Benzene, propyl-

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Kovats' RI, non-polar column, isothermal

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101OV-101HP-101HP-101DB-1
Column length (m) 50.50.50.50.10.
Carrier gas HeHeH2H2He
Substrate      
Column diameter (mm) 0.250.250.20.20.25
Phase thickness (μm)   0.20.20.25
Temperature (C) 40.60.60.60.140.
I 932.2937.2938.14938.14961.
ReferenceChen, Liang, et al., 2001Chen, Liang, et al., 2001Garay, 2000Garay, 2000Beens, Tijssen, et al., 1998
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1CP Sil 2OV-101OV-101HP-1
Column length (m) 10.100.20.20.25.
Carrier gas He   N2
Substrate      
Column diameter (mm) 0.250.250.50.50.20
Phase thickness (μm) 0.250.25   
Temperature (C) 60.80.150.180.60.
I 940.943.9964.6973.0938.
ReferenceBeens, Tijssen, et al., 1998Estel, Mohnke, et al., 1995Cha and Lee, 1994Cha and Lee, 1994Zhang, Li, et al., 1992
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryPackedCapillaryCapillaryCapillary
Active phase HP-1ApolaneOV-101OV-101OV-101
Column length (m) 25.3.750.50.278.
Carrier gas N2  HeH2
Substrate      
Column diameter (mm) 0.20 0.250.200.25
Phase thickness (μm)      
Temperature (C) 60.130.100.100.100.
I 938.964.947.5949.949.
ReferenceZhang, Li, et al., 1992Dutoit, 1991Dimov and Mekenyan, 1989Matisová, Kovacicová, et al., 1989Matisová, Rukríglová, et al., 1988
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101OV-101SqualaneOV-101OV-101
Column length (m) 278.50. 85.85.
Carrier gas H2  N2N2
Substrate      
Column diameter (mm) 0.250.30 0.280.28
Phase thickness (μm)      
Temperature (C) 100.100.100.100.100.
I 949.950.937.947.949.
ReferenceMatisová, Rukríglová, et al., 1988Engewald, Topalova, et al., 1987Nabivach and Vasiliev, 1987Boneva, Papazova, et al., 1983Boneva, Papazova, et al., 1983
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101OV-101OV-101SqualaneSqualane
Column length (m) 85.85.85.100.100.
Carrier gas N2N2N2HeHe
Substrate      
Column diameter (mm) 0.280.280.28  
Phase thickness (μm)      
Temperature (C) 100.110.90.106.96.
I 947.950.944.936.934.
ReferenceBoneva, Papazova, et al., 1983Boneva, Papazova, et al., 1983Boneva, Papazova, et al., 1983Kugucheva and Mashinsky, 1983Kugucheva and Mashinsky, 1983
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryPackedCapillary
Active phase DB-1DB-1SE-30SE-30SE-30
Column length (m) 60.60.15.2.100.
Carrier gas   N2  
Substrate    Gaschrom Q 
Column diameter (mm) 0.2640.2590.25 0.5
Phase thickness (μm)  1.   
Temperature (C) 60.60.70.100.130.
I 937.7938.1941.8950.959.
ReferenceLubeck and Sutton, 1983Lubeck and Sutton, 1983Tóth, 1983Winskowski, 1983Bredael, 1982
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SE-30OV-101OV-101OV-101Squalane
Column length (m) 100.50.50.50.50.
Carrier gas  N2N2N2N2
Substrate      
Column diameter (mm) 0.50.300.300.300.25
Phase thickness (μm)      
Temperature (C) 80.100.120.140.86.
I 944.949.955.961.932.7
ReferenceBredael, 1982Gerasimenko and Nabivach, 1982Gerasimenko and Nabivach, 1982Gerasimenko and Nabivach, 1982Macák, Nabivach, et al., 1982
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryPacked
Active phase SqualaneOV-101OV-101OV-101Squalane
