2,6-Octadien-1-ol, 3,7-dimethyl-, (Z)-

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Normal alkane RI, polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-InnowaxBP-20BP-20InnowaxHP-Innowax
Column length (m) 30. 50.30.30.
Carrier gas HeliumNitrogenHeliumHeliumNitrogen
Substrate      
Column diameter (mm) 0.25 0.220.250.25
Phase thickness (μm) 0.25 0.250.250.52
Tstart (C) 50.60.60.40.35.
Tend (C) 250.200.220.250.205.
Heat rate (K/min) 5.5.2.6.3.
Initial hold (min) 5.  1.10.
Final hold (min) 10. 20.4.10.
I 1797.1801.1804.1811.1797.
ReferenceMenichini, Tundis, et al., 2011Mishra, Chaudhary, et al., 2010Ottavioli, Bighelli, et al., 2009Seo, Kim, et al., 2009Wannes, Mhamdi, et al., 2009
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxHP-InnowaxCarbowaxCarbowaxBP-20
Column length (m) 30.50.60.60.30.
Carrier gas HeliumHeliumHeHeHe
Substrate      
Column diameter (mm) 0.250.200.20.20.25
Phase thickness (μm) 0.250.200.250.250.25
Tstart (C) 40.45.60.60.70.
Tend (C) 230.190.250.250.220.
Heat rate (K/min) 3.4.2.2.4.
Initial hold (min) 2.2.8.8.4.
Final hold (min) 5.50.15.15.5.
I 1797.1803.1781.1752.1808.
ReferenceZhao, Xu, et al., 2009Soria, Sanz, et al., 2008Ferhat, Meklati, et al., 2007Ferhat, Tigrine-Kordjani, et al., 2007Rawat, Gulati, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-20DB-WaxDB-WaxDB-WaxBP-20
Column length (m) 30.60.30.60.50.
Carrier gas HeHeHeliumHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.22
Phase thickness (μm) 0.250.250.250.50.25
Tstart (C) 70.60.40.50.60.
Tend (C) 220.180.250.230.220.
Heat rate (K/min) 4.3.3.3.2.
Initial hold (min) 4.8. 2. 
Final hold (min) 5.80.20.20.20.
I 1807.1799.1757.1795.1790.
ReferenceRawat, Gulati, et al., 2007Wei A. and Shibamoto T., 2007Berlinet, Brat, et al., 2006Cai, Lin, et al., 2006Fanciullino, Tomi, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-Wax EtrDB-WaxDB-WaxHP-20MNB-20M
Column length (m) 60.60.25.50.30.
Carrier gas He HeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.20.2
Phase thickness (μm) 0.250.250.250.20.25
Tstart (C) 40.70.100.70.50.
Tend (C) 230.230.250.180.250.
Heat rate (K/min) 2.2.8.4.2.
Initial hold (min) 5.2. 4. 
Final hold (min) 100.20. 15. 
I 1811.1796.1830.1752.1806.
ReferenceIbarz, Ferreira, et al., 2006Lan Phi N.T., Nishiyama C., et al., 2006Lattoo, Dhar, et al., 2006Mastelic, Jerkovic, et al., 2006Orav, Raal, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-Wax EtrDB-WaxSupelcowax-10Supelcowax-10Carbowax 20M
Column length (m) 30.60.30.30.60.
Carrier gas He HeHeN2
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.70.50.50.40.
Tend (C) 220.230.220.250.190.
Heat rate (K/min) 2.2.4.4.10.
Initial hold (min) 1.2.1.1.2.
Final hold (min) 10.20.10.10.15.
I 1827.1800.1801.1749.1757.
ReferencePerestrelo, Fernandes, et al., 2006Sawamura, Onishi, et al., 2006Wong, Lim, et al., 2006Wong, Sivasothy, et al., 2006Babu and Kaul, 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-20MStabilwaxStabilwaxInnowaxHP-20M
Column length (m) 50.30.30.60.50.
Carrier gas HeliumH2 HeHelium
Substrate      
Column diameter (mm) 0.200.320.320.250.20
Phase thickness (μm) 0.200.50.50.250.20
Tstart (C) 70.40.40.60.70.
Tend (C) 250.280.280.240.180.
Heat rate (K/min) 4.6.6.5.4.
Initial hold (min) 4.5.5. 4.
Final hold (min) 10.5.5.30.10.
I 1752.1783.1783.1798.1752.
ReferenceBezic, Skocibusic, et al., 2005Jirovetz, Buchbauer, et al., 2005Jirovetz, Buchbauer, et al., 2005, 2Joichi, Yomogida, et al., 2005Kulisic, Radonic, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxSupelcowax-10Supelcowax-10SW-10
Column length (m) 30.60.30.30.50.
Carrier gas HeN2 HeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.20
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.70.40.50.50.
Tend (C) 180.230.220.220.230.
Heat rate (K/min) 3.2.3.4.2.
Initial hold (min)  2.5.3. 
Final hold (min) 40.20.10.30. 
I 1797.1835.1797.1788.1790.
ReferenceLee, Umano, et al., 2005Njoroge, Koaze, et al., 2005Vichi, Riu-Aumatell, et al., 2005Wong and Tan, 2005Raal, Paaver, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxHP-20MHP-20MHP-Innowax
Column length (m) 60.60.50.50.50.
Carrier gas  NitrogenHeHe 
Substrate      
Column diameter (mm) 0.250.250.20.20.2
Phase thickness (μm) 0.250.250.20.20.2
Tstart (C) 70.70.70.70.50.
Tend (C) 230.230.180.180.220.
Heat rate (K/min) 2.2.4.4.4.
Initial hold (min) 2.2.4.4.5.
