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vanadium trifluoride


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Fluorine anion + vanadium trifluoride = (Fluorine anion bullet vanadium trifluoride)

By formula: F- + F3V = (F- bullet F3V)

Quantity Value Units Method Reference Comment
Deltar429. ± 18.kJ/molTDAsBoltalina, Borshchevskii, et al., 1992gas phase; Critical review; value altered from reference due to conversion from electron convention to ion convention
Deltar422. ± 28.kJ/molTDEqSidorov, Boltalina, et al., 1989gas phase; Fluoride Affinity: 16.0±2.4 kcal/mol > CrF2; value altered from reference due to conversion from electron convention to ion convention

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Boltalina, Borshchevskii, et al., 1992
Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N., Thermochemistry of 3d Elements Fluorides and Their Negative Ions in Gas Phase, Russ. J. Phys. Chem., 1992, 66, 1223. [all data]

Sidorov, Boltalina, et al., 1989
Sidorov, L.N.; Boltalina, O.V.; Borschevskii, A.Ya., Electron Affinities of Vanadium Fluorides. Additional Experimental Data and Corrections., Int. J. Mass Spectrom. Ion Proc., 1989, 87, 2, R1, https://doi.org/10.1016/0168-1176(89)80025-4 . [all data]


Notes

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