2,6-Octadienal, 3,7-dimethyl-, (Z)-


Normal alkane RI, polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-InnowaxBP-20BP-20InnowaxCarbowax
Column length (m) 30. 50.30.60.
Carrier gas HeliumNitrogenHeliumHeliumHe
Substrate      
Column diameter (mm) 0.25 0.220.250.2
Phase thickness (μm) 0.25 0.250.250.25
Tstart (C) 50.60.60.40.60.
Tend (C) 250.200.220.250.250.
Heat rate (K/min) 5.5.2.6.2.
Initial hold (min) 5.  1.8.
Final hold (min) 10. 20.4.15.
I 1694.1676.1691.1690.1670.
ReferenceMenichini, Tundis, et al., 2011Mishra, Chaudhary, et al., 2010Ottavioli, Bighelli, et al., 2009Seo, Kim, et al., 2009Ferhat, Meklati, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CarbowaxPEG-20MSupelcowax-10CP-Wax 52CBDB-Wax
Column length (m) 60.60.30.30.60.
Carrier gas HeHe He 
Substrate      
Column diameter (mm) 0.20.250.250.320.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.90.40.60.70.
Tend (C) 250.225.250.220.230.
Heat rate (K/min) 2.3.2.3.32.
Initial hold (min) 8.  7.2.
Final hold (min) 15.15.33.3.20.
I 1647.1685.1688.1678.1679.
ReferenceFerhat, Tigrine-Kordjani, et al., 2007Gil A., Van Baren C.M., et al., 2007Sylvestre, Pichette, et al., 2007Hymete, Rohloff, et al., 2006Lan Phi N.T., Nishiyama C., et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxNB-20MDB-WaxCarbowax-PEG
Column length (m) 60.25.30.60.60.
Carrier gas  HeHe Helium
Substrate      
Column diameter (mm) 0.250.250.20.250.20
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 70.100.50.70.60.
Tend (C) 230.250.250.230.250.
Heat rate (K/min) 2.8.2.2.2.
Initial hold (min) 2.  2.8.
Final hold (min) 20.  20.15.
I 1680.1685.1645.1682.1680.
ReferenceLan Phi N.T., Nishiyama C., et al., 2006Lattoo, Dhar, et al., 2006Orav, Raal, et al., 2006Sawamura, Onishi, et al., 2006Tigrine-Kordiani, Meklati, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Supelcowax-10HP-20MStabilwaxStabilwaxInnowax
Column length (m) 30.50.30.30.60.
Carrier gas HeHeliumH2 He
Substrate      
Column diameter (mm) 0.250.200.320.320.25
Phase thickness (μm) 0.250.200.50.50.25
Tstart (C) 50.70.40.40.60.
Tend (C) 250.250.280.280.240.
Heat rate (K/min) 4.4.6.6.5.
Initial hold (min) 1.4.5.5. 
Final hold (min) 10.10.5.5.30.
I 1676.1633.1675.1677.1693.
ReferenceWong, Sivasothy, et al., 2006Bezic, Skocibusic, et al., 2005Jirovetz, Buchbauer, et al., 2005Jirovetz, Buchbauer, et al., 2005, 2Joichi, Yomogida, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-20MDB-WaxDB-WaxSupelcowax-10DB-Wax
Column length (m) 50.60.60.30.60.
Carrier gas HeliumN2N2HeN2
Substrate      
Column diameter (mm) 0.200.250.250.250.25
Phase thickness (μm) 0.200.250.250.250.25
Tstart (C) 70.70.70.50.70.
Tend (C) 180.230.230.220.230.
Heat rate (K/min) 4.2.2.4.2.
Initial hold (min) 4.2.2.3.2.
Final hold (min) 10.20.20.30.20.
I 1641.1686.1686.1675.1698.
ReferenceKulisic, Radonic, et al., 2005Njoroge, Koaze, et al., 2005Njoroge, Koaze, et al., 2005, 2Wong, Lee, et al., 2005Choi, 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxDB-WaxBP-20DB-Wax
Column length (m) 60.60.60.25.60.
Carrier gas N2HeHeN2He
Substrate      
Column diameter (mm) 0.250.250.250.250.32
Phase thickness (μm) 0.25  0.250.25
Tstart (C) 70.60.60.60.35.
Tend (C) 230.220.220.220.220.
Heat rate (K/min) 2.2.2.5.3.
Initial hold (min) 2.4.4.  
Final hold (min) 20.    
I 1696.1676.1676.1688.1691.
ReferenceChoi, 2004, 2Jiang and Kubota, 2004Jiang and Kubota, 2004Mallavarapu, Kulkarni, et al., 2004Palá-Paúl, Brophy, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase NB-20MDB-WaxDB-WaxHP-20MHP-Innowax
Column length (m) 50.60.60.50.50.
Carrier gas He NitrogenHe 
Substrate      
Column diameter (mm) 0.20.250.250.20.2
Phase thickness (μm) 0.250.250.250.20.2
Tstart (C) 50.70.70.70.50.
Tend (C) 250.230.230.180.220.
Heat rate (K/min) 2.2.2.4.4.
Initial hold (min)  2.2.4.5.
Final hold (min)  20. 10. 
I 1680.1697.1697.1641.1682.
ReferenceRaal, Arak, et al., 2004Sawamura, Son, et al., 2004Sawamura, Sou, et al., 2004Juteau, Jerkovic, et al., 2003Stashenko, Jaramillo, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-InnowaxDB-WaxDB-WaxDB-WaxDB-Wax
Column length (m) 50.60.60.60.60.
