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strontium chloride

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Deltafgas-473.21kJ/molReviewChase, 1998Data last reviewed in December, 1972
Quantity Value Units Method Reference Comment
gas,1 bar316.34J/mol*KReviewChase, 1998Data last reviewed in December, 1972

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 3000. - 6000.
A 58.10781
B 0.079950
C -0.021715
D 0.001855
E -0.210803
F -491.2476
G 385.4468
H -473.2104
ReferenceChase, 1998
Comment Data last reviewed in December, 1972

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Deltafliquid-805.35kJ/molReviewChase, 1998Data last reviewed in December, 1972
Quantity Value Units Method Reference Comment
liquid,1 bar135.82J/mol*KReviewChase, 1998Data last reviewed in December, 1972
Quantity Value Units Method Reference Comment
Deltafsolid-828.85kJ/molReviewChase, 1998Data last reviewed in December, 1972
Quantity Value Units Method Reference Comment
solid114.81J/mol*KReviewChase, 1998Data last reviewed in December, 1972

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 1147. - 3000.
A 104.6000
B 4.193874×10-8
C -1.833062×10-8
D 2.682757×10-9
E 6.966110×10-9
F -847.5361
G 239.6884
H -805.3531
ReferenceChase, 1998
Comment Data last reviewed in December, 1972

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. - 1000.1000. - 1147.
A 54.42882123.0100
B 113.7676-0.000006
C -177.44970.000003
D 115.0826-5.560327×10-7
E -0.003286-8.034954×10-7
F -848.8081-884.8742
G 153.6084223.0210
H -828.8504-828.8504
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1972 Data last reviewed in December, 1972

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus1146.KN/ADworkin and Bredig, 1963Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Deltasub328.9 ± 4.8kJ/molLELoehman, Kent, et al., 1965AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
9.8SEmons, Kiessling, et al., 1982LBLHLM
10.49 ± 0.04PELee and Potts, 1979LLK
9.70 ± 0.10EIHildenbrand, 1970RDSH
10.5 ± 1.0EIHildenbrand, 1970, 2RDSH
10.2PEHammer, Allen, et al., 1978Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
ClSr+10.2ClSEmons, Kiessling, et al., 1982LBLHLM
SrCl+10.48 ± 0.10ClEIHildenbrand, 1970RDSH
SrCl+10.7 ± 0.3ClEIHildenbrand, 1970, 2RDSH
Sr+14.6Cl2SEmons, Kiessling, et al., 1982LBLHLM

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Dworkin and Bredig, 1963
Dworkin, A.S.; Bredig, M.A., Heat Content and Entropy or Strontium CHloride from 298 to 1200 K, J. Chem. Eng. Data, 1963, 8, 416-7. [all data]

Loehman, Kent, et al., 1965
Loehman, R.E.; Kent, R.A.; Margrave, J.L., Vaporization and Sublimation of SrCl 2 ., J. Chem. Eng. Data, 1965, 10, 3, 296-297, https://doi.org/10.1021/je60026a028 . [all data]

Emons, Kiessling, et al., 1982
Emons, H.-H.; Kiessling, D.; Horlbeck, W., Dampfdruckmessungen und massenspektrometrische untersuchungen der gasphase uber erdalkalimetallhalogeniden, Z. Anorg. Allg. Chem., 1982, 488, 219. [all data]

Lee and Potts, 1979
Lee, E.P.F.; Potts, A.W., An investigation of the valence shell electronic structure of alkaline earth halides by using Ab initio S. C. F. calculations and photoelectron spectroscopy, Proc. R. Soc. London A:, 1979, 365, 395. [all data]

Hildenbrand, 1970
Hildenbrand, D.L., Electron impact studies of the IIA metal chlorides, Intern. J. Mass Spectrom. Ion Phys., 1970, 4, 75. [all data]

Hildenbrand, 1970, 2
Hildenbrand, D.L., Dissociation energies and chemical bonding in the alkaline-earth chlorides from mass spectrometric studies, J. Chem. Phys., 1970, 52, 5751. [all data]

Hammer, Allen, et al., 1978
Hammer, C.A.; Allen, J.D., Jr.; Cusachs, L.C.; Schweitzer, G.K., The high-temperature photoelectron spectra of alkaline-earth chlorides and iodides, J. Electron Spectrosc. Relat. Phenom., 1978, 13, 149. [all data]


Notes

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