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Diphenyl ether

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltacliquid-6113.7 ± 3.8kJ/molCcbCass, Fletcher, et al., 1958Reanalyzed by Cox and Pilcher, 1970, Original value = -6113. ± 4. kJ/mol; Corresponding «DELTA»fliquid = -37.6 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
Deltafsolid-32.11 ± 0.93kJ/molCcbFurukawa, Ginnings, et al., 1951ALS
Quantity Value Units Method Reference Comment
Deltacsolid-6119.24 ± 0.88kJ/molCcbFurukawa, Ginnings, et al., 1951Corresponding «DELTA»fsolid = -32.03 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar233.91J/mol*KN/AFurukawa, Ginnings, et al., 1951DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
216.56298.15Ginnings and Furukawa, 1953T = 14 to 570 K.; DH
216.56298.15Furukawa, Ginnings, et al., 1951T = 18 to 570 K.; DH
215.9298.5Smith and Andrews, 1931T = 102 to 298 K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cass, Fletcher, et al., 1958
Cass, R.C.; Fletcher, S.E.; Mortimer, C.T.; Springall, H.D.; White, T.R., Heats of combustion and molecular structure. Part V. The mean bond energy term for the C-O bond in ethers, and the structures of some cyclic ethers, J. Chem. Soc., 1958, 1406-1410. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Furukawa, Ginnings, et al., 1951
Furukawa, G.T.; Ginnings, D.C.; McCoskey, R.E.; Nelson, R.A., Calorimetric properties of diphenyl ether from 0° to 570°K, J. Res. NBS, 1951, 46, 195-206. [all data]

Ginnings and Furukawa, 1953
Ginnings, D.C.; Furukawa, G.T., Heat capacity standards for the range 14 to 1200°K, J. Am. Chem. Soc., 1953, 75, 522-527. [all data]

Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H., Thermal energy studies. II. Phenyl derivatives of metals, J. Am. Chem. Soc., 1931, 53, 3661-3667. [all data]


Notes

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