(CH3)2Zn+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 32220 T gas 633 635 Grieman, Fujikawa, et al., 1996

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 16440 gas A-X 594 669 Bancroft, Creber, et al., 1977
Grieman, Fujikawa, et al., 1996

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

CH3 s-deform. 1086 gas EF Grieman, Fujikawa, et al., 1996

Additional references: Jacox, 1998, page 357

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Grieman, Fujikawa, et al., 1996
Grieman, F.J.; Fujikawa, E.S.; Phillips, J.C., Discovery and Analysis of an Electronic Spectrum of the Dimethylzinc Cation Produced in a Free-Jet Expansion, J. Phys. Chem., 1996, 100, 22, 9276, https://doi.org/10.1021/jp9600118 . [all data]

Bancroft, Creber, et al., 1977
Bancroft, G.M.; Creber, D.K.; Ratner, M.A.; Moskowitz, J.W.; Topiol, S., Valence band and Zn 3d energy levels in Me2Zn from photoelectron spectra and pseudopotential ab initio calculations: electric field gradients in gas phase Zn compounds, Chem. Phys. Lett., 1977, 50, 2, 233, https://doi.org/10.1016/0009-2614(77)80170-X . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]


Notes

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