Final hold (min) 20. 10.10. 
I 1814.1814.1758.1752.1755.
ReferenceSawamura, Son, et al., 2004Sawamura, Sou, et al., 2004Juteau, Jerkovic, et al., 2003Mastelic and Jerkovic, 2003Stashenko, Jaramillo, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-InnowaxInnowaxDB-WaxDB-WaxDB-Wax
Column length (m) 50.60.60.60.60.
Carrier gas  HeN2N2H2
Substrate      
Column diameter (mm) 0.20.250.250.250.32
Phase thickness (μm) 0.2 0.250.250.25
Tstart (C) 50.60.70.70.40.
Tend (C) 220.220.230.230.245.
Heat rate (K/min) 4.4.2.2.1.5
Initial hold (min) 5.10.2.2. 
Final hold (min)  10.20.20.20.
I 1755.1808.1830.1787.1796.
ReferenceStashenko, Jaramillo, et al., 2003Suleimenov, Atazharova, et al., 2003Tu, Onishi, et al., 2003Tu, Onishi, et al., 2003, 2Gancel, Ollé, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Supelcowax-10DB-WaxDB-WaxCarbowax 20MBP-20
Column length (m) 60.60.60.30.50.
Carrier gas HeN2HeHeHe
Substrate      
Column diameter (mm) 0.20.250.250.250.22
Phase thickness (μm) 0.50.250.250.250.25
Tstart (C) 70.70.45.50.60.
Tend (C) 220.230.240.215.230.
Heat rate (K/min) 2.2.3.4.2.
Initial hold (min)  2.   
Final hold (min)  20.  35.
I 1800.1837.1797.1757.1790.
ReferenceOrav, Kailas, et al., 2002Tu, Onishi, et al., 2002Christoph, 2001Kasali, Oyedeji, et al., 2001Lota, de Rocca Serra, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Supelcowax-10BP-20DB-WaxSupelcowax-10Innowax
Column length (m) 60.25.60.30.60.
Carrier gas HeNitrogenNitrogen He
Substrate      
Column diameter (mm) 0.250.500.250.250.25
Phase thickness (μm) 0.250.25 0.250.25
Tstart (C) 60.60.40.60.60.
Tend (C) 280.200.200.220.220.
Heat rate (K/min) 4.5.2.4. 
Initial hold (min)   10. 10.
Final hold (min)      
I 1755.1751.1811.1783.1808.
ReferenceKorány, Mednyánszky, et al., 2000Mallavarapu, Rao, et al., 2000Tamura, Boonbumrung, et al., 2000Choo, Wong, et al., 1999Kaya, Baser, et al., 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase FFAPDB-WaxDB-WaxCarbowax 20MHP-Innowax
Column length (m) 25.60.60.60.25.
Carrier gas HeHeHeHe 
Substrate      
Column diameter (mm) 0.20.250.250.320.32
Phase thickness (μm)  0.250.250.5 
Tstart (C) 70.60.40.40.35.
Tend (C) 210.240.200.190.250.
Heat rate (K/min) 3.4.2.2.4.
Initial hold (min) 10. 2.5. 
Final hold (min)      
I 1818.1794.1801.1809.1796.
ReferenceMockute and Bernotiene, 1999Ngassoum, Yonkeu, et al., 1999Umano, Nakahara, et al., 1999Ferreira, Ardanuy, et al., 1998Ong and Acree, 1998
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-InnowaxHP-Innowax FSCPEG-20MTC-WaxSupelcowax-10
Column length (m) 60.60.60.60.60.
Carrier gas HeHeHe He
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.25  0.25
Tstart (C) 50.60.70.80.40.
Tend (C) 220.220.210.240.200.
Heat rate (K/min) 5.4.3.3.3.
Initial hold (min) 5.10. 5.3.
Final hold (min)  10.  30.
I 1757.1808.1798.1798.1817.
ReferenceStashenko, Cervantes, et al., 1998Tümen, Baser, et al., 1998Awano, Honda, et al., 1997Shuichi, Masazumi, et al., 1996Wong and Lai, 1996
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Carbowax 20MSupelcowax-10DB-WaxCarbowax 20MDB-Wax
Column length (m) 60.30.60.60.30.
Carrier gas  HeHeHeHe
Substrate      
Column diameter (mm) 0.250.530.250.250.25
Phase thickness (μm)  1.0.250.25 
Tstart (C) 60.80.50.50.60.
Tend (C) 180.210.180.150.240.
Heat rate (K/min) 2.3.2.52.3.
Initial hold (min) 4. 5.10.10.
Final hold (min)    20. 
I 1766.1753.1780.1832.1775.
ReferenceKawakami, Ganguly, et al., 1995Nishimura, 1995Stashenko, Torres, et al., 1995Tirado, Stashenko, et al., 1995Hatsuko, Kazuko, et al., 1992
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryPacked
Active phase Carbowax 20MFFAPCarbowax 20MCarbowax 20M
Column length (m) 50.50.50.2.
Carrier gas He  Hydrogen
Substrate    Gas-Chrom Z (80-100 mesh)
Column diameter (mm) 0.25 0.32 
Phase thickness (μm)     
Tstart (C) 60.50.70.65.
Tend (C) 180.180.180.220.
Heat rate (K/min) 2.10.2.4.
Initial hold (min) 4.1.  
Final hold (min)     
I 1766.1807.1773.1772.
ReferenceKawakami and Kobayashi, 1991Brophy, Davies, et al., 1989Engel and Tressl, 1983Stancher and Pertoldi, 1967
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Normal alkane RI, polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Menichini, Tundis, et al., 2011
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Lee, Umano, et al., 2005
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Notes

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