Column length (m) 50.50.50.50.1.
Carrier gas N2N2N2N2He
Substrate     Chromaton N-AW-HMDS
Column diameter (mm) 0.250.30.30.3 
Phase thickness (μm)      
Temperature (C) 96.100.120.140.100.
I 935.1949.3954.6960.7938.
ReferenceMacák, Nabivach, et al., 1982Gerasimenko, Kirilenko, et al., 1981Gerasimenko, Kirilenko, et al., 1981Gerasimenko, Kirilenko, et al., 1981Nabivach and Kirilenko, 1980
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SqualaneSqualaneSqualaneSqualaneSqualane
Column length (m) 50.50.50.50.100.
Carrier gas N2N2  N2
Substrate      
Column diameter (mm)   0.250.250.23
Phase thickness (μm)      
Temperature (C) 86.86.86.96.100.
I 932.0933.0932.7935.1938.
ReferenceNabivach and Kirilenko, 1979Nabivach and Kirilenko, 1979Nabivach, Bur'yan, et al., 1978Nabivach, Bur'yan, et al., 1978Engewald and Wennrich, 1976
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryPackedCapillaryPacked
Active phase SqualaneSqualaneApolaneSqualaneSE-30
Column length (m) 120.120.2.4100.6.1
Carrier gas HeHeHeH2N2
Substrate   Chromosorb Chrom W
Column diameter (mm) 0.250.25 0.25 
Phase thickness (μm)      
Temperature (C) 100.100.70.80.110.
I 932.5932.943.0929.74952.
ReferenceLulova, Leont'eva, et al., 1976Lulova, Leont'eva, et al., 1976Riedo, Fritz, et al., 1976Soják and Rijks, 1976Mitra, Mohan, et al., 1974
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedCapillaryCapillaryCapillaryCapillary
Active phase SE-30SE-30SE-30SqualaneSqualane
Column length (m) 6.125.525.510.550.
Carrier gas N2HeHeHeN2
Substrate Chrom W   Celite 545
Column diameter (mm)  0.50.50.250.3
Phase thickness (μm)      
Temperature (C) 140.65.65.100.120.
I 968.938.1938.1936.1939.
ReferenceMitra, Mohan, et al., 1974Svob, Deur-Siftar, et al., 1974Svob and Deur-Siftar, 1974Svob and Deur-Siftar, 1974Agrawal, Tesarík, et al., 1972
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryPackedPacked
Active phase SqualaneSqualaneSqualaneApiezon LApiezon L
Column length (m) 50.200.200.2.310.
Carrier gas N2N2N2N2 
Substrate Celite 545  DCMS-treated Chromosorb WChromosorb P
Column diameter (mm) 0.30.20.2  
Phase thickness (μm)      
Temperature (C) 86.115.86.100.100.
I 932.940.2932.6966.966.
ReferenceAgrawal, Tesarík, et al., 1972Soják and Bucinská, 1970Soják and Bucinská, 1970Brown, Chapman, et al., 1968Bonastre and Grenier, 1967
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPackedPackedPacked
Active phase Apiezon LApiezon LApiezon LSqualaneSqualane
Column length (m) 10.10.10.6.6.
Carrier gas      
Substrate Chromosorb PChromosorb PChromosorb PChromosorb PChromosorb P
Column diameter (mm)      
Phase thickness (μm)      
Temperature (C) 120.140.80.100.120.
I 973.980.958.938.943.
ReferenceBonastre and Grenier, 1967Bonastre and Grenier, 1967Bonastre and Grenier, 1967Bonastre and Grenier, 1967Bonastre and Grenier, 1967
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPacked
Active phase SqualaneSqualane
Column length (m) 6.6.
Carrier gas   
Substrate Chromosorb PChromosorb P
Column diameter (mm)   
Phase thickness (μm)   
Temperature (C) 140.80.
I 949.933.
ReferenceBonastre and Grenier, 1967Bonastre and Grenier, 1967
Comment MSDC-RI MSDC-RI

