Ferrocene

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Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

ΔsubH° (kJ/mol) Method Reference Comment
73.3 ± 1.9MELousada, Pinto, et al., 2008AC
72.7 ± 0.2CLousada, Pinto, et al., 2008AC
72.7 ± 0.2GSEmel'yanenko, Verevkin, et al., 2007Based on data from 290. - 363. K.; AC
73.3 ± 0.1CMonte, Santos, et al., 2006AC
74.9 ± 1.7CSantos, Schröder, et al., 2004AC
73.3 ± 0.1CKiyobayashi and Minas da Piedade, 2001AC
74.1 ± 1.4DSCRojas-Aguilar, Orozco-Guareño, et al., 2001See also Emel'yanenko, Verevkin, et al., 2007.; AC
74.3 ± 0.4METorres, Gudiño, et al., 1995AC
73.2 ± 0.7CTorres, Gudiño, et al., 1995AC
72.4 ± 1.0N/ADa Silva and Monte, 1990AC
70.3 ± 1.0MEMinas da Piedade, 1989Based on data from 294. - 302. K. See also Da Silva and Monte, 1990.; AC
71.9 ± 0.4N/ATorres-Gómez, Barreiro-Rodríguez, et al., 1988AC
75.6 ± 0.4TE,ME,DMJacobs, Van Ekeren, et al., 1983AC
73.6 ± 0.4N/APilcher and Skinner, 1983See also Tel'noi, Kirynov, et al., 1975.; AC
74. ± 2.TEPelino, Tomassetti, et al., 1981AC
72.6 ± 1.4MECalado, Dias, et al., 1980AC
71.9 ± 2.0DSCMurray, Cavell, et al., 1980Based on data from 328. - 398. K. See also Emel'yanenko, Verevkin, et al., 2007.; AC
67.9N/ABarkatin, Gaidym, et al., 1977Based on data from 348. - 451. K. See also Emel'yanenko, Verevkin, et al., 2007.; AC
74.1 ± 1.7TCMde Kruif and Oonk, 1973AC
87.6 ± 2.0DSCBeech and Lintonbon, 1971Based on data from 385. - 455. K. See also Emel'yanenko, Verevkin, et al., 2007.; AC; Data excluded from overall average
73. ± 2.MEAndrews and Westrum, 1969AC
77. ± 1.MEEdwards and Kington, 1962AC
76.8 ± 0.9MEEdwards, Kington, et al., 1960Based on data from 295. - 303. K. See also Emel'yanenko, Verevkin, et al., 2007.; AC
84.7MECordes and Schreiner, 1959Based on data from 323. - 367. K. See also Emel'yanenko, Verevkin, et al., 2007.; AC; Data excluded from overall average
73.7BGKaplan, Kester, et al., 1952Based on data from 357. - 455. K. See also Emel'yanenko, Verevkin, et al., 2007.; AC

References

Go To: Top, Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lousada, Pinto, et al., 2008
Lousada, Cláudio M.; Pinto, Susana S.; Canongia Lopes, José N.; Minas da Piedade, M. Fátima; Diogo, Hermínio P.; Minas da Piedade, Manuel E., Experimental and Molecular Dynamics Simulation Study of the Sublimation and Vaporization Energetics of Iron Metalocenes. Crystal Structures of Fe(η 5 -C 5 H 4 CH 3 ) 2 and Fe[(η 5 -(C 5 H 5 )(η 5 -C 5 H 4 CHO)], J. Phys. Chem. A, 2008, 112, 13, 2977-2987, https://doi.org/10.1021/jp7107818 . [all data]

Emel'yanenko, Verevkin, et al., 2007
Emel'yanenko, Vladimir N.; Verevkin, Sergey P.; Krol, Olesya V.; Varushchenko, Raisa M.; Chelovskaya, Nelly V., Vapour pressures and enthalpies of vaporization of a series of the ferrocene derivatives, The Journal of Chemical Thermodynamics, 2007, 39, 4, 594-601, https://doi.org/10.1016/j.jct.2006.09.001 . [all data]

Monte, Santos, et al., 2006
Monte, Manuel J.S.; Santos, Luís M.N.B.F.; Fulem, Michal; Fonseca, José M.S.; Sousa, Carlos A.D., New Static Apparatus and Vapor Pressure of Reference Materials: Naphthalene, Benzoic Acid, Benzophenone, and Ferrocene, J. Chem. Eng. Data, 2006, 51, 2, 757-766, https://doi.org/10.1021/je050502y . [all data]

Santos, Schröder, et al., 2004
Santos, Luis M.N.B.F.; Schröder, Bernd; Fernandes, Oscar O.P.; Ribeiro da Silva, Manuel A.V., Measurement of enthalpies of sublimation by drop method in a Calvet type calorimeter: design and test of a new system, Thermochimica Acta, 2004, 415, 1-2, 15-20, https://doi.org/10.1016/j.tca.2003.07.016 . [all data]

Kiyobayashi and Minas da Piedade, 2001
Kiyobayashi, Tetsu; Minas da Piedade, Manuel E., The standard molar enthalpy of sublimation ofη5-bis-pentamethylcyclopentadienyl iron measured with an electrically calibrated vacuum-drop sublimation microcalorimetric apparatus, The Journal of Chemical Thermodynamics, 2001, 33, 1, 11-21, https://doi.org/10.1006/jcht.2000.0716 . [all data]

Rojas-Aguilar, Orozco-Guareño, et al., 2001
Rojas-Aguilar, Aarón; Orozco-Guareño, Eulogio; Martínez-Herrera, Melchor, An experimental system for measurement of enthalpies of sublimation by d.s.c., The Journal of Chemical Thermodynamics, 2001, 33, 10, 1405-1418, https://doi.org/10.1006/jcht.2001.0857 . [all data]

