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Diethyl carbonate

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil399.6 ± 0.8KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Deltavap12. ± 6.kcal/molAVGN/AAverage of 7 values; Individual data points

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
10.1359.EBXing, Fang, et al., 2009Based on data from 344. - 398. K.; AC
9.49367.N/ARodríguez, Canosa, et al., 2002Based on data from 352. - 403. K.; AC
9.78323.AStephenson and Malanowski, 1987Based on data from 308. - 400. K.; AC
9.35308. - 368.MMChoi and Joncich, 1971AC
10.6278.N/AStull, 1947Based on data from 263. - 399. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
263.1 - 399.04.770451721.904-37.959Stull, 1947Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Method Reference Comment
2.21198.2DSCDing, 2004AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Xing, Fang, et al., 2009
Xing, Yan; Fang, Wenjun; Li, Dan; Guo, Yongsheng; Lin, Ruisen, Density, Viscosity, and Vapor Pressure for Binary Mixtures of Tricyclo [5.2.1.0 2.6 ] Decane and Diethyl Carbonate, J. Chem. Eng. Data, 2009, 54, 6, 1865-1870, https://doi.org/10.1021/je800984q . [all data]

Rodríguez, Canosa, et al., 2002
Rodríguez, A.; Canosa, J.; Domínguez, A.; Tojo, J., Isobaric Vapor-Liquid Equilibria of Diethyl Carbonate with Four Alkanes at 101.3 kPa, J. Chem. Eng. Data, 2002, 47, 5, 1098-1102, https://doi.org/10.1021/je010260b . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Choi and Joncich, 1971
Choi, J.K.; Joncich, M.J., Heats of combustion, heats of formation and vapor pressures of some organic carbonates. Estimation of carbonate group contribution to heat of formation, J. Chem. Eng. Data, 1971, 16, 87-90. [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Ding, 2004
Ding, Michael S., Liquid-Solid Phase Equilibria and Thermodynamic Modeling for Binary Organic Carbonates, J. Chem. Eng. Data, 2004, 49, 2, 276-282, https://doi.org/10.1021/je034134e . [all data]


Notes

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