References

Go To: Top, Kovats' RI, non-polar column, isothermal, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chen, Liang, et al., 2001
Chen, J.P.; Liang, X.M.; Zhang, Q.; Zhang, L.F., Prediction of GC retention values under various column temperature conditions from temperature programmed data, Chromatographia, 2001, 53, 9/10, 539-547, https://doi.org/10.1007/BF02491619 . [all data]

Garay, 2000
Garay, F., Application of a flow-tunable, serially coupled gas chromatographic capillary column system for the analysis of complex mixtures, Chromatographia Sup., 2000, 51, 1, s108-s120, https://doi.org/10.1007/BF02492792 . [all data]

Beens, Tijssen, et al., 1998
Beens, J.; Tijssen, R.; Blomberg, J., Prediction of comprehensive two-dimensional gas chromatographic separations. A theoretical and practical exercise, J. Chromatogr. A, 1998, 822, 2, 233-251, https://doi.org/10.1016/S0021-9673(98)00649-9 . [all data]

Estel, Mohnke, et al., 1995
Estel, D.; Mohnke; Biermans; Rotzsche, The analysis of C4-C11 hydrocarbons in naphtha and reformate with a new apolar fused silica column, J. Hi. Res. Chromatogr., 1995, 18, 7, 403-412, https://doi.org/10.1002/jhrc.1240180703 . [all data]

Cha and Lee, 1994
Cha, K.-W.; Lee, D.-J., Prediction of retention indices of various compounds in gas-liquid chromatography, J. Korean Chem. Soc., 1994, 38, 2, 108-120, retrieved from http://journal.kcsnet.or.kr/publi/dh/dh94n2/108.pdf. [all data]

Zhang, Li, et al., 1992
Zhang, M.J.; Li, S.D.; Chen, B.J., Compositional studies of high-temperature coal tar by GC/FTIR analysis of light oil fractions, Chromatographia, 1992, 33, 3/4, 138-146, https://doi.org/10.1007/BF02275894 . [all data]

Dutoit, 1991
Dutoit, J., Gas chromatographic retention behaviour of some solutes on structurally similar polar and non-polar stationary phases, J. Chromatogr., 1991, 555, 1-2, 191-204, https://doi.org/10.1016/S0021-9673(01)87179-X . [all data]

Dimov and Mekenyan, 1989
Dimov, N.; Mekenyan, Ov., Quantitative Relationships Between the Structure of Alkylbenzenes and Their Gas Chromatographic Retention on Stationary Phasses with Different Polarity, J. Chromatogr., 1989, 471, 227-236, https://doi.org/10.1016/S0021-9673(00)94170-0 . [all data]

Matisová, Kovacicová, et al., 1989
Matisová, E.; Kovacicová, E.; Ha, P.T.; Kolek, E.; Engewald, W., Identification of alkylbenzenes up to C12 by capillary gas chromatography-mass spectrometry. II. Retention indices on OV-101 columns and retention-molecular structure correlations, J. Chromatogr., 1989, 475, 2, 113-123, https://doi.org/10.1016/S0021-9673(01)89667-9 . [all data]

Matisová, Rukríglová, et al., 1988
Matisová, E.; Rukríglová, M.; Krupcík, J.; Kovacicová, E.; Holotík, S., Identification of alkylbenzenes up to C12 by capillary gas chromatography and combined gas chromatography-mass spectrometry. I. OV-101 as stationary phase, J. Chromatogr., 1988, 455, 301-309, https://doi.org/10.1016/S0021-9673(01)82129-4 . [all data]

Engewald, Topalova, et al., 1987
Engewald, W.; Topalova, I.; Petsev, N.; Dimitrov, Chr., Structure-Retention Correlations of Hydrocarbons in GLC and GSC. Alkenylbenzenes, Chromatographia, 1987, 23, 8, 561-565, https://doi.org/10.1007/BF02324864 . [all data]