Torres, Gudiño, et al., 1995
Torres, Luis Alfonso; Gudiño, Ramón; Sabbah, Raphaël; Guardado, Juan Antonio, Standard reference material proposed for enthalpy-of-sublimation measurements. A comparative study of the standard molar enthalpy of sublimation of Fe(c-C5H5)2(ferrocene) by calorimetry and knudsen-effusion techniques, The Journal of Chemical Thermodynamics, 1995, 27, 11, 1261-1266, https://doi.org/10.1006/jcht.1995.0132 . [all data]

Da Silva and Monte, 1990
Da Silva, Manuel A.V. Ribeiro; Monte, Manuel J.S., The construction, testing and use of a new knudsen effusion apparatus, Thermochimica Acta, 1990, 171, 169-183, https://doi.org/10.1016/0040-6031(90)87017-7 . [all data]

Minas da Piedade, 1989
Minas da Piedade, M.E., , Ph.D. Thesis, Technical University, Lisbon, 1989. [all data]

Torres-Gómez, Barreiro-Rodríguez, et al., 1988
Torres-Gómez, Luis Alfonso; Barreiro-Rodríguez, Guadalupe; Méndez-Ruíz, Francisco, Vapour pressures and enthalpies of sublimation of ferrocene, cobaltocene and nickelocene, Thermochimica Acta, 1988, 124, 179-183, https://doi.org/10.1016/0040-6031(88)87020-5 . [all data]

Jacobs, Van Ekeren, et al., 1983
Jacobs, M.H.G.; Van Ekeren, P.J.; De Kruif, C.G., The vapour pressure and enthalpy of sublimation of ferrocene, The Journal of Chemical Thermodynamics, 1983, 15, 7, 619-623, https://doi.org/10.1016/0021-9614(83)90075-7 . [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Tel'noi, Kirynov, et al., 1975
Tel'noi, V.I.; Kirynov, K.V.; Ermolaev, V.I.; Rabinovich, I.B., Dokl. Akad. Nauk SSSR, 1975, 220, 1088. [all data]

Pelino, Tomassetti, et al., 1981
Pelino, M.; Tomassetti, M.; Piacente, V.; D'Ascenzo, G., Vapor pressure measurements of ferrocene, mono- and 1,1´-di-acetyl ferrocene, Thermochimica Acta, 1981, 44, 1, 89-99, https://doi.org/10.1016/0040-6031(81)80274-2 . [all data]

Calado, Dias, et al., 1980
Calado, J.C.G.; Dias, A.R.; Minas da Piedade, M.E.; Martinho Simoes, J.A., Standard enthalpy of sublimation of [Mo(η-C5H5)2(CH3)2].  A reevaluation of molybdenum-methyl and tungsten-methyl bond enthalpy contributions, Rev. Port. Quim., 1980, 22, 1-2, 53. [all data]

Murray, Cavell, et al., 1980
Murray, J.P.; Cavell, K.J.; Hill, J.O., A DSC study of benzoic acid: a suggested calibrant compound, Thermochimica Acta, 1980, 36, 1, 97-101, https://doi.org/10.1016/0040-6031(80)80114-6 . [all data]

Barkatin, Gaidym, et al., 1977
Barkatin, A.A.; Gaidym, I.L.; Baev, A.K., Khim. Khim. Technol. (USSR), 1977, 12, 44. [all data]

de Kruif and Oonk, 1973
de Kruif, C.G.; Oonk, H.A.J., The determination of enthalpies of sublimation by means of thermal conductivity manometers, Chemie Ing. Techn., 1973, 45, 7, 455-461, https://doi.org/10.1002/cite.330450705 . [all data]

Beech and Lintonbon, 1971
Beech, Graham; Lintonbon, Roger M., The measurement of sublimation enthalpies by differential scanning calorimetry, Thermochimica Acta, 1971, 2, 1, 86-88, https://doi.org/10.1016/0040-6031(71)85027-X . [all data]

Andrews and Westrum, 1969
Andrews, John T.S.; Westrum, Edgar F., Vapor pressure and third-law entropy of ferrocene, Journal of Organometallic Chemistry, 1969, 17, 2, 349-352, https://doi.org/10.1016/S0022-328X(00)88627-1 . [all data]

Edwards and Kington, 1962
Edwards, J.W.; Kington, G.L., Thermodynamic properties of ferrocene. Part 2.?Vapour pressure and latent heat of sublimation at 25«65533»C by the effusion and thermistor manometer methods, Trans. Faraday Soc., 1962, 58, 1323, https://doi.org/10.1039/tf9625801323 . [all data]

Edwards, Kington, et al., 1960
Edwards, J.W.; Kington, G.L.; Mason, R., The thermodynamic properties of ferrocene. Part 1.?The low-temperature transition in ferrocene crystals, Trans. Faraday Soc., 1960, 56, 660, https://doi.org/10.1039/tf9605600660 . [all data]

Cordes and Schreiner, 1959
Cordes, J.F.; Schreiner, S., Dampfdruckmessungen bei einigen Aromatenkomplexen, Z. Anorg. Allg. Chem., 1959, 299, 1-2, 87-91, https://doi.org/10.1002/zaac.19592990111 . [all data]

Kaplan, Kester, et al., 1952
Kaplan, Louis; Kester, William L.; Katz, Joseph J., Some Properties of Iron Biscyclopentadienyl, J. Am. Chem. Soc., 1952, 74, 21, 5531-5532, https://doi.org/10.1021/ja01141a518 . [all data]


Notes

Go To: Top, Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.), References