1-Hexanol, 2-ethyl-

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Normal alkane RI, polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-FFAPHP-FFAPHP-FFAPHP-InnowaxVF-Wax MS
Column length (m) 25.25.25.60.60.
Carrier gas HeliumHeliumHeliumHeliumHelium
Substrate      
Column diameter (mm) 0.320.320.320.250.25
Phase thickness (μm) 0.500.500.500.250.25
Tstart (C) 45.45.45.60.60.
Tend (C) 220.220.220.220.220.
Heat rate (K/min) 15.15.15.3.3.
Initial hold (min)    1.5.
Final hold (min)    5.25.
I 1502.1503.1503.1490.1486.
ReferenceWanakhachornkrai and Lertsiri, 9999Wanakhachornkrai and Lertsiri, 9999Wanakhachornkrai and Lertsiri, 9999Feng, Zhuang, et al., 2011Duarte, Dias, et al., 2010
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxCP-WaxDB-WaxInnowaxStabilwax
Column length (m) 30.60.30.30.60.
Carrier gas HydrogenHeliumHelium Helium
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 30.50.40.40.40.
Tend (C) 230.230.230.200.240.
Heat rate (K/min) 8.6.3.10.3.
Initial hold (min) 5.2.2.5.5.
Final hold (min) 10.15.5.15.10.
I 1483.1462.1488.1503.1484.
ReferenceKarlsson, Birgersson, et al., 2009Mo, Fan, et al., 2009Zhao, Xu, et al., 2009Kaypak and Avsar, 2008Cros, Vandanjon, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxBP-20DB-WaxDB-WaxHP-Innowax
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeN2He
Substrate      
Column diameter (mm) 0.320.250.320.320.25
Phase thickness (μm) 0.50.250.250.250.5
Tstart (C) 40.70.40.40.40.
Tend (C) 240.220.230.230.200.
Heat rate (K/min) 5.4.4.6.2.
Initial hold (min)  4.2.2.3.
Final hold (min)  5.15.15.15.
I 1501.1494.1474.1495.1472.
ReferenceDury-Brun, Fournier, et al., 2007Rawat, Gulati, et al., 2007Fan and Qian, 2006Fan and Qian, 2006, 2Komes, Ulrich, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-Wax EtrZB-WaxZB-WaxZB-WaxDB-Wax
Column length (m) 30.60.30.30.60.
Carrier gas HeHeHeliumHe 
Substrate      
Column diameter (mm) 0.250.320.320.320.25
Phase thickness (μm) 0.250.50.250.250.5
Tstart (C) 40.40.40.40.35.
Tend (C) 220.250.250.250.240.
Heat rate (K/min) 2.3.5.5.4.
Initial hold (min) 1.2.2.2.5.
Final hold (min) 10.10.5.10.10.
I 1515.1505.1476.1476.1512.
ReferencePerestrelo, Fernandes, et al., 2006Wierda R.L., Fletcher G., et al., 2006N/AWu, Krings, et al., 2005Chida, Sone, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxStabilwaxDB-WaxDB-WaxDB-Wax
Column length (m) 60.60.60.30.30.
Carrier gas HeHeliumH2HeHe
Substrate      
Column diameter (mm) 0.250.250.320.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.40.40.40.50.
Tend (C) 220.240.230.185.230.
Heat rate (K/min) 3.3.4.4.3.
Initial hold (min) 5.5.5.4.2.
Final hold (min)  10.25.20.20.
I 1499.1484.1490.1487.1495.
ReferenceLópez, Ezpeleta, et al., 2004Cros, Vandanjon, et al., 2003Dregus and Engel, 2003Lee and Noble, 2003Lin, Cai, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Carbowax 20MDB-WaxDB-WaxHP-FFAPHP-FFAP
Column length (m) 50.30.30.25.25.
Carrier gas He  HeHe
Substrate      
Column diameter (mm) 0.250.250.250.320.32
Phase thickness (μm) 0.250.250.250.50.5
Tstart (C) 45.30.30.45.45.
Tend (C) 190.250.250.220.220.
Heat rate (K/min) 4.4.4.15.15.
Initial hold (min) 2.1.1.  
Final hold (min) 50.    
I 1484.1495.1496.1503.1503.
ReferenceSoria, Martinez-Castro, et al., 2003Tanaka, Yamauchi, et al., 2003Tanaka, Yamauchi, et al., 2003Wanakhachornkrai and Lertsiri, 2003Wanakhachornkrai and Lertsiri, 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-FFAPDB-WaxRTX-WaxHP-WaxDB-Wax
Column length (m) 25.30.60.60.60.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.320.250.250.250.25
Phase thickness (μm) 0.50.250.50.50.25
Tstart (C) 45.40.40.40.40.
Tend (C) 220.250.180.190.200.
Heat rate (K/min) 15.8.5.3.2.
Initial hold (min)  5.5.6.2.
Final hold (min)  5.20.  
I 1502.1491.1493.1509.1481.
ReferenceWanakhachornkrai and Lertsiri, 2003Fu, Yoon, et al., 2002Galindo-Cuspinera, Lubran, et al., 2002Sanz, Maeztu, et al., 2002Umano, Hagi, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxHP-WaxSupelcowax-10Supelcowax-10DB-Wax
Column length (m) 30.60.60.30.60.
Carrier gas HeliumHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.320.25
Phase thickness (μm) 0.250.50.250.250.25
Tstart (C) 25.40.35.70.40.
Tend (C) 220.190.200.240.200.
Heat rate (K/min) 4.3.4.5.2.
Initial hold (min)  6.10.8.2.
Final hold (min) 30.  20. 
I 1475.1509.1492.1490.1492.
ReferenceDuque, Bonilla, et al., 2001Maeztu, Sanz, et al., 2001Girard and Durance, 2000Kim, Kim, et al., 2000Umano, Hagi, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP-Wax 52CBInnowaxDB-WaxSupelcowax-10DB-Wax
Column length (m) 50.60.60.60.60.
Carrier gas H2HeHeH2He
Substrate      
Column diameter (mm) 0.320.250.250.320.25
Phase thickness (μm) 0.220.250.250.5 
Tstart (C) 60.60.40.35.60.
Tend (C) 190.220.200.250.180.
Heat rate (K/min) 2. 2.5.2.
Initial hold (min) 4.10.2.5. 
Final hold (min) 21.  20. 
I 1458.1495.1490.1505.1491.
ReferenceHwan and Chou, 1999Kaya, Baser, et al., 1999Umano, Nakahara, et al., 1999Campeanu, Burcea, et al., 1998Sekiwa, Kubota, et al., 1997
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxPEG-20MTC-WaxSupelcowax-10Carbowax 20M
Column length (m) 60.50.60.60.60.
Carrier gas HeNitrogen He 
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm)  0.25 0.25 
Tstart (C) 50.60.80.40.60.
Tend (C) 200.180.240.200.180.
Heat rate (K/min) 3.2.3.3.2.
Initial hold (min)   5.3.4.
Final hold (min) 40.  30. 
I 1483.1461.1487.1491.1453.
ReferenceWada and Shibamoto, 1997Kubota, Matsujage, et al., 1996Shuichi, Masazumi, et al., 1996Wong and Lai, 1996Kawakami, Ganguly, et al., 1995
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillary
Active phase Carbowax 20MCarbowax 20M
Column length (m) 50.50.
Carrier gas HeHe
Substrate   
Column diameter (mm) 0.250.25
Phase thickness (μm)   
Tstart (C) 60.60.
Tend (C) 180.180.
Heat rate (K/min) 2.2.
Initial hold (min) 4.4.
Final hold (min)   
I 1453.1453.
ReferenceKawakami, Kobayashi, et al., 1993Kawakami and Kobayashi, 1991
Comment MSDC-RI MSDC-RI

