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lithium iodide


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
0.750 ± 0.040N/AMiller, Leopold, et al., 1986Extrapolated by polarizability and radius from experimental data.; B
>1.12001EIAEEbinghaus, 1964From (LiI)2; B

Ionization energy determinations

IE (eV) Method Reference Comment
7.5PEPotts and Lee, 1979LLK
8.6 ± 0.3EIPlatel, 1965RDSH
<=8.55 ± 0.15EIFriedman, 1955RDSH
8.44 ± 0.03PEPotts and Lee, 1979Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
I+14.4 ± 0.3LiEIPlatel, 1965RDSH
I+14.5 ± 0.20LiEIFriedman, 1955RDSH
Li+9.5 ± 0.3IEIPlatel, 1965RDSH
Li+9.2 ± 0.15IEIFriedman, 1955RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Miller, Leopold, et al., 1986
Miller, T.M.; Leopold, D.G.; Murray, K.K.; Lineberger, W.C., Electron Affinities of the Alkali Halides and the Structure of their Negative Ions, J. Chem. Phys., 1986, 85, 5, 2368, https://doi.org/10.1063/1.451091 . [all data]

Ebinghaus, 1964
Ebinghaus, H.Z., Negative Ionen aus Alkalihalogeniden und Electronenaffinitaten der Alkalimetalle und Alkalihalogenide, Z. Naturfor., 1964, 19A, 727. [all data]

Potts and Lee, 1979
Potts, A.W.; Lee, E.P.F., Photoelectron spectra and electronic structure of lithium halide monomers and dimers, J. Chem. Soc. Faraday Trans. 2, 1979, 75, 941. [all data]

Platel, 1965
Platel, G., Mesures des potentials d'apparition des ions obtenus par impact electronique dans la phase vapeur des iodures alcalins et des melanges LiI-MI, J. Chim. Phys., 1965, 62, 1176. [all data]

Friedman, 1955
Friedman, L., Mass spectrum of lithium iodide, J. Chem. Phys., 1955, 23, 477. [all data]


Notes

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