Styrene
- Formula: C8H8
- Molecular weight: 104.1491
- IUPAC Standard InChIKey: PPBRXRYQALVLMV-UHFFFAOYSA-N
- CAS Registry Number: 100-42-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Benzene, ethenyl-; Bulstren K-525-19; Cinnamene; Phenethylene; Phenylethene; Phenylethylene; Styrol (German); Styrole; Styrolene; Styropol SO; Vinylbenzene; Vinylbenzol; Ethenylbenzene; Cinnaminol; Cinnamol; Styrol; Benzene, vinyl-; Cinnamenol; Ethylene, phenyl-; NCI-C02200; Stirolo; Styreen; Styren; Styrene monomer; Vinylbenzen; Annamene; NSC 62785; ethenylbenzene (styrene); Vinylbenzene (styrene)
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Kovats' RI, non-polar column, isothermal
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-101 | HP-1 | HP-1 | HP-1 | HP-1 |
Column length (m) | 50. | 25. | 25. | 25. | 25. |
Carrier gas | H2 | N2 | N2 | N2 | N2 |
Substrate | |||||
Column diameter (mm) | 0.2 | 0.20 | 0.20 | 0.20 | 0.20 |
Phase thickness (μm) | 0.2 | ||||
Temperature (C) | 60. | 60. | 60. | 100. | 100. |
I | 874.35 | 873. | 873. | 885. | 885. |
Reference | Garay, 2000 | Zhang, Li, et al., 1992 | Zhang, Li, et al., 1992 | Zhang, Li, et al., 1992 | Zhang, Li, et al., 1992 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | OV-101 | OV-101 | OV-101 | OV-101 | OV-101 |
Column length (m) | 50. | 85. | 85. | 85. | 85. |
Carrier gas | N2 | N2 | N2 | N2 | |
Substrate | |||||
Column diameter (mm) | 0.30 | 0.28 | 0.28 | 0.28 | 0.28 |
Phase thickness (μm) | |||||
Temperature (C) | 100. | 100. | 100. | 100. | 110. |
I | 885. | 884. | 885. | 884. | 885. |
Reference | Engewald, Topalova, et al., 1987 | Boneva, Papazova, et al., 1983 | Boneva, Papazova, et al., 1983 | Boneva, Papazova, et al., 1983 | Boneva, Papazova, et al., 1983 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Packed |
---|---|---|---|---|---|
Active phase | OV-101 | Squalane | Squalane | SE-30 | SE-30 |
Column length (m) | 85. | 100. | 100. | 15. | 2. |
Carrier gas | N2 | He | He | N2 | |
Substrate | Gaschrom Q | ||||
Column diameter (mm) | 0.28 | 0.25 | |||
Phase thickness (μm) | |||||
Temperature (C) | 90. | 106. | 96. | 70. | 100. |
I | 880. | 875. | 872. | 877.8 | 886. |
Reference | Boneva, Papazova, et al., 1983 | Kugucheva and Mashinsky, 1983 | Kugucheva and Mashinsky, 1983 | Tóth, 1983 | Winskowski, 1983 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | SE-30 | SE-30 | Squalane | Squalane | OV-101 |
Column length (m) | 100. | 100. | 50. | 50. | 50. |
Carrier gas | N2 | N2 | N2 | ||
Substrate | |||||
Column diameter (mm) | 0.5 | 0.5 | 0.25 | 0.25 | 0.3 |
Phase thickness (μm) | |||||
Temperature (C) | 130. | 80. | 86. | 96. | 100. |
I | 893. | 880. | 872. | 874.5 | 885.0 |
Reference | Bredael, 1982 | Bredael, 1982 | Macák, Nabivach, et al., 1982 | Macák, Nabivach, et al., 1982 | Gerasimenko, Kirilenko, et al., 1981 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Packed | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | OV-101 | OV-101 | Squalane | Squalane | Squalane |
Column length (m) | 50. | 50. | 1. | 100. | 50. |
Carrier gas | N2 | N2 | He | ||
Substrate | Chromaton N-AW-HMDS | ||||
Column diameter (mm) | 0.3 | 0.3 | 0.25 | 0.25 | |
Phase thickness (μm) | |||||
Temperature (C) | 120. | 140. | 100. | 50. | 86. |
I | 890.5 | 897.3 | 875. | 860.9 | 872.0 |
Reference | Gerasimenko, Kirilenko, et al., 1981 | Gerasimenko, Kirilenko, et al., 1981 | Nabivach and Kirilenko, 1980 | Bajus, Veselý, et al., 1979 | Nabivach, Bur'yan, et al., 1978 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Packed | Packed | Packed | Capillary |
---|---|---|---|---|---|
Active phase | Squalane | Squalane | Squalane | Squalane | OV-101 |
Column length (m) | 50. | 2. | 2. | 2. | 20. |
Carrier gas | N2 | N2 | N2 | ||