Nabivach and Vasiliev, 1987
Nabivach, V.M.; Vasiliev, E.E.E., Correlation dependencies of GC retention indices from physical chemical properties and structures of aromatic hydrocarbons, Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol., 1987, 30, 72-75. [all data]

Boneva, Papazova, et al., 1983
Boneva, St.; Papazova, D.; Dimov, N., Retention Indices of aromatic hydrocarbons on glass and metal capillary columns with stationary phase OV-101, Jahrb. Chem. Tech. Hochschule Burgas, 1983, 18, 143-148. [all data]

Kugucheva and Mashinsky, 1983
Kugucheva, E.E.; Mashinsky, V.I., Retention Indices of Aromatic Hydrocarbons on Capillary Columns with Squalan and Polyphenyl Ether, Zh. Anal. Khim. (Rus), 1983, 38, 11, 2023-2026. [all data]

Lubeck and Sutton, 1983
Lubeck, A.J.; Sutton, DL., Kovats retention indices of selected hydrocarbons through C10 on bonded phase fused silica capillaries, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1983, 6, 6, 328-332, https://doi.org/10.1002/jhrc.1240060612 . [all data]

Tóth, 1983
Tóth, T., Use of capillary gas chromatography in collecting retention and chemical information for the analysis of complex petrochemical mixtures, J. Chromatogr., 1983, 279, 157-165, https://doi.org/10.1016/S0021-9673(01)93614-3 . [all data]

Winskowski, 1983
Winskowski, J., Gaschromatographische Identifizierung von Stoffen anhand von Indexziffem und unterschiedlichen Detektoren, Chromatographia, 1983, 17, 3, 160-165, https://doi.org/10.1007/BF02271041 . [all data]

Bredael, 1982
Bredael, P., Retention indices of hydrocarbons on SE-30, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1982, 5, 6, 325-328, https://doi.org/10.1002/jhrc.1240050610 . [all data]

Gerasimenko and Nabivach, 1982
Gerasimenko, V.A.; Nabivach, V.M., Relationship between molecular structure and gas chromatographic retention of alkylbenzenes C8-C1 2 on polydimethylsiloxane, Zh. Anal. Khim., 1982, 37, 110-116. [all data]

Macák, Nabivach, et al., 1982
Macák, J.; Nabivach, V.; Buryan, P.; Sindler, S., Dependence of retention indices of alkylbenzenes on their molecular structure, J. Chromatogr., 1982, 234, 2, 285-302, https://doi.org/10.1016/S0021-9673(00)81867-1 . [all data]

Gerasimenko, Kirilenko, et al., 1981
Gerasimenko, V.A.; Kirilenko, A.V.; Nabivach, V.M., Capillary gas chromatography of aromatic compounds found in coal tar fractions, J. Chromatogr., 1981, 208, 1, 9-16, https://doi.org/10.1016/S0021-9673(00)87953-4 . [all data]

Nabivach and Kirilenko, 1980
Nabivach, V.M.; Kirilenko, A.V., Relationship between the gas chromatographic behaviour and the molecular structure of hydrocarbon samples and various stationary phases. Part II. Correlation between the retention index, physicochemical properties and molecular structure, Chromatographia, 1980, 13, 2, 93-100, https://doi.org/10.1007/BF02263060 . [all data]

Nabivach and Kirilenko, 1979
Nabivach, V.M.; Kirilenko, A.V., The use of retention indices for identifying the components of crude benzene, Solid Fuel Chem. (Engl. Transl.), 1979, 13, 3, 82-87. [all data]

Nabivach, Bur'yan, et al., 1978
Nabivach, V.M.; Bur'yan, P.; Matsak, I., Retention indices of aromatic hydrocarbons on a squalane capillary column, Zh. Anal. Khim., 1978, 33, 7, 1108-1113. [all data]

