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Dicobalt octacarbonyl


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.3 ± 0.1EIBidinosti and McIntyre, 1970RDSH
8.12 ± 0.22EIWinters and Kiser, 1965RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CoCO+14.4 ± 0.5?EIWinters and Kiser, 1965RDSH
Co2CO+16.7 ± 0.37COEIWinters and Kiser, 1965RDSH
CoC2O2+12.7 ± 0.4?EIWinters and Kiser, 1965RDSH
Co2C2O2+14.7 ± 0.56COEIWinters and Kiser, 1965RDSH
CoC3O3+10.9 ± 0.3?EIWinters and Kiser, 1965RDSH
CoC4O4+8.8 ± 0.1?EIBidinosti and McIntyre, 1967RDSH
Co2C4O4+12.2 ± 0.34COEIWinters and Kiser, 1965RDSH
Co2C5O5+10.1 ± 0.43COEIWinters and Kiser, 1965RDSH
Co2C6O6+9.4 ± 0.32COEIWinters and Kiser, 1965RDSH
Co2C7O7+8.6 ± 0.3COEIWinters and Kiser, 1965RDSH
Co+16.9 ± 0.4?EIWinters and Kiser, 1965RDSH
Co2+17.8 ± 0.48COEIWinters and Kiser, 1965RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bidinosti and McIntyre, 1970
Bidinosti, D.R.; McIntyre, N.S., Mass spectrometric study of the thermal decomposition of dimanganese decacarbonyl and dicobalt octacarbonyl, Can. J. Chem., 1970, 48, 593. [all data]

Winters and Kiser, 1965
Winters, R.E.; Kiser, R.W., Ions produced by electron impact with the dimetallic carbonyls of cobalt and manganese, J. Phys. Chem., 1965, 69, 1618. [all data]

Bidinosti and McIntyre, 1967
Bidinosti, D.R.; McIntyre, N.S., The metal-metal bond dissociation energy in cobalt octacarbonyl, Chem. Commun., 1967, 1. [all data]


Notes

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