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Oxacyclohexadecan-2-one

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tfus310.2KN/AVoitkevich and Lyubshits, 1957Uncertainty assigned by TRC = 1. K; TRC
Tfus310.15KN/ASerpinskii, Voitkevich, et al., 1954Uncertainty assigned by TRC = 0.6 K; TRC
Quantity Value Units Method Reference Comment
Ttriple308.5KN/AEvstropov, Lebedev, et al., 1983Crystal phase 1 phase; Uncertainty assigned by TRC = 0.1 K; TRC
Ttriple308.5KN/ALebedev, Evstropov, et al., 1981Crystal phase 1 phase; Uncertainty assigned by TRC = 1. K; TRC
Ttriple308.5KN/ALebedev, Evstropov, et al., 1979Crystal phase 1 phase; Uncertainty assigned by TRC = 0.1 K; TRC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
78.2378.AStephenson and Malanowski, 1987Based on data from 363. - 443. K.; AC
74.2315.A,MEStephenson and Malanowski, 1987Based on data from 310. - 320. K. See also Serpinskii, Voitkevich, et al., 1954, 2.; AC

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
81.3300.MEStephenson and Malanowski, 1987Based on data from 290. - 310. K. See also Jones, 1960 and Serpinskii, Voitkevich, et al., 1954, 2.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Method Reference Comment
6.99308.5ACPitzer, Peiper, et al., 1984Based on data from 10. - 370. K. See also Lebedev, Yevstropov, et al., 1981.; AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
96.47283.Domalski, Evans, et al., 1984CAL
22.65308.5

Enthalpy of phase transition

DeltaHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
27.300282.98crystaline, IIcrystaline, IYevstropov, Lebedev, et al., 1983DH
6.980308.5crystaline, IliquidYevstropov, Lebedev, et al., 1983DH
0.193.crystaline, I''crystaline, I'Yevstropov, Lebedev, et al., 1983DH
27.301282.98crystaline, IIcrystaline, ILebedev, Yevstropov, et al., 1981, 2DH
6.979308.5crystaline, IliquidLebedev, Yevstropov, et al., 1981, 2DH

Entropy of phase transition

DeltaStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
96.3282.98crystaline, IIcrystaline, IYevstropov, Lebedev, et al., 1983DH
22.6308.5crystaline, IliquidYevstropov, Lebedev, et al., 1983DH
0.193.crystaline, I''crystaline, I'Yevstropov, Lebedev, et al., 1983DH
96.2282.98crystaline, IIcrystaline, ILebedev, Yevstropov, et al., 1981, 2DH
22.6308.5crystaline, IliquidLebedev, Yevstropov, et al., 1981, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Voitkevich and Lyubshits, 1957
Voitkevich, S.A.; Lyubshits, N.Yu., Maslob-Zhir. Prom-st., 1957, No. 4, 20. [all data]

Serpinskii, Voitkevich, et al., 1954
Serpinskii, V.V.; Voitkevich, S.A.; Lyuboshits, N.Y., Zh. Fiz. Khim., 1954, 28, 1969. [all data]

Evstropov, Lebedev, et al., 1983
Evstropov, A.A.; Lebedev, B.V.; Kiparisova, E.G., Thermodynamics of pentadecanolactone, its polymerization, and the resulting polypentadecanolactone in the 0-400 K region, Vysokomol. Soedin., Ser. A, 1983, 25, 1679-1685. [all data]

Lebedev, Evstropov, et al., 1981
Lebedev, B.V.; Evstropov, A.A.; Kiparisova, Ye.G., Thermodynamics of undecanolactone, tridecanolactone, and pentadecanolactone from 0 to 340 K, J. Chem. Thermodyn., 1981, 13, 1185. [all data]

Lebedev, Evstropov, et al., 1979
Lebedev, B.V.; Evstropov, A.A.; Shurygina, A.M., Heat capacity and thermodynamic properties of pentadecanolactone in the O-3 30 K range, Termodin. Org. Soedin. (USSR), 1979, 1979, 5. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Serpinskii, Voitkevich, et al., 1954, 2
Serpinskii, V.V.; Voitkevich, S.A.; Lyuboshits, N.Y., Zh. Fiz. Khim., 1954, 28, 810. [all data]

Jones, 1960
Jones, A.H., Sublimation Pressure Data for Organic Compounds., J. Chem. Eng. Data, 1960, 5, 2, 196-200, https://doi.org/10.1021/je60006a019 . [all data]

Pitzer, Peiper, et al., 1984
Pitzer, Kenneth S.; Peiper, J. Christopher; Busey, R.H., Thermodynamic Properties of Aqueous Sodium Chloride Solutions, J. Phys. Chem. Ref. Data, 1984, 13, 1, 1, https://doi.org/10.1063/1.555709 . [all data]

Lebedev, Yevstropov, et al., 1981
Lebedev, B.V.; Yevstropov, A.A.; Kiparisova, Ye.G., Thermodynamics of undecanolactone, tridecanolactone, and pentadecanolactone from 0 to 340 K, J. Chem. Thermodyn., 1981, 13, 1185-1204. [all data]

Domalski, Evans, et al., 1984
Domalski, E.S.; Evans, W.H.; Hearing, E.D., J. Phys. Chem. Ref. Data, suppl. 1, 1984. [all data]

Yevstropov, Lebedev, et al., 1983
Yevstropov, A.A.; Lebedev, B.V.; Krparisova, Ye.G., Thermodynamics of pentadecanolactone, of the process of its polymerization and of the resultant polypentadecanolactone in the 0 to 400 K region, Vysokomol. Soedin, Ser., 1983, A 25(8), 1679-1685. [all data]

Lebedev, Yevstropov, et al., 1981, 2
Lebedev, B.V.; Yevstropov, A.A.; Kiparisova, Y.G., Thermodynamic properties of undecanolactone over the range, 1981, Termodin. [all data]


Notes

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