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dichloroborane


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 BH stretch 2616.9 w gas IR Lynds and Stern, 1959
Nadeau and Oaks, 1960
Myers and Putnam, 1963
Lynds and Bass, 1964
1 BH stretch 2625 Ar IR Bass, Lynds, et al., 1964
2 BCl2 s-stretch 740 T gas IR Bass, Lynds, et al., 1964, 2
b1 4 OPLA 784 T gas IR Bass, Lynds, et al., 1964, 2
4 OPLA 788 Ar IR Bass, Lynds, et al., 1964
b2 5 HBCl bend 1089 s gas IR Lynds and Stern, 1959
Nadeau and Oaks, 1960
Myers and Putnam, 1963
Bass, Lynds, et al., 1964, 2
5 HBCl bend 1082.5 Ar IR Bass, Lynds, et al., 1964
Miller and Andrews, 1980
6 BCl2 a-stretch 892 s gas IR Lynds and Stern, 1959
Nadeau and Oaks, 1960
Myers and Putnam, 1963
Bass, Lynds, et al., 1964, 2
6 BCl2 a-stretch 886.3 Ar IR Bass, Lynds, et al., 1964
Miller and Andrews, 1980

Additional references: Jacox, 1998, page 238; Sugie, Takeo, et al., 1994

Notes

wWeak
sStrong
TTentative assignment or approximate value

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lynds and Stern, 1959
Lynds, L.; Stern, D.R., None, J. Am. Chem. Soc., 1959, 81, 18, 5006, https://doi.org/10.1021/ja01527a070 . [all data]

Nadeau and Oaks, 1960
Nadeau, H.G.; Oaks, D.M., Jr., Infrared Spectrophotometric Determination of Diborane (6), Dichloroborane, and Trichloroborane in Mixtures, Analyt. Chem., 1960, 32, 11, 1480, https://doi.org/10.1021/ac60167a030 . [all data]

Myers and Putnam, 1963
Myers, H.W.; Putnam, R.F., On the Properties of Monochlorodiborane, Inorg. Chem., 1963, 2, 3, 655, https://doi.org/10.1021/ic50007a067 . [all data]

Lynds and Bass, 1964
Lynds, L.; Bass, C.D., Infrared Spectrum of «nu»2 of Dichloroborane and Dichloroborane-d, J. Chem. Phys., 1964, 40, 6, 1590, https://doi.org/10.1063/1.1725365 . [all data]

Bass, Lynds, et al., 1964
Bass, C.D.; Lynds, L.; Wolfram, T.; DeWames, R.E., Matrix Isolation Spectra of HBCl2 and DBCl2, Inorg. Chem., 1964, 3, 7, 1063, https://doi.org/10.1021/ic50017a047 . [all data]

Bass, Lynds, et al., 1964, 2
Bass, C.D.; Lynds, L.; Wolfram, T.; DeWames, R.E., Vibrational Analysis of Substituted and Perturbed Molecules. II. Planar XY3 Molecules; Application to BCl3[Single Bond]HBCl2[Single Bond]DBCl2, J. Chem. Phys., 1964, 40, 12, 3611, https://doi.org/10.1063/1.1725062 . [all data]

Miller and Andrews, 1980
Miller, J.H.; Andrews, L., Matrix photoionization and radiolysis of boron trihalides. Infrared and ultraviolet spectra of boron trichloride(1+) and boron tribromide(1+) and infrared spectra of boron dichloride and boron dibromide, J. Am. Chem. Soc., 1980, 102, 15, 4900, https://doi.org/10.1021/ja00535a011 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Sugie, Takeo, et al., 1994
Sugie, M.; Takeo, H.; Matsumura, C., Spectrochim. Acta, 1994, 50A, 1379. [all data]


Notes

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