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Propiolonitrile

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CH6N+ + Propiolonitrile = (CH6N+ bullet Propiolonitrile)

By formula: CH6N+ + C3HN = (CH6N+ bullet C3HN)

Quantity Value Units Method Reference Comment
Deltar24.0kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated, CD3NH3+
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KN/ASpeller and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated, CD3NH3+

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.6500.PHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated, CD3NH3+

C3H2N+ + Propiolonitrile = (C3H2N+ bullet Propiolonitrile)

By formula: C3H2N+ + C3HN = (C3H2N+ bullet C3HN)

Quantity Value Units Method Reference Comment
Deltar27.4kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase
Quantity Value Units Method Reference Comment
Deltar25.7cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase

NH4+ + Propiolonitrile = (NH4+ bullet Propiolonitrile)

By formula: H4N+ + C3HN = (H4N+ bullet C3HN)

Quantity Value Units Method Reference Comment
Deltar22.9kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase
Quantity Value Units Method Reference Comment
Deltar22.6cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Speller and Meot-Ner (Mautner), 1985
Speller, C.V.; Meot-Ner (Mautner), M., The Ionic Hydrogen Bond and Ion Solvation. 3. Bonds Involving Cyanides. Correlations with Proton Affinites, J. Phys. Chem., 1985, 81, 24, 5217, https://doi.org/10.1021/j100270a020 . [all data]


Notes

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