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Diphenyl carbonate

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-311. ± 8.8kJ/molCcbCarson, Fine, et al., 1971Hfusion=5.6±0.3

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid-401.4 ± 1.9kJ/molCcbSinke, Hildenbrand, et al., 1958ALS
Quantity Value Units Method Reference Comment
Deltacsolid-6143.6 ± 1.9kJ/molCcbSinke, Hildenbrand, et al., 1958Corresponding «DELTA»fsolid = -401.2 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar278.40J/mol*KN/ASinke, Hildenbrand, et al., 1958DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
263.13298.15Sinke, Hildenbrand, et al., 1958T = 15 to 310 K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Carson, Fine, et al., 1971
Carson, A.S.; Fine, D.H.; Gray, P.; Laye, P.G., Standard enthalpies of formation of diphenyl oxalate and benzoic anhydride and some related bond dissociation energies, J. Chem. Soc. B, 1971, 1611-1615. [all data]

Sinke, Hildenbrand, et al., 1958
Sinke, G.C.; Hildenbrand, D.L.; McDonald, R.A.; Kramer, W.R.; Stull, D.R., The heat, entropy and free energy of formation of diphenyl carbonate, J. Phys. Chem., 1958, 62, 1461-1462. [all data]


Notes

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