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Diethyl carbonate

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Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

DeltavapH° (kJ/mol) Method Reference Comment
43.6N/AMajer and Svoboda, 1985 
44.4 ± 0.2GSKozlova, Emel'yanenko, et al., 2008Based on data from 273. - 315. K.; AC
43.6 ± 0.2CCounsell and Lee, 1973AC
43.60 ± 0.15VMansson, 1972ALS
43.6N/AMansson, 1972DRB
39.1VChoi and Joncich, 1971Pedley's value is off by 10.19kcal/mol; ALS
81.8N/AChoi and Joncich, 1971DRB

References

Go To: Top, Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Kozlova, Emel'yanenko, et al., 2008
Kozlova, Svetlana A.; Emel'yanenko, Vladimir N.; Georgieva, Miglena; Verevkin, Sergey P.; Chernyak, Yury; Schäffner, Benjamin; Börner, Armin, Vapour pressure and enthalpy of vaporization of aliphatic dialkyl carbonates, The Journal of Chemical Thermodynamics, 2008, 40, 7, 1136-1140, https://doi.org/10.1016/j.jct.2008.02.012 . [all data]

Counsell and Lee, 1973
Counsell, J.F.; Lee, D.A., Thermodynamic properties of organic oxygen compounds 31. Vapour heat capacity and enthalpy of vaporization of methanol, The Journal of Chemical Thermodynamics, 1973, 5, 4, 583-589, https://doi.org/10.1016/S0021-9614(73)80107-7 . [all data]

Mansson, 1972
Mansson, M., Enthalpies of combustion and formation of ethyl propionate and diethyl carbonate, J. Chem. Thermodyn., 1972, 4, 865-871. [all data]

Choi and Joncich, 1971
Choi, J.K.; Joncich, M.J., Heats of combustion, heats of formation and vapor pressures of some organic carbonates. Estimation of carbonate group contribution to heat of formation, J. Chem. Eng. Data, 1971, 16, 87-90. [all data]


Notes

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