Substrate | Chromosorb G | Chromosorb G | Chromosorb G | ||
Column diameter (mm) | 0.25 | ||||
Phase thickness (μm) | |||||
Temperature (C) | 96. | 100. | 100. | 100. | 60. |
I | 874.5 | 915. | 916. | 916. | 873. |
Reference | Nabivach, Bur'yan, et al., 1978 | Evans and Newton, 1976 | Evans and Newton, 1976 | Evans and Newton, 1976 | Blazsó and Garzó, 1974 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | SE-30 | SE-30 | SE-30 | SE-30 | SE-30 |
Column length (m) | 25.5 | 25.5 | 25.5 | 25.5 | 25.5 |
Carrier gas | He | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
Phase thickness (μm) | |||||
Temperature (C) | 65. | 65. | 65. | 65. | 65. |
I | 874.4 | 874.4 | 874.4 | 874.7 | 874.7 |
Reference | Svob, Deur-Siftar, et al., 1974 | Svob, Deur-Siftar, et al., 1974 | Svob, Deur-Siftar, et al., 1974 | Svob, Deur-Siftar, et al., 1974 | Svob, Deur-Siftar, et al., 1974 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Packed | Packed | Packed | Packed |
---|---|---|---|---|---|
Active phase | SE-30 | SE-30 | Squalane | Squalane | Squalane |
Column length (m) | 25.5 | 6.1 | 3.0 | 15. | 15. |
Carrier gas | He | N2 | N2 | He | He |
Substrate | Chromosorb W | Embacel | Chromosorb P | Chromosorb P | |
Column diameter (mm) | 0.5 | 0.25 | 0.25 | ||
Phase thickness (μm) | |||||
Temperature (C) | 65. | 75. | 100. | 49. | 67. |
I | 874.9 | 878. | 876. | 863. | 869. |
Reference | Svob and Deur-Siftar, 1974 | Robinson and Odell, 1971 | Robinson and Odell, 1971 | Hively and Hinton, 1968 | Hively and Hinton, 1968 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Packed | Packed | Packed | Packed | Capillary |
---|---|---|---|---|---|
Active phase | Squalane | DC-200 | Squalane | Apiezon L | Squalane |
Column length (m) | 15. | 4. | 5. | 5. | |
Carrier gas | He | ||||
Substrate | Chromosorb P | ||||
Column diameter (mm) | 0.25 | ||||
Phase thickness (μm) | |||||
Temperature (C) | 86. | 100. | 100. | 100. | 70. |
I | 874. | 885. | 874. | 914. | 867. |
Reference | Hively and Hinton, 1968 | Rohrschneider, 1966 | Rohrschneider, 1966 | Rohrschneider, 1966 | Schomburg, 1966 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Kovats' RI, non-polar column, isothermal, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Garay, 2000
Garay, F.,
Application of a flow-tunable, serially coupled gas chromatographic capillary column system for the analysis of complex mixtures,
Chromatographia Sup., 2000, 51, 1, s108-s120, https://doi.org/10.1007/BF02492792
. [all data]
Zhang, Li, et al., 1992
Zhang, M.J.; Li, S.D.; Chen, B.J.,
Compositional studies of high-temperature coal tar by GC/FTIR analysis of light oil fractions,
Chromatographia, 1992, 33, 3/4, 138-146, https://doi.org/10.1007/BF02275894
. [all data]
Engewald, Topalova, et al., 1987
Engewald, W.; Topalova, I.; Petsev, N.; Dimitrov, Chr.,
Structure-Retention Correlations of Hydrocarbons in GLC and GSC. Alkenylbenzenes,
Chromatographia, 1987, 23, 8, 561-565, https://doi.org/10.1007/BF02324864
. [all data]
Boneva, Papazova, et al., 1983
Boneva, St.; Papazova, D.; Dimov, N.,
Retention Indices of aromatic hydrocarbons on glass and metal capillary columns with stationary phase OV-101,
Jahrb. Chem. Tech. Hochschule Burgas, 1983, 18, 143-148. [all data]
Kugucheva and Mashinsky, 1983
Kugucheva, E.E.; Mashinsky, V.I.,
Retention Indices of Aromatic Hydrocarbons on Capillary Columns with Squalan and Polyphenyl Ether,
Zh. Anal. Khim. (Rus), 1983, 38, 11, 2023-2026. [all data]
Tóth, 1983
Tóth, T.,
Use of capillary gas chromatography in collecting retention and chemical information for the analysis of complex petrochemical mixtures,
J. Chromatogr., 1983, 279, 157-165, https://doi.org/10.1016/S0021-9673(01)93614-3
. [all data]
Winskowski, 1983
Winskowski, J.,
Gaschromatographische Identifizierung von Stoffen anhand von Indexziffem und unterschiedlichen Detektoren,
