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Quinoline, 5,6,7,8-tetrahydro-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil491.2KN/AAldrich Chemical Company Inc., 1990BS
Tboil495.2KN/AWeast and Grasselli, 1989BS
Quantity Value Units Method Reference Comment
Tfus222.634KN/ASteele, Chirico, et al., 1986DH
Quantity Value Units Method Reference Comment
Ttriple222.630KN/ASteele, Chirico, et al., 1989Crystal phase 1 phase; Uncertainty assigned by TRC = 0.01 K; TRC
Quantity Value Units Method Reference Comment
Deltavap57.56kJ/molVSteele, Chirico, et al., 1989, 2ALS
Deltavap57.6kJ/molN/ASteele, Chirico, et al., 1989, 2DRB
Deltavap57.6 ± 0.2kJ/molIP,EBSteele, Chirico, et al., 1989, 2Based on data from 303. - 544. K.; AC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
366.70.016Weast and Grasselli, 1989BS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
56.1 ± 0.1320.IP,EBSteele, Chirico, et al., 1989, 2Based on data from 303. - 544. K.; AC
53.6 ± 0.1360.IP,EBSteele, Chirico, et al., 1989, 2Based on data from 303. - 544. K.; AC
51.1 ± 0.1400.IP,EBSteele, Chirico, et al., 1989, 2Based on data from 303. - 544. K.; AC
48.7 ± 0.3440.IP,EBSteele, Chirico, et al., 1989, 2Based on data from 303. - 544. K.; AC
46.2 ± 0.4480.IP,EBSteele, Chirico, et al., 1989, 2Based on data from 303. - 544. K.; AC
43.5 ± 0.5520.IP,EBSteele, Chirico, et al., 1989, 2Based on data from 303. - 544. K.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
9.08222.7Acree, 1991AC

Enthalpy of phase transition

DeltaHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
9.0717222.634crystaline, IliquidSteele, Chirico, et al., 1989, 3DH

Entropy of phase transition

DeltaStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
40.75222.634crystaline, IliquidSteele, Chirico, et al., 1989, 3DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Steele, Chirico, et al., 1986
Steele, W.V.; Chirico, R.D.; Collier, W.B.; Hossenlopp, I.A.; Nguyen, A.; Strube, M.M., Thermochemical and thermophysical properties of organic nitrogen compounds found in fossil materials, NIPER Report, 1986, 188, 112p. [all data]

Steele, Chirico, et al., 1989
Steele, W.V.; Chirico, R.D.; Hossenlopp, I.A.; Nguyen, A.; Smith, N.K.; Gammon, B.E., The thermodynamic properties of 1,2,3,4- and 5,6,7,8-tetrahydroquinolines, J. Chem. Thermodyn., 1989, 21, 1121. [all data]

Steele, Chirico, et al., 1989, 2
Steele, W.V.; Chirico, R.D.; Hossenlopp, I.A.; Nguyen, A.; Smith, N.K.; Gammon, B.E., The thermodynamic properties of 1,2,3,4- and 5,6,7,8-tetrahydroquinolines, J. Chem. Thermodyn., 1989, 21, 1121-1149. [all data]

Acree, 1991
Acree, William E., Thermodynamic properties of organic compounds: enthalpy of fusion and melting point temperature compilation, Thermochimica Acta, 1991, 189, 1, 37-56, https://doi.org/10.1016/0040-6031(91)87098-H . [all data]

Steele, Chirico, et al., 1989, 3
Steele, W.V.; Chirico, R.D.; Hossenlopp, I.A.; Nguyen, A.; Smith, N.K.; Gammon, B.E., The thermodynamic properties of the five benzoquinolines, J. Chem. Thermodyn., 1989, 21, 81-107. [all data]


Notes

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