Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Benzenemethanethiol

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas22.26 ± 0.27kcal/molCcrGood, 1972 
Deltafgas20.96 ± 0.48kcal/molCcrMackle and McClean, 1962Reanalyzed by Cox and Pilcher, 1970, Original value = 21.9 ± 0.6 kcal/mol

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafliquid8.73 ± 0.26kcal/molCcrGood, 1972 
Deltafliquid10.50 ± 0.50kcal/molCcrMackle and McClean, 1962Reanalyzed by Cox and Pilcher, 1970, Original value = 9.55 ± 0.48 kcal/mol
Quantity Value Units Method Reference Comment
Deltacliquid-1084.23 ± 0.24kcal/molCcrGood, 1972Reanalyzed by Pedley, Naylor, et al., 1986, Original value = -1084.12 ± 0.24 kcal/mol
Deltacliquid-1086.07 ± 0.48kcal/molCcrMackle and McClean, 1962Reanalyzed by Cox and Pilcher, 1970, Original value = -1083.95 ± 0.48 kcal/mol

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Good, 1972
Good, W.D., Enthalpies of combustion of 18 organic sulfur compounds related to petroleum, J. Chem. Eng. Data, 1972, 17, 158-162. [all data]

Mackle and McClean, 1962
Mackle, H.; McClean, R.T.B., Studies in the thermochemistry of organic sulphides. Part 4.-Heat of formation of the mercaptyl radical, Trans. Faraday Soc., 1962, 58, 895-899. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Pedley, Naylor, et al., 1986
Pedley, J.B.; Naylor, R.D.; Kirby, S.P., Thermochemical Data of Organic Compounds, Chapman and Hall, New York, 1986, 1-792. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References