty assigned by TRC = 0.2 K; Visual, TE with digital voltmeter calibr. by meas. on alkanes.; TRC
Tc558.7KN/AGuye and Mallet, 1902Uncertainty assigned by TRC = 2. K; TRC
Tc558.85KN/AGuye and Mallet, 1902, 2Uncertainty assigned by TRC = 1. K; TRC
Tc558.85KN/AGuye and Mallet, 1902, 2Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Pc42.60barN/ACastillo-Lopez and Trejo Rodriguez, 1987Uncertainty assigned by TRC = 0.10 bar; Visual; TRC
Pc41.80barN/AGuye and Mallet, 1902Uncertainty assigned by TRC = 0.9119 bar; TRC
Pc41.7459barN/AGuye and Mallet, 1902, 2Uncertainty assigned by TRC = 0.8106 bar; TRC
Pc41.9485barN/AGuye and Mallet, 1902, 2Uncertainty assigned by TRC = 0.8106 bar; TRC
Quantity Value Units Method Reference Comment
Deltavap36.3 ± 0.8kJ/molAVGN/AAverage of 6 values; Individual data points

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
36.116298.15N/AWeber and Kilpatrick, 1962, 2P = 6.29 kPa; DH
31.81371.N/AMajer and Svoboda, 1985 
36.1303.AStephenson and Malanowski, 1987Based on data from 288. - 371. K.; AC
36.7326.BGBaldt and Hall, 1971Based on data from 308. - 363. K.; AC
36.5280.N/AMilazzo, 1956Based on data from 189. - 295. K. See also Boublik, Fried, et al., 1984.; AC
35.9323.N/ADreisbach and Shrader, 1949Based on data from 308. - 370. K. See also Dreisbach and Martin, 1949 and Boublik, Fried, et al., 1984.; AC

Entropy of vaporization

DeltavapS (J/mol*K) Temperature (K) Reference Comment
121.1298.15Weber and Kilpatrick, 1962, 2P; DH

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
308.7 - 370.503.617321036.424-83.76Dreisbach and Shrader, 1949Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
5.03180.4Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
9.67177.0Domalski and Hearing, 1996CAL
27.91180.4

Enthalpy of phase transition

DeltaHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
1.7067176.96crystaline, IIcrystaline, IWeber and Kilpatrick, 1962, 2DH
5.0300180.37crystaline, IliquidWeber and Kilpatrick, 1962, 2DH

Entropy of phase transition

DeltaStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
9.64176.96crystaline, IIcrystaline, IWeber and Kilpatrick, 1962, 2DH
27.89180.37crystaline, IliquidWeber and Kilpatrick, 1962, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weber and Kilpatrick, 1962
Weber, L.A.; Kilpatrick, J.E., Entropy and related thermodynamic properties of propionitrile, J. Chem. Phys., 1962, 36, 829. [all data]

Castillo-Lopez and Trejo Rodriguez, 1987
Castillo-Lopez, N.; Trejo Rodriguez, A., The critical temperatures and pressures of several n-alkanenitriles, J. Chem. Thermodyn., 1987, 19, 671. [all data]

Guye and Mallet, 1902
Guye, P.A.; Mallet, E., Critical Constant and Molecular Complexity of Several Organic Compds., C. R. Hebd. Seances Acad. Sci., 1902, 133, 168. [all data]

Guye and Mallet, 1902, 2
Guye, P.A.; Mallet, E., Measurement of Critical Constants, Arch. Sci. Phys. Nat., 1902, 13, 274-296. [all data]

Weber and Kilpatrick, 1962, 2
Weber, L.A.; Kilpatrick, J.E., Entropy and related thermodynamic properties of propionitrile, J. Chem. Phys., 1962, 36, 829-834. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Baldt and Hall, 1971
Baldt, J.H.; Hall, H.K.K., Jr., Thermochemistry of strained-ring bridgehead nitriles and esters, J. Am. Chem. Soc., 1971, 93, 140-145. [all data]

Milazzo, 1956
Milazzo, G., Ann. Chim. (Rome), 1956, 46, 1105. [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

Dreisbach and Shrader, 1949
Dreisbach, R.R.; Shrader, S.A., Vapor Pressure--Temperature Data on Some Organic Compounds, Ind. Eng. Chem., 1949, 41, 12, 2879-2880, https://doi.org/10.1021/ie50480a054 . [all data]

Dreisbach and Martin, 1949
Dreisbach, R.R.; Martin, R.A., Physical Data on Some Organic Compounds, Ind. Eng. Chem., 1949, 41, 12, 2875-2878, https://doi.org/10.1021/ie50480a053 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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