Carrier gas  N2N2H2N2
Substrate      
Column diameter (mm) 0.20.250.250.320.25
Phase thickness (μm) 0.20.250.250.250.25
Tstart (C) 50.70.70.40.70.
Tend (C) 220.230.230.245.230.
Heat rate (K/min) 4.2.2.1.52.
Initial hold (min) 5.2.2. 2.
Final hold (min)  20.20.20.20.
I 1680.1669.1671.1664.1675.
ReferenceStashenko, Jaramillo, et al., 2003Tu, Onishi, et al., 2003Tu, Onishi, et al., 2003, 2Gancel, Ollé, et al., 2002Tu, Onishi, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxCarbowax 20MBP-20PEG-20M
Column length (m) 60.60.30.50.50.
Carrier gas N2HeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.220.2
Phase thickness (μm) 0.250.250.250.25 
Tstart (C) 70.45.50.60.70.
Tend (C) 230.240.215.230.220.
Heat rate (K/min) 2.3.4.2.2.
Initial hold (min)      
Final hold (min)    35. 
I 1688.1688.1680.1674.1677.
ReferenceTu, Thanh, et al., 2002Christoph, 2001Kasali, Oyedeji, et al., 2001Lota, de Rocca Serra, et al., 2001Orav and Kann, 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxCP-Wax 52CBCP-Wax 52CBDB-WaxBP-20
Column length (m) 60.50.50.60.25.
Carrier gas  HeHeNitrogen 
Substrate      
Column diameter (mm) 0.250.300.300.250.33
Phase thickness (μm) 0.250.250.25 0.5
Tstart (C) 30.40.40.40.80.
Tend (C) 170.220.220.200.220.
Heat rate (K/min) 2.3.3.2.5.
Initial hold (min) 4.5.5.10. 
Final hold (min) 30.    
I 1681.1682.1682.1697.1702.
ReferenceButtery, Light, et al., 2000Chagonda, Makanda, et al., 2000Chagonda, Makanda, et al., 2000Tamura, Boonbumrung, et al., 2000Dunlop, Bignell, et al., 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase FFAPDB-WaxBP-20CP-Wax 52CBDB-Wax
Column length (m) 25.60.25.25.60.
Carrier gas HeHeH2HeH2
Substrate      
Column diameter (mm) 0.20.250.330.320.32
Phase thickness (μm)  0.250.50.20.25
Tstart (C) 70.40.80.60.60.
Tend (C) 210.200.220.240.220.
Heat rate (K/min) 3.2.5.6.3.
Initial hold (min) 10.2. 2. 
Final hold (min)    10. 
I 1695.1676.1702.1673.1674.
ReferenceMockute and Bernotiene, 1999Umano, Nakahara, et al., 1999Bignell, Dunlop, et al., 1998Chisowa, Hall, et al., 1998Werkhoff, Güntert, et al., 1998
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-20BP-20BP-20BP-20BP-20
Column length (m) 25.25.25.25.25.
Carrier gas H2H2H2H2 
Substrate      
Column diameter (mm) 0.330.330.330.330.33
Phase thickness (μm) 0.50.50.50.50.5
Tstart (C) 80.80.80.80.80.
Tend (C) 220.220.220.220.220.
Heat rate (K/min) 5.5.5.5.5.
Initial hold (min)      
Final hold (min)      
I 1702.1702.1702.1702.1702.
ReferenceBignell, Dunlop, et al., 1997Bignell, Dunlop, et al., 1997, 2Bignell, Dunlop, et al., 1997, 3Bignell, Dunlop, et al., 1997, 4Bignell, Dunlop, et al., 1997, 5
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-20DB-WaxSupelcowax-10Carbowax 20MCarbowax 20M
Column length (m) 25.30.30.60.50.
Carrier gas H2H2HeHeHe
Substrate      
Column diameter (mm) 0.330.320.530.250.25
Phase thickness (μm) 0.50.51.0.25 
Tstart (C) 80.40.80.50.60.
Tend (C) 220.220.210.150.180.
Heat rate (K/min) 5.4.3.2.2.
Initial hold (min)    10.4.
Final hold (min)    20. 
I 1702.1692.1630.1705.1649.
ReferenceBignell, Dunlop, et al., 1997, 6Lebossé, Ducruet, et al., 1997Nishimura, 1995Tirado, Stashenko, et al., 1995Kawakami, Kobayashi, et al., 1993
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryPackedPacked
Active phase Carbowax 20MCarbowax 20MCarbowax 20MCarbowax 20MCarbowax 20M
Column length (m) 50.100.100.2.2.
Carrier gas He  HydrogenHydrogen
Substrate    Gas-Chrom Z (80-100 mesh)Gas-Chrom Z (80-100 mesh)
Column diameter (mm) 0.250.250.25  
Phase thickness (μm)      
Tstart (C) 60.70.70.65.65.
Tend (C) 180.170.170.220.220.
Heat rate (K/min) 2.1.1.4.4.
Initial hold (min) 4.    
Final hold (min)      
I 1649.1679.1680.1696.1699.
ReferenceKawakami and Kobayashi, 1991Shibamoto and Jennings, 1977Shibamoto and Jennings, 1977Stancher and Pertoldi, 1967Stancher and Pertoldi, 1967
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Normal alkane RI, polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Tu, Onishi, et al., 2003, 2
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Gancel, Ollé, et al., 2002
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Notes

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