References

Go To: Top, Normal alkane RI, polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wanakhachornkrai and Lertsiri, 9999
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Dregus and Engel, 2003
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Lee and Noble, 2003
Lee, S.-J.; Noble, A.C., Characterization of odor-active compounds in Californian Chardonnay wines using GC-olfactometry and GC-mass spectrometry, J. Agric. Food Chem., 2003, 51, 27, 8036-8044, https://doi.org/10.1021/jf034747v . [all data]

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Umano, Nakahara, et al., 1999
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Kubota, Matsujage, et al., 1996
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Shuichi, Masazumi, et al., 1996
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Wong and Lai, 1996
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Kawakami, Ganguly, et al., 1995
Kawakami, M.; Ganguly, S.N.; Banerjee, J.; Kobayashi, A., Aroma composition of oolong tea and black tea by brewed extraction method and characterizing compounds of Darjeeling tea aroma, J. Agric. Food Chem., 1995, 43, 1, 200-207, https://doi.org/10.1021/jf00049a037 . [all data]

Kawakami, Kobayashi, et al., 1993
Kawakami, M.; Kobayashi, A.; Kator, K., Volatile constituents of Rooibos tea (Aspalathus linearis) as affected by extraction process, J. Agric. Food Chem., 1993, 41, 4, 633-636, https://doi.org/10.1021/jf00028a023 . [all data]

Kawakami and Kobayashi, 1991
Kawakami, M.; Kobayashi, A., Volatitle constituents of greem mate and roasted mate, J. Agric. Food Chem., 1991, 39, 7, 1275-1279, https://doi.org/10.1021/jf00007a016 . [all data]


Notes

Go To: Top, Normal alkane RI, polar column, temperature ramp, References