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Stannane, chlorotrimethyl-


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas-195.4kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -379.8 ± 4.1 kJ/mol for the enthalpy of formation of Sn(Me)3(OH)(cr).

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafliquid-212.5 ± 7.1kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -49.7 ± 2.0 kJ/mol for the enthalpy of formation of Sn(Me)4(l).
Quantity Value Units Method Reference Comment
Deltafsolid-245.6 ± 4.1kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -379.8 ± 4.1 kJ/mol for the enthalpy of formation of Sn(Me)3(OH)(cr).

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltasub50.2kJ/molRSCBaldwin, Lappert, et al., 1972 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

3Stannane, tetramethyl- (l) + Tin(IV) chloride (l) = 4Stannane, chlorotrimethyl- (l)

By formula: 3C4H12Sn (l) + Cl4Sn (l) = 4C3H9ClSn (l)

Quantity Value Units Method Reference Comment
Deltar-184. ± 28.kJ/molRSCNash, Skinner, et al., 1965Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS

Stannane, chlorotrimethyl- (cr) + Water (l) = C3H10OSn (cr) + (Hydrogen chloride bullet 55Water) (solution)

By formula: C3H9ClSn (cr) + H2O (l) = C3H10OSn (cr) + (HCl bullet 55H2O) (solution)

Quantity Value Units Method Reference Comment
Deltar-13.8 ± 0.4kJ/molRSCBaldwin, Lappert, et al., 1972MS

Chlorine anion + Stannane, chlorotrimethyl- = C3H9Cl2Sn-

By formula: Cl- + C3H9ClSn = C3H9Cl2Sn-

Quantity Value Units Method Reference Comment
Deltar131. ± 7.1kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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IR spectrum
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Additional Data

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Owner NIST Standard Reference Data Program
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Sadtler Research Labs Under US-EPA Contract
State gas

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-3022
NIST MS number 231124

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Baldwin, Lappert, et al., 1972
Baldwin, J.C.; Lappert, M.F.; Pedley, J.B.; Poland, J.S., J. Chem. Soc., Dalton Trans., 1972, 1943.. [all data]

Nash, Skinner, et al., 1965
Nash, G.A.; Skinner, H.A.; Stack, W.F., Trans. Faraday Soc., 1965, 61, 640. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Hao, Kaspar, et al., 2005
Hao, C.T.; Kaspar, J.D.; Check, C.E.; Lobring, K.C.; Gilbert, T.M.; Sunderlin, L.S., Effect of substituents on the strength of A-Cl- (A = Si, Ge, and Sn) bonds in hypervalent systems: ACl(5)(-), ACl(4)F(-), and A(CH3)(3)Cl-2(-), J. Phys. Chem. A, 2005, 109, 9, 2026-2034, https://doi.org/10.1021/jp040743x . [all data]


Notes

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