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vanadium trifluoride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

View reactions leading to F3V+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
2.10 ± 0.30TDEqSidorov, Boltalina, et al., 1989VF3- + CrF4- <=> CrF3- + VF4-, «DELTA»H=-27.0±0.1 kcal/mol
1.60 ± 0.40EIAEFlesch and Svec, 1975From VOF3

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sidorov, Boltalina, et al., 1989
Sidorov, L.N.; Boltalina, O.V.; Borschevskii, A.Ya., Electron Affinities of Vanadium Fluorides. Additional Experimental Data and Corrections., Int. J. Mass Spectrom. Ion Proc., 1989, 87, 2, R1, https://doi.org/10.1016/0168-1176(89)80025-4 . [all data]

Flesch and Svec, 1975
Flesch, G.D.; Svec, H.J., Thermochemistry of vanadium oxytrichloride and vanadium oxytrifluoride by mass spectrometry, Inorg. Chem., 1975, 14, 1817. [all data]


Notes

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