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Hexane, 2,3,5-trimethyl-

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Kovats' RI, non-polar column, isothermal

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SqualaneSqualaneSqualaneSqualaneDB-1
Column length (m)   50.50.60.
Carrier gas   HeHe 
Substrate      
Column diameter (mm)   0.220.220.264
Phase thickness (mum)      
Temperature (C) 100.25.50.70.60.
I 813.810.811.4813.3817.
ReferenceHeinzen, Soares, et al., 1999Hilal, Carreira, et al., 1994Lunskii and Paizanskaya, 1988Lunskii and Paizanskaya, 1988Lubeck and Sutton, 1983
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1SqualaneSqualaneVacuum Grease Oil (VM-4)Squalane
Column length (m) 60.  150.100.
Carrier gas    N2N2
Substrate      
Column diameter (mm) 0.259  0.250.25
Phase thickness (mum) 1.    
Temperature (C) 60.60.60.95.50.
I 817.813.813.2811.7812.
ReferenceLubeck and Sutton, 1983Chretien and Dubois, 1976Chretien and Dubois, 1976Sultanov and Arustamova, 1975Rijks and Cramers, 1974
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SqualaneVacuum Grease Oil (VM-4)Vacuum Grease Oil (VM-4)Vacuum Grease Oil (VM-4)Vacuum Grease Oil (VM-4)
Column length (m) 100.    
Carrier gas N2    
Substrate      
Column diameter (mm) 0.25    
Phase thickness (mum)      
Temperature (C) 70.35.45.50.58.
I 814.806.808.808.810.
ReferenceRijks and Cramers, 1974Sidorov, Petrova, et al., 1972Sidorov, Petrova, et al., 1972Sidorov, Petrova, et al., 1972Sidorov, Petrova, et al., 1972
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryPackedPackedCapillaryPacked
Active phase Vacuum Grease Oil (VM-4)SE-30SqualaneSqualaneSqualane
Column length (m)    91.410.
Carrier gas  N2N2N2H2
Substrate      
Column diameter (mm)    0.25 
Phase thickness (mum)      
Temperature (C) 68.80.25.60.30.
I 812.818.810.813.810.5
ReferenceSidorov, Petrova, et al., 1972Mitra and Saha, 1970Mitra and Saha, 1970Matukuma, 1969Tourres, 1967
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedCapillaryCapillaryCapillary
Active phase SqualaneSqualaneSqualaneSqualane
Column length (m) 10.100.100.100.
Carrier gas H2H2H2H2
Substrate     
Column diameter (mm)  0.250.250.25
Phase thickness (mum)     
Temperature (C) 50.30.50.70.
I 812.811.812.812.
ReferenceTourres, 1967Tourres, 1967, 2Tourres, 1967, 2Tourres, 1967, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Kovats' RI, non-polar column, isothermal, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Heinzen, Soares, et al., 1999
Heinzen, V.E.F.; Soares, M.F.; Yunes, R.A., Semi-empirical topological method for the prediction of the chromatographic retention of cis- and trans-alkene isomers and alkanes, J. Chromatogr. A, 1999, 849, 2, 495-506, https://doi.org/10.1016/S0021-9673(99)00530-0 . [all data]

Hilal, Carreira, et al., 1994
Hilal, S.H.; Carreira, L.A.; Karickhoff, S.W.; Melton, C.M., Estimation of Gas-Liquid Chromatographic Retention Times from Molecular Structure, J. Chromatogr. A, 1994, 662, 2, 269-280, https://doi.org/10.1016/0021-9673(94)80515-6 . [all data]

Lunskii and Paizanskaya, 1988
Lunskii, M.Kh.; Paizanskaya, I.L., Identification of hydrocarbons C1-C9 of petrol fractions of oils and condensates in the use of capillary columns with dinonylphthalate, Zh. Anal. Khim., 1988, 43, 127-135. [all data]

Lubeck and Sutton, 1983
Lubeck, A.J.; Sutton, DL., Kovats retention indices of selected hydrocarbons through C10 on bonded phase fused silica capillaries, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1983, 6, 6, 328-332, https://doi.org/10.1002/jhrc.1240060612 . [all data]

Chretien and Dubois, 1976
Chretien, J.R.; Dubois, J.-E., New Perspectives in the Prediction of Kovats Indices, J. Chromatogr., 1976, 126, 171-189, https://doi.org/10.1016/S0021-9673(01)84071-1 . [all data]

Sultanov and Arustamova, 1975
Sultanov, N.T.; Arustamova, L.G., Determination of the boiling points of C10 isoalkanes in an n-decane isomerizate from gas chromatographic retention indices, J. Chromatogr., 1975, 115, 2, 553-558, https://doi.org/10.1016/S0021-9673(01)98959-9 . [all data]

Rijks and Cramers, 1974
Rijks, J.A.; Cramers, C.A., High precision capillary gas chromatography of hydrocarbons, Chromatographia, 1974, 7, 3, 99-106, https://doi.org/10.1007/BF02269819 . [all data]

Sidorov, Petrova, et al., 1972
Sidorov, R.I.; Petrova, V.I.; Ivanova, M.P., Qualitative analysis of wide-boiling fraction C5-C10 with capillary chromatography in Processes in chromatographic columns. Vol.17, 1972, 14-25. [all data]

Mitra and Saha, 1970
Mitra, G.D.; Saha, N.C., Determination of Retention Indices of Saturated Hydrocarbons by Graphical Methods, J. Chromatogr. Sci., 1970, 8, 2, 95-102, https://doi.org/10.1093/chromsci/8.2.95 . [all data]

Matukuma, 1969
Matukuma, A., Retention indices of alkanes through C10 and alkenes through C8 and relation between boiling points and retention data, Gas Chromatogr., Int. Symp. Anal. Instrum. Div Instrum Soc. Amer., 1969, 7, 55-75. [all data]

Tourres, 1967
Tourres, D.A., Structural analysis of industrial butene dimers by gas chromatography, J. Gas Chromatogr., 1967, 5, 1, 35-40, https://doi.org/10.1093/chromsci/5.1.35 . [all data]

Tourres, 1967, 2
Tourres, D.A., Structure moléculaire et rétention en chromatographie en phase gazeuse. Influence de la température sur l'indice de rétention d'alcanes isomères, J. Chromatogr., 1967, 30, 357-377, https://doi.org/10.1016/S0021-9673(00)84168-0 . [all data]


Notes

Go To: Top, Kovats' RI, non-polar column, isothermal, References