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Propane, 1,1,1,3-tetrachloro-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-208.7 ± 1.1kJ/molCcrKolesov, Tomareva, et al., 1970hf298_gas[kcal/mol]=-38.47±0.41; Kolesov and Kozina, 1986; ALS
Quantity Value Units Method Reference Comment
Deltacliquid-1638. ± 1.1kJ/molCcrKolesov, Tomareva, et al., 1970hf298_gas[kcal/mol]=-38.47±0.41; Kolesov and Kozina, 1986; ALS
Quantity Value Units Method Reference Comment
liquid284.30J/mol*KN/AKolesov, Vorob'ev, et al., 1974DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
196.40298.15Kolesov, Vorob'ev, et al., 1974T = 12 to 300 K.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil432.2KN/AWeast and Grasselli, 1989BS
Tboil432.KN/AJoyce, Hanford, et al., 1948Uncertainty assigned by TRC = 2. K; TRC
Tboil430.9KN/AStevens, 1946Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Ttriple237.74KN/AKolesov, Vorob'ev, et al., 1974, 2Crystal phase 1 phase; Uncertainty assigned by TRC = 0.02 K; TRC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
352. - 354.0.073PCR Inc., 1990BS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
57.8315.AStephenson and Malanowski, 1987Based on data from 300. - 377. K.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
10.49237.7Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
10.03219.9Domalski and Hearing, 1996CAL
44.13237.7

Enthalpy of phase transition

DeltaHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
2.205219.9crystaline, IIcrystaline, IKolesov, Vorob'ev, et al., 1974DH
10.489237.74crystaline, IliquidKolesov, Vorob'ev, et al., 1974DH

Entropy of phase transition

DeltaStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
10.03219.9crystaline, IIcrystaline, IKolesov, Vorob'ev, et al., 1974DH
44.12237.74crystaline, IliquidKolesov, Vorob'ev, et al., 1974DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
NIST MS number 22212

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Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryOV-101921.Zenkevich, Eliseenkov, et al., 2006Nitrogen, 6. K/min, 240. C @ 10. min; Column length: 25. m; Column diameter: 0.20 mm; Tstart: 60. C

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryPolydimethyl siloxanes921.Zenkevich, Eliseenkov, et al., 2006Program: not specified

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kolesov, Tomareva, et al., 1970
Kolesov, V.P.; Tomareva, E.M.; Skuratov, S.M., Standard enthalpy of formation of 1,1,1,3-tetrachloropropane, Russ. J. Phys. Chem. (Engl. Transl.), 1970, 44, 1580-1581. [all data]

Kolesov and Kozina, 1986
Kolesov, V.P.; Kozina, M.P., Thermochemistry of organic and organohalogen compounds, Russ. Chem. Rev., 1986, 55, 912. [all data]

Kolesov, Vorob'ev, et al., 1974
Kolesov, V.P.; Vorob'ev, V.N.; Sarzhina, E.A.; Pentin, Yu.A.; Timoshenkova, Yu.D., Heat capacity from 12 to 300 K, phase transitions, and thermodynamic functions of 1,1,1-trifluoro-3-chloropropane and 1,1,1,3-tetrachloropropane, J. Chem. Thermodynam., 1974, 6, 613-628. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Joyce, Hanford, et al., 1948
Joyce, R.M.; Hanford, W.E.; Harmon, J., J. Am. Chem. Soc., 1948, 70, 2529. [all data]

Stevens, 1946
Stevens, P.G., Some New Cyclopropanes with A Note on the Exterior Valence Angles of Cyclopropane, J. Am. Chem. Soc., 1946, 68, 620-2. [all data]

Kolesov, Vorob'ev, et al., 1974, 2
Kolesov, V.P.; Vorob'ev, V.N.; Sarzhina, E.A.; Pentin, Y.A.; Timoshenkova, Yu.D., Heat capacity from 12 to 300 K, phase transitions, and thermodynamic functions of 1,1,1-trifluoro-3-chloropropane and 1,1,1,3-tetrachloropropane, J. Chem. Thermodyn., 1974, 6, 613-28. [all data]

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Zenkevich, Eliseenkov, et al., 2006
Zenkevich, I.G.; Eliseenkov, E.V.; Kasatochkin, A.N., Application of Retention Indices in GC-MS Identification of Halogenated Organic Compounds, Mass Spectromery (Rus.), 2006, 3, 2, 131-140. [all data]


Notes

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