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U(BH4)4 radical


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Fluorine anion + H16B4U = (Fluorine anion bullet H16B4U)

By formula: F- + H16B4U = (F- bullet H16B4U)

Quantity Value Units Method Reference Comment
Deltar45.0 ± 8.1kcal/molIMRBBabcock, Herd, et al., 1984gas phase; Obs. F- transfer from SF6-, not from UF5-

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
<1.13649IMRBArmentrout and Beauchamp, 1979No electron transfer from NO2- to neutral.

Ion clustering data

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Fluorine anion + H16B4U = (Fluorine anion bullet H16B4U)

By formula: F- + H16B4U = (F- bullet H16B4U)

Quantity Value Units Method Reference Comment
Deltar45.0 ± 8.1kcal/molIMRBBabcock, Herd, et al., 1984gas phase; Obs. F- transfer from SF6-, not from UF5-

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Babcock, Herd, et al., 1984
Babcock, L.M.; Herd, C.R.; Streit, G.E., A Flowing Afterglow Study of Uranium Tetraborohydride, Chem. Phys. Lett., 1984, 112, 2, 169, https://doi.org/10.1016/0009-2614(84)85015-0 . [all data]

Armentrout and Beauchamp, 1979
Armentrout, P.B.; Beauchamp, J.L., Properties and reactions of uranium(IV) tetrahydroborate by ion cyclotron mass spectrometry, Inorg. Chem., 1979, 18, 1349. [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References