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Benzyl methyl ketone

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-94.64kJ/molCcbNicholson, Szwarc, et al., 1954 
Deltafgas-94.64kJ/molCcbNicholson, Szwarc, et al., 1954 

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafliquid-151.9 ± 1.7kJ/molCcbNicholson, Szwarc, et al., 1954Reanalyzed by Cox and Pilcher, 1970, Original value = -152.3 kJ/mol
Deltafliquid-152.3kJ/molCcbNicholson, Szwarc, et al., 1954 
Deltafliquid-162.5 ± 1.3kJ/molCcbParks, Manchester, et al., 1954Reanalyzed by Cox and Pilcher, 1970, Original value = -163.0 ± 1.3 kJ/mol
Quantity Value Units Method Reference Comment
Deltacliquid-4818.8 ± 1.7kJ/molCcbNicholson, Szwarc, et al., 1954Reanalyzed by Cox and Pilcher, 1970, Original value = -4819. ± 2. kJ/mol; Corresponding «DELTA»fliquid = -151.9 kJ/mol (simple calculation by NIST; no Washburn corrections)
Deltacliquid-4818.5 ± 1.7kJ/molCcbNicholson, Szwarc, et al., 1954Corresponding «DELTA»fliquid = -152.3 kJ/mol (simple calculation by NIST; no Washburn corrections)
Deltacliquid-4808.2 ± 1.2kJ/molCcbParks, Manchester, et al., 1954Reanalyzed by Cox and Pilcher, 1970, Original value = -4807.79 kJ/mol; Corresponding «DELTA»fliquid = -162.6 kJ/mol (simple calculation by NIST; no Washburn corrections)
Deltacliquid-4818. ± 3.kJ/molCcbSpringall and White, 1954Corresponding «DELTA»fliquid = -152. kJ/mol (simple calculation by NIST; no Washburn corrections)

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nicholson, Szwarc, et al., 1954
Nicholson, G.R.; Szwarc, M.; Taylor, J.W., The heats of formation of diacetyl and of benzyl methyl ketone in the vapour phase, J. Chem. Soc., 1954, 2767-2769. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Parks, Manchester, et al., 1954
Parks, G.S.; Manchester, K.E.; Vaughan, L.M., Heats of combustion and formation of some alcohols, phenols, and ketones, J. Chem. Phys., 1954, 22, 2089-2090. [all data]

Springall and White, 1954
Springall, H.D.; White, T.R., Heats of combustion and molecular structure. Part II. The mean bond energy term for the carbonyl system in certain ketones, J. Chem. Soc., 1954, 2765-27. [all data]


Notes

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