Tetraphosphorus hexaoxide


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to O6P4+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
9.5PEEgdell, Palmer, et al., 1980LLK
10.6 ± 0.5EIMuenow, Uy, et al., 1970RDSH
10.55PEEgdell, Palmer, et al., 1980Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
PO+18.0 ± 0.5?EIMuenow, Uy, et al., 1970RDSH
P2O+23.6 ± 0.5?EIMuenow, Uy, et al., 1970RDSH
PO2+23.0 ± 0.5?EIMuenow, Uy, et al., 1970RDSH
P2O2+18.8 ± 0.5?EIMuenow, Uy, et al., 1970RDSH
P2O3+17.5 ± 0.5?EIMuenow, Uy, et al., 1970RDSH
P3O3+18.8 ± 0.5?EIMuenow, Uy, et al., 1970RDSH
P3O4+16.1 ± 0.5?EIMuenow, Uy, et al., 1970RDSH
P3O5+15.0 ± 0.5?EIMuenow, Uy, et al., 1970RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Egdell, Palmer, et al., 1980
Egdell, R.G.; Palmer, M.H.; Findlay, R.H., Electronic structure of the group 5 oxides: Photoelectron spectra and ab initio molecular orbital calculations, Inorg. Chem., 1980, 19, 1314. [all data]

Muenow, Uy, et al., 1970
Muenow, D.W.; Uy, O.M.; Margrave, J.L., Mass spectrometric studies of the vaporization of phosphorus oxides, J. Inorg. Nucl. Chem., 1970, 32, 3459. [all data]


Notes

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