Engewald and Wennrich, 1976
Engewald, W.; Wennrich, L., Molekülstruktur und Retentionsverhalten. VIII. Zum Retentionsverhalten höherer Alkylbenzole bei der Gas-Verteilungs-Chromatographie, Chromatographia, 1976, 9, 11, 540-547, https://doi.org/10.1007/BF02275960 . [all data]

Lulova, Leont'eva, et al., 1976
Lulova, N.I.; Leont'eva, S.A.; Timofeeva, A.N., Gas-chromatographic method of determination of individual hydrocarbons in catalytic cracking gasolines in Proceedings of All-Union Research Institute on Oil Processes. Vol.18, All-Union Research Institute on Oil Processes, Moscow, 1976, 30-53. [all data]

Riedo, Fritz, et al., 1976
Riedo, F.; Fritz, D.; Tarján, G.; Kováts, E.Sz., A tailor-made C87 hydrocarbon as a possible non-polar standard stationary phase for gas chromatography, J. Chromatogr., 1976, 126, 63-83, https://doi.org/10.1016/S0021-9673(01)84063-2 . [all data]

Soják and Rijks, 1976
Soják, L.; Rijks, J.A., Capillary gas chromatography of alkylbenzenes. I. Some problems encountered with the precision of the retention indcies of alkylbenzenes, J. Chromatogr., 1976, 119, 505-521, https://doi.org/10.1016/S0021-9673(00)86812-0 . [all data]

Mitra, Mohan, et al., 1974
Mitra, G.D.; Mohan, G.; Sinha, A., Advances in the utilization of the retention index system for characterizing hydrocarbons in complex mixtures by gas chromatography, J. Chromatogr., 1974, 99, 215-230, https://doi.org/10.1016/S0021-9673(00)90857-4 . [all data]

Svob, Deur-Siftar, et al., 1974
Svob, V.; Deur-Siftar, D.; Cramers, C.A., Mechanisms of the thermal degradation of alkylbenzenes, J. Chromatogr., 1974, 91, 659-675, https://doi.org/10.1016/S0021-9673(01)97946-4 . [all data]

Svob and Deur-Siftar, 1974
Svob, V.; Deur-Siftar, D., Kovats Retention Indices in the Identification of Alkylbenzene Degradation Products, J. Chromatogr., 1974, 91, 677-689, https://doi.org/10.1016/S0021-9673(01)97947-6 . [all data]

Agrawal, Tesarík, et al., 1972
Agrawal, B.B.; Tesarík, K.; Janák, J., Gas chromatographic characterization of sulphur compounds in the 93-162° gasoline cut from Romashkino crude oil using Kováts retention indices, J. Chromatogr., 1972, 65, 1, 207-215, https://doi.org/10.1016/S0021-9673(00)86933-2 . [all data]

Soják and Bucinská, 1970
Soják, L.; Bucinská, A., Open tubular column gas chromatography of dehydrogenation products of C6-C10 n-alkanes. Separation and identification of mixtures of C6-C10 straight-chain alkanes, alkenes and aromatics, J. Chromatogr., 1970, 51, 75-82, https://doi.org/10.1016/S0021-9673(01)96841-4 . [all data]

Brown, Chapman, et al., 1968
Brown, I.; Chapman, I.L.; Nicholson, G.J., Gas chromatography of polar solutes in electron acceptor stationary phases, Aust. J. Chem., 1968, 21, 5, 1125-1141, https://doi.org/10.1071/CH9681125 . [all data]

Bonastre and Grenier, 1967
Bonastre, J.; Grenier, P., Contribution à l'étude de la polarité des phases stationnaires en chromatographie gas-liquide. I. Calcul des coefficients d'activité relatifs et des indices de rétention de quelques hydrocarbures aromatiques, Bull. Soc. Chim. Fr., 1967, 4, 1395-1405. [all data]


Notes

Go To: Top, Kovats' RI, non-polar column, isothermal, References