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Propylamine

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C3H10N+ + Propylamine = (C3H10N+ bullet Propylamine)

By formula: C3H10N+ + C3H9N = (C3H10N+ bullet C3H9N)

Quantity Value Units Method Reference Comment
Deltar24.5kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar27.6cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M

(C3H10N+ bullet Propylamine) + Propylamine = (C3H10N+ bullet 2Propylamine)

By formula: (C3H10N+ bullet C3H9N) + C3H9N = (C3H10N+ bullet 2C3H9N)

Quantity Value Units Method Reference Comment
Deltar16.0kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar19.5kcal/molHPMSZielinska and Wincel, 1974gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar26.3cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar41.6cal/mol*KHPMSZielinska and Wincel, 1974gas phase; Entropy change is questionable; M

(C3H10N+ bullet 2Propylamine) + Propylamine = (C3H10N+ bullet 3Propylamine)

By formula: (C3H10N+ bullet 2C3H9N) + C3H9N = (C3H10N+ bullet 3C3H9N)

Quantity Value Units Method Reference Comment
Deltar14.0kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar17.1kcal/molHPMSZielinska and Wincel, 1974gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar30.1cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
Deltar42.3cal/mol*KHPMSZielinska and Wincel, 1974gas phase; Entropy change is questionable; M

(C3H10N+ bullet 3Propylamine) + Propylamine = (C3H10N+ bullet 4Propylamine)

By formula: (C3H10N+ bullet 3C3H9N) + C3H9N = (C3H10N+ bullet 4C3H9N)

Quantity Value Units Method Reference Comment
Deltar7.7kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar20.1cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M

(C3H10N+ bullet 4Propylamine) + Propylamine = (C3H10N+ bullet 5Propylamine)

By formula: (C3H10N+ bullet 4C3H9N) + C3H9N = (C3H10N+ bullet 5C3H9N)

Quantity Value Units Method Reference Comment
Deltar7.kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/AMeot-Ner (Mautner), 1992gas phase; Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.4174.PHPMSMeot-Ner (Mautner), 1992gas phase; Entropy change calculated or estimated; M

Potassium ion (1+) + Propylamine = (Potassium ion (1+) bullet Propylamine)

By formula: K+ + C3H9N = (K+ bullet C3H9N)

Quantity Value Units Method Reference Comment
Deltar21.8kcal/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
Deltar25.5cal/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

Sodium ion (1+) + Propylamine = (Sodium ion (1+) bullet Propylamine)

By formula: Na+ + C3H9N = (Na+ bullet C3H9N)

Quantity Value Units Method Reference Comment
Deltar28.9 ± 1.4kcal/molCIDTMoision and Armentrout, 2002RCD

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner (Mautner), 1992
Meot-Ner (Mautner), M., Intermolecular Forces in Organic Clusters, J. Am. Chem. Soc., 1992, 114, 9, 3312, https://doi.org/10.1021/ja00035a024 . [all data]

Zielinska and Wincel, 1974
Zielinska, T.J.; Wincel, H., Gas - Phase Solvation of Protonated Aliphatic Amines: Methyl, Ethyl, n - Propyl, and Iso - Propylamine, Chem. Phys. Lett., 1974, 25, 354. [all data]

Davidson and Kebarle, 1976
Davidson, W.R.; Kebarle, P., Binding Energies and Stabilities of Potassium Ion Complexes from Studies of Gas Phase Ion Equilibria K+ + M = K+.M, J. Am. Chem. Soc., 1976, 98, 20, 6133, https://doi.org/10.1021/ja00436a011 . [all data]

Moision and Armentrout, 2002
Moision, R.M.; Armentrout, P.B., Experimental and Theoretical Dissection of Sodium Cation/Glycine Interactions, J. Phys. Chem A, 2002, 106, 43, 10350, https://doi.org/10.1021/jp0216373 . [all data]


Notes

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