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terbium (III) chloride hexahydrate

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Chlorine anion + Cl3Tb = Cl4Tb-

By formula: Cl- + Cl3Tb = Cl4Tb-

Quantity Value Units Method Reference Comment
Deltar353. ± 18.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention
Deltar304. ± 6.7kJ/molTDEqKhasanshin, Kudin, et al., 1999gas phase; value altered from reference due to conversion from electron convention to ion convention

TbCl4- + Cl3Tb = Cl7Tb2-

By formula: TbCl4- + Cl3Tb = Cl7Tb2-

Quantity Value Units Method Reference Comment
Deltar242. ± 38.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention
Deltar374. ± 10.kJ/molTDEqKhasanshin, Kudin, et al., 1999gas phase; value altered from reference due to conversion from electron convention to ion convention

TbCl4- + 2Cl3Tb = Cl10Tb3-

By formula: TbCl4- + 2Cl3Tb = Cl10Tb3-

Quantity Value Units Method Reference Comment
Deltar390. ± 9.6kJ/molTDEqKhasanshin, Kudin, et al., 1999gas phase; value altered from reference due to conversion from electron convention to ion convention

TbCl4- + 3Cl3Tb = Cl13Tb4-

By formula: TbCl4- + 3Cl3Tb = Cl13Tb4-

Quantity Value Units Method Reference Comment
Deltar320. ± 84.kJ/molTDEqKhasanshin, Kudin, et al., 1999gas phase; value altered from reference due to conversion from electron convention to ion convention

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E., The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions, Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X . [all data]

Khasanshin, Kudin, et al., 1999
Khasanshin, I.V.; Kudin, L.S.; Pogrebnoi, A.M., A mass spectrometric study of saturated vapor over terbium trichloride and the TbCl3-DyCl3 system, Russ. J. Phys. Chem., 1999, 73, 849-855. [all data]


Notes

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