Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Caffeic acid, 3TMS derivative


Van Den Dool and Kratz RI, non-polar column, temperature ramp

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5DB-5DB-5PE-5ht
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (mum) 0.250.250.250.250.1
Tstart (C) 50.50.50.50.50.
Tend (C) 320.320.320.320.320.
Heat rate (K/min) 3.3.3.3.3.
Initial hold (min)      
Final hold (min)      
I 2155.2158.2158.2159.2158.
ReferenceJaroszynska and Ligor, 2005Jaroszynska and Ligor, 2005Jaroszynska and Ligor, 2005Jaroszynska and Ligor, 2005Jaroszynska and Ligor, 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase PE-5htPE-5htPE-5htPE-5msPE-5ms
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (mum) 0.10.10.10.250.25
Tstart (C) 50.50.50.50.50.
Tend (C) 320.320.320.320.320.
Heat rate (K/min) 3.3.3.3.3.
Initial hold (min)      
Final hold (min)      
I 2163.2167.2167.2136.2136.
ReferenceJaroszynska and Ligor, 2005Jaroszynska and Ligor, 2005Jaroszynska and Ligor, 2005Jaroszynska and Ligor, 2005Jaroszynska and Ligor, 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5MSPE-5DB-5DB-5DB-5
Column length (m) 10.30.30.30.30.
Carrier gas  HeHeHeHe
Substrate      
Column diameter (mm) 0.180.250.250.250.25
Phase thickness (mum) 0.18 0.250.250.25
Tstart (C) 70.50.50.50.50.
Tend (C) 320.250.240.240.240.
Heat rate (K/min) 40.5.3.3.7.
Initial hold (min) 2.    
Final hold (min) 2.    
I 2136.52152.2152.2158.2152.
ReferenceJonsson, Johansson, et al., 2005Isidorov and Vinogorova, 2003Jaroszynska, 2003Jaroszynska, 2003Jaroszynska, 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryPackedPacked
Active phase DB-5OV-1OV-1
Column length (m) 30.2.2.
Carrier gas HeN2He
Substrate  SupelcoportChromosorb W HP (80-100 mesh)
Column diameter (mm) 0.25  
Phase thickness (mum) 0.25  
Tstart (C) 50.80.100.
Tend (C) 240.240.325.
Heat rate (K/min) 7.4.10.
Initial hold (min)    
Final hold (min)    
I 2158.2143.2141.
ReferenceJaroszynska, 2003Mattsson and Petersson, 1977Butts, 1972
Comment MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jaroszynska and Ligor, 2005
Jaroszynska, J.; Ligor, T., The identification of phenolic compounds by a gas chromatographic method on three capillary columns with the same non-polar stationary phase, Anal. Chim. Acta., 2005, 539, 1-2, 11-15, https://doi.org/10.1016/j.aca.2005.03.024 . [all data]

Jonsson, Johansson, et al., 2005
Jonsson, P.; Johansson, A.I.; Gullberg, J.; Trygg, J.; Jiye, A.; Grung, B.; Marklund, S.; Sjöström, M.; Antti, H.; Moritz, T., High-throughput data analysis for detecting and identifying differences between samples in GC/MS-based metabolomic analyses, Anal. Chem., 2005, 77, 17, 5635-5642, https://doi.org/10.1021/ac050601e . [all data]

Isidorov and Vinogorova, 2003
Isidorov, V.A.; Vinogorova, V.T., GC-MS analysis of compounds extracted from buds of Populus balsamifera and Populus nigra, Z. Naturforsch. C:, 2003, 58, 355-360. [all data]

Jaroszynska, 2003
Jaroszynska, J., Isolation of free phenolic compounds from arboreal leaves by use of the Florisil/C18 system, Anal. Bioanal. Chem., 2003, 377, 4, 702-708, https://doi.org/10.1007/s00216-003-2155-z . [all data]

Mattsson and Petersson, 1977
Mattsson, M.; Petersson, G., Reference GLC Data for the Analysis of Phenolic Compounds as Trimethylsilyl Derivatives, J. Chromatogr. Sci., 1977, 15, 12, 546-554, https://doi.org/10.1093/chromsci/15.12.546 . [all data]

Butts, 1972
Butts, W.C., Two-Column Gas Chromatography of Trimethylsilyl Derivatives of Biochemically Significant Compounds, Anal. Biochemistry, 1972, 46, 1, 187-199, https://doi.org/10.1016/0003-2697(72)90411-3 . [all data]


Notes

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References