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lanthanum chloride, anhydrous


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Clustering reactions

Chlorine anion + Cl3La = (Chlorine anion bullet Cl3La)

By formula: Cl- + Cl3La = (Cl- bullet Cl3La)

Quantity Value Units Method Reference Comment
Deltar332. ± 17.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B

(Chlorine anion bullet Cl3La) + Cl3La = (Chlorine anion bullet 2Cl3La)

By formula: (Cl- bullet Cl3La) + Cl3La = (Cl- bullet 2Cl3La)

Quantity Value Units Method Reference Comment
Deltar136. ± 15.kJ/molMSButman, Kudin, et al., 1987gas phase; Knudsen cell; M

Cl4La- + Cl3La = Cl7La2-

By formula: Cl4La- + Cl3La = Cl7La2-

Quantity Value Units Method Reference Comment
Deltar239. ± 41.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B
Deltar194. ± 34.kJ/molTDAsButman, Kudin, et al., 1987gas phase; value altered from reference due to conversion from electron convention to ion convention; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E., The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions, Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X . [all data]

Butman, Kudin, et al., 1987
Butman, M.F.; Kudin, L.S.; Burdukovskaya, G.G.; Krasnov, K.S.; Bozhko, N.V., Mass Spectrometric Determination of the Enthalpy of Formation of the Gaseous Ions LaCl4- and La2Cl7-, Russ. J. Phys. Chem., 1987, 61, 1518. [all data]


Notes

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