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Benzenamine, N-ethyl-

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

C8H10N- + Hydrogen cation = Benzenamine, N-ethyl-

By formula: C8H10N- + H+ = C8H11N

Quantity Value Units Method Reference Comment
Deltar1523. ± 8.8kJ/molG+TSTaft, 1987gas phase; value altered from reference due to change in acidity scale; B
Quantity Value Units Method Reference Comment
Deltar1493. ± 8.4kJ/molIMRETaft, 1987gas phase; value altered from reference due to change in acidity scale; B

Benzenamine, N-ethyl- + Nitrous acid = Benzenamine, N-ethyl-N-nitroso- + Water

By formula: C8H11N + HNO2 = C8H10N2O + H2O

Quantity Value Units Method Reference Comment
Deltar-78.83kJ/molCmSwientoslawski, 1910liquid phase; ALS

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Taft, 1987
Taft, R.W., The Nature and Analysis of Substitutent Electronic Effects, Personal communication. See also Prog. Phys. Org. Chem., 1987, 16, 1. [all data]

Swientoslawski, 1910
Swientoslawski, W., Thermochemische Untersuchungen der organischen Verbindungen. Dritte Mitteilung. Stickstoffhaltige Verbindungen., Z. Phys. Chem., 1910, 72, 49-83. [all data]


Notes

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