Chromatographia, 1983, 17, 3, 160-165, https://doi.org/10.1007/BF02271041
. [all data]
Bredael, 1982
Bredael, P.,
Retention indices of hydrocarbons on SE-30,
J. Hi. Res. Chromatogr. Chromatogr. Comm., 1982, 5, 6, 325-328, https://doi.org/10.1002/jhrc.1240050610
. [all data]
Macák, Nabivach, et al., 1982
Macák, J.; Nabivach, V.; Buryan, P.; Sindler, S.,
Dependence of retention indices of alkylbenzenes on their molecular structure,
J. Chromatogr., 1982, 234, 2, 285-302, https://doi.org/10.1016/S0021-9673(00)81867-1
. [all data]
Gerasimenko, Kirilenko, et al., 1981
Gerasimenko, V.A.; Kirilenko, A.V.; Nabivach, V.M.,
Capillary gas chromatography of aromatic compounds found in coal tar fractions,
J. Chromatogr., 1981, 208, 1, 9-16, https://doi.org/10.1016/S0021-9673(00)87953-4
. [all data]
Nabivach and Kirilenko, 1980
Nabivach, V.M.; Kirilenko, A.V.,
Relationship between the gas chromatographic behaviour and the molecular structure of hydrocarbon samples and various stationary phases. Part II. Correlation between the retention index, physicochemical properties and molecular structure,
Chromatographia, 1980, 13, 2, 93-100, https://doi.org/10.1007/BF02263060
. [all data]
Bajus, Veselý, et al., 1979
Bajus, M.; Veselý, V.; Leclercq, P.A.; Rijks, J.A.,
Steam cracking of hydrocarbons. 2. Pyrolysis of methylcyclohexane,
Ind. Eng. Chem. Prod. Res. Dev., 1979, 18, 2, 135-142, https://doi.org/10.1021/i360070a012
. [all data]
Nabivach, Bur'yan, et al., 1978
Nabivach, V.M.; Bur'yan, P.; Matsak, I.,
Retention indices of aromatic hydrocarbons on a squalane capillary column,
Zh. Anal. Khim., 1978, 33, 7, 1108-1113. [all data]
Evans and Newton, 1976
Evans, M.B.; Newton, R.,
Inverse gas chromatography in the study of polymer degradation. Part I. Oxidation of squalene as a model for the oxidative degradation of natural rubber,
Chromatographia, 1976, 9, 11, 561-566, https://doi.org/10.1007/BF02275963
. [all data]
Blazsó and Garzó, 1974
Blazsó, M.; Garzó, G.,
Identification of Isomeric Structures of Phenyl and Trimethylsilyl Substituted 1-Alkenes by Gas Chromatography,
Chromatographia, 1974, 7, 8, 395-398, https://doi.org/10.1007/BF02330942
. [all data]
Svob, Deur-Siftar, et al., 1974
Svob, V.; Deur-Siftar, D.; Cramers, C.A.,
Mechanisms of the thermal degradation of alkylbenzenes,
J. Chromatogr., 1974, 91, 659-675, https://doi.org/10.1016/S0021-9673(01)97946-4
. [all data]
Svob and Deur-Siftar, 1974
Svob, V.; Deur-Siftar, D.,
Kovats Retention Indices in the Identification of Alkylbenzene Degradation Products,
J. Chromatogr., 1974, 91, 677-689, https://doi.org/10.1016/S0021-9673(01)97947-6
. [all data]
Robinson and Odell, 1971
Robinson, P.G.; Odell, A.L.,
A system of standard retention indices and its uses. The characterisation of stationary phases and the prediction of retention indices,
J. Chromatogr., 1971, 57, 1-10, https://doi.org/10.1016/0021-9673(71)80001-8
. [all data]
Hively and Hinton, 1968
Hively, R.A.; Hinton, R.E.,
Variation of the retention index with temperature on squalane substrates,
J. Gas Chromatogr., 1968, 6, 4, 203-217, https://doi.org/10.1093/chromsci/6.4.203
. [all data]
Rohrschneider, 1966
Rohrschneider, L.,
Eine methode zur charakterisierung von gaschromatographischen trennflüssigkeiten,
J. Chromatogr., 1966, 22, 6-22, https://doi.org/10.1016/S0021-9673(01)97064-5
. [all data]
Schomburg, 1966
Schomburg, G.,
Gaschromatographische Retentionsdaten und struktur chemischer verbindungen. III. Alkylverzweigte und ungesättigte cyclische Kohlenwasserstoffe,
J. Chromatogr., 1966, 23, 18-41, https://doi.org/10.1016/S0021-9673(01)98653-4
. [all data]
Notes
Go To: Top, Kovats' RI, non-polar column, isothermal, References
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