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Propane, 1-bromo-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil343.9 ± 0.5KAVGN/AAverage of 26 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus162.7KN/AVan de Vloed, 1939Uncertainty assigned by TRC = 0.2 K; TRC
Tfus163.KN/ATimmermans, 1935Uncertainty assigned by TRC = 2. K; TRC
Tfus163.15KN/ATimmermans, 1934Uncertainty assigned by TRC = 0.4 K; TRC
Tfus163.2KN/ASapgir, 1929Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Tc536.94KN/ALi, Ma, et al., 1993Uncertainty assigned by TRC = 0.1 K; TRC
Tc544.5KN/AMajer and Svoboda, 1985 
Quantity Value Units Method Reference Comment
Pc47.35atmN/ALi, Ma, et al., 1993Uncertainty assigned by TRC = 0.20 atm; TRC
Quantity Value Units Method Reference Comment
Deltavap7.679kcal/molN/AMajer and Svoboda, 1985 
Deltavap7.62 ± 0.02kcal/molCWadsö, Murto, et al., 1966AC
Deltavap7.62 ± 0.02kcal/molCWadso, 1966ALS

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
7.132344.2N/AMajer and Svoboda, 1985 
7.60316.A,EBStephenson and Malanowski, 1987Based on data from 301. - 344. K. See also Svoboda, Majer, et al., 1977.; AC
8.15265.A,EStephenson and Malanowski, 1987Based on data from 250. - 368. K. See also Li and Rossini, 1961 and Dykyj, 1970.; AC
7.43 ± 0.02322.CSvoboda, Majer, et al., 1977AC
7.29 ± 0.02332.CSvoboda, Majer, et al., 1977AC
7.19 ± 0.02339.CSvoboda, Majer, et al., 1977AC
7.00 ± 0.02352.CSvoboda, Majer, et al., 1977AC
8.48235.N/AStull, 1947Based on data from 220. - 344. K.; AC
7.14341.8VMathews and Fehlandt, 1931ALS
7.79288.N/ARex, 1906Based on data from 273. - 303. K. See also Boublik, Fried, et al., 1984.; AC

Enthalpy of vaporization

ΔvapH = A exp(-βTr) (1 − Tr)β
    ΔvapH = Enthalpy of vaporization (at saturation pressure) (kcal/mol)
    Tr = reduced temperature (T / Tc)

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Temperature (K) A (kcal/mol) beta Tc (K) Reference Comment
298. - 352.10.570.2412544.5Majer and Svoboda, 1985 

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
220. - 344.4.156851259.836-41.108Stull, 1947Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Van de Vloed, 1939
Van de Vloed, A., Bull. Soc. Chim. Belg., 1939, 48, 229. [all data]

Timmermans, 1935
Timmermans, J., Researches in Stoichiometry. I. The Heat of Fusion of Organic Compounds., Bull. Soc. Chim. Belg., 1935, 44, 17-40. [all data]

Timmermans, 1934
Timmermans, J., Theory of Concentrated Solutions XII., Bull. Soc. Chim. Belg., 1934, 43, 626. [all data]

Sapgir, 1929
Sapgir, S., The concentrated solutions theory, Bull. Soc. Chim. Belg., 1929, 38, 392-408. [all data]

Li, Ma, et al., 1993
Li, Y.; Ma, P.; Ruan, Y., Measurement of the critical constants of 1-hexene and 1-bromopropane, Shiyou Huagong, 1993, 22, 322-324. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Wadsö, Murto, et al., 1966
Wadsö, Ingemar; Murto, Maija-Leena; Bergson, Göran; Ehrenberg, L.; Brunvoll, J.; Bunnenberg, E.; Djerassi, Carl; Records, Ruth, Heats of Vaporization for a Number of Organic Compounds at 25 degrees C., Acta Chem. Scand., 1966, 20, 544-552, https://doi.org/10.3891/acta.chem.scand.20-0544 . [all data]

Wadso, 1966
Wadso, I., Acta Chem. Scand., 1966, 20, 544. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Svoboda, Majer, et al., 1977
Svoboda, V.; Majer, V.; Veselý, F.; Pick, J., Heats of vaporization of alkyl bromides, Collect. Czech. Chem. Commun., 1977, 42, 6, 1755-1760, https://doi.org/10.1135/cccc19771755 . [all data]

Li and Rossini, 1961
Li, J.C.M.; Rossini, F.D., Vapor Pressures and Boiling Points of the l-Fluoroalkanes, l-Chloroalkanes, l-Bromoalkanes, and l-Iodoalkanes, C 1 to C 20 ., J. Chem. Eng. Data, 1961, 6, 2, 268-270, https://doi.org/10.1021/je60010a025 . [all data]

Dykyj, 1970
Dykyj, J., Petrochemica, 1970, 10, 2, 51. [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Mathews and Fehlandt, 1931
Mathews, J.H.; Fehlandt, P.R., The heats of vaporization of some organic compounds, J. Am. Chem. Soc., 1931, 53, 3212-32. [all data]

Rex, 1906
Rex, A., Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1906, 55, 355. [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]


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