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ethyl methyl sulphite

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-125.2 ± 0.5kcal/molCcbMackle and Steele, 1969 

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafliquid-135.6 ± 0.3kcal/molCcbMackle and Steele, 1969 
Quantity Value Units Method Reference Comment
Deltacliquid-563.74 ± 0.26kcal/molCcbMackle and Steele, 1969Reanalyzed by Cox and Pilcher, 1970, Original value = -562.60 ± 0.26 kcal/mol

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil414.KN/AMackle and Steele, 1969, 2Uncertainty assigned by TRC = 1. K; TRC
Tboil414.65KN/ACarre and Libermann, 1933Uncertainty assigned by TRC = 5. K; TRC
Tboil414.KN/ACarre and Mauclere, 1931Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Deltavap10.4 ± 0.4kcal/molEMackle and Steele, 1969ALS

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mackle and Steele, 1969
Mackle, H.; Steele, W.V., Studies in the thermochemistry of organic sulphites and sulphates. Part 1.-Heats of combustion and formation of some dialkyl sulphites and sulphates, Trans. Faraday Soc., 1969, 65, 2053-2059. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Mackle and Steele, 1969, 2
Mackle, H.; Steele, W.V., Studies in the thermochemistry of organic sulphites and sulphates: I heats of combustion and formation of some dialkyl sulphites and sulphates, Trans. Faraday Soc., 1969, 65, 2053-9. [all data]

Carre and Libermann, 1933
Carre, P.; Libermann, D., Chlorides of the alkyl- and arylsulfurous acids (alkyl and aryl chlorosulfites) and mixed sulfurous esters, Bull. Soc. Chim., 1933, 53, 1050-75. [all data]

Carre and Mauclere, 1931
Carre, P.; Mauclere, P., The chloride of ethyl hydrogen sulfite, and the neutral mixed alcoyl sulfites, C. R. Hebd. Seances Acad. Sci., 1931, 192, 1738-40. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References