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vanadium tetrafluoride


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Fluorine anion + vanadium tetrafluoride = (Fluorine anion bullet vanadium tetrafluoride)

By formula: F- + vanadium tetrafluoride = (F- bullet vanadium tetrafluoride)

Quantity Value Units Method Reference Comment
Deltar365. ± 24.kJ/molTDEqKuznetsov, Korobov, et al., 1989gas phase; Fluoride Affinity: 14.2±3.9 kcal/mol < UF4
Deltar363. ± 27.kJ/molTDEqSidorov, Boltalina, et al., 1989gas phase; value altered from reference due to conversion from electron convention to ion convention

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kuznetsov, Korobov, et al., 1989
Kuznetsov, S.V.; Korobov, M.V.; Sidorov, L.N., Gas-Phase Negative Ion Chemistry of Platinum Metal Fluorides. III. Negative Ions of Pentafluorides., Int. J. Mass Spectrom. Ion Proc., 1989, 91, 3, 283, https://doi.org/10.1016/0168-1176(89)80083-7 . [all data]

Sidorov, Boltalina, et al., 1989
Sidorov, L.N.; Boltalina, O.V.; Borschevskii, A.Ya., Electron Affinities of Vanadium Fluorides. Additional Experimental Data and Corrections., Int. J. Mass Spectrom. Ion Proc., 1989, 87, 2, R1, https://doi.org/10.1016/0168-1176(89)80025-4 . [all data]


Notes

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