Mevalonolactone, TMS derivative
- Formula: C9H18O3Si
- Molecular weight: 202.3229
- IUPAC Standard InChI: InChI=1S/C9H18O3Si/c1-9(12-13(2,3)4)5-6-11-8(10)7-9/h5-7H2,1-4H3
- IUPAC Standard InChIKey: CNPIMSSHNMVFPM-UHFFFAOYSA-N
- CAS Registry Number: 102146-02-1
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Mevalonic lactone, trimethylsilyl deriv.; Mevalonic lactone, trimethylsilyl; Mevalonic acid, lactone, TMS; Mevalonolactone, monoTMS; Mevalonic acid, lactone, TMS ether; Mevalonic acid, lactone, trimethylsilyl ether; Mevalonic acid, mono-TMS; Mevalonic lactone, O-TMS; MEVALONOLACTONE TMS
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Options:
Van Den Dool and Kratz RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
| Column type | Capillary | Capillary | Capillary |
|---|---|---|---|
| Active phase | CP Sil 5 CB | DB-5 | SE-52 |
| Column length (m) | 25. | 30. | 25. |
| Carrier gas | He | He | |
| Substrate | |||
| Column diameter (mm) | 0.15 | 0.25 | 0.32 |
| Phase thickness (μm) | 0.12 | 1. | 0.52 |
| Tstart (C) | 90. | 100. | 70. |
| Tend (C) | 270. | 290. | 270. |
| Heat rate (K/min) | 10. | 4. | 5. |
| Initial hold (min) | 1. | 4. | |
| Final hold (min) | 7. | 10. | |
| I | 1360. | 1393. | 1380. |
| Reference | Halket, Przyborowska, et al., 1999 | Kimura, Yamamoto, et al., 1999 | Lefevere, Verhaeghe, et al., 1989 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Halket, Przyborowska, et al., 1999
Halket, J.N.; Przyborowska, A.; Stein, S.E.; Mallard, W.G.; Down, S.; Chalmers, R.,
Deconvolution gas chromatography / mass spectrometry of urinary organic acids - potential for pattern recognition and automated identification of metabolic disorders,
Rapid Commun. Mass spectrom., 1999, 13, 4, 279-284, https://doi.org/10.1002/(SICI)1097-0231(19990228)13:4<279::AID-RCM478>3.0.CO;2-I
. [all data]
Kimura, Yamamoto, et al., 1999
Kimura, M.; Yamamoto, T.; Yamaguchi, S.,
Automated metabolic profiling and interpretation of GC/MS data for organic acidemia screening: a personal computer-based system,
Tohoku J. Exp. Med., 1999, 188, 4, 317-334, https://doi.org/10.1620/tjem.188.317
. [all data]
Lefevere, Verhaeghe, et al., 1989
Lefevere, M.F.; Verhaeghe, B.J.; Declerck, D.H.; Van Bocxlaer, J.F.; De Leenheer, A.P.; De Sagher, R.M.,
Metabolic Profiling of Urinary Organic Acids by Single and Multicolumn Capillary Gas Chromatography,
J. Chromatogr. Sci., 1989, 27, 1, 23-29, https://doi.org/10.1093/chromsci/27.1.23
. [all data]
Notes
Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.