Styrene
- Formula: C8H8
- Molecular weight: 104.1491
- IUPAC Standard InChIKey: PPBRXRYQALVLMV-UHFFFAOYSA-N
- CAS Registry Number: 100-42-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Benzene, ethenyl-; Bulstren K-525-19; Cinnamene; Phenethylene; Phenylethene; Phenylethylene; Styrol (German); Styrole; Styrolene; Styropol SO; Vinylbenzene; Vinylbenzol; Ethenylbenzene; Cinnaminol; Cinnamol; Styrol; Benzene, vinyl-; Cinnamenol; Ethylene, phenyl-; NCI-C02200; Stirolo; Styreen; Styren; Styrene monomer; Vinylbenzen; Annamene; NSC 62785; ethenylbenzene (styrene); Vinylbenzene (styrene)
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Normal alkane RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | Polydimethyl siloxane: CP-Sil 5 CB | VF-5 MS | VF-5 MS | HP-5 | Ultra-ALLOY-5 |
Column length (m) | 60. | 60. | 60. | 60. | 30. |
Carrier gas | Helium | Helium | Helium | Helium | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.32 | 0.32 | 0.25 | 0.25 |
Phase thickness (μm) | 1.0 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 45. | 30. | 30. | 35. | 40. |
Tend (C) | 210. | 260. | 260. | 220. | 320. |
Heat rate (K/min) | 3.6 | 2. | 2. | 10. | 20. |
Initial hold (min) | 1.45 | 1. | 2. | ||
Final hold (min) | 2.72 | 28. | 28. | 15. | 13. |
I | 878. | 890. | 892. | 893. | 896. |
Reference | Bramston-Cook, 2013 | Leffingwell and Alford, 2011 | Leffingwell and Alford, 2011 | Piyachaiseth, Jirapakkul, et al., 2011 | Tsuge, Ohtan, et al., 2011 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | ZB-5 | RTX-5 MS | VF-5MS | HP-1 | HP-1 |
Column length (m) | 30. | 30. | 30. | 50. | 50. |
Carrier gas | Helium | Helium | He | He | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.2 | 0.2 |
Phase thickness (μm) | 0.25 | 0.50 | 0.25 | 0.33 | 0.33 |
Tstart (C) | 40. | 35. | 40. | 60. | 60. |
Tend (C) | 280. | 225. | 250. | 250. | 250. |
Heat rate (K/min) | 6. | 6. | 7. | 2. | 2. |
Initial hold (min) | 1. | 5. | 4. | 4. | |
Final hold (min) | 9. | 10. | 30. | 30. | |
I | 893. | 895. | 890. | 877. | 871. |
Reference | Harrison and Priest, 2009 | Watcharananun, Cadwallader, et al., 2009 | Ghiasvand, Setkova, et al., 2007 | Castel, Fernandez, et al., 2006 | Castel, Fernandez, et al., 2006 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-1 | HP-1 | HP-1 | BPX-5 | HP-5 |
Column length (m) | 50. | 50. | 50. | 25. | 30. |
Carrier gas | He | He | He | Helium | |
Substrate | |||||
Column diameter (mm) | 0.2 | 0.2 | 0.2 | 0.20 | 0.25 |
Phase thickness (μm) | 0.33 | 0.5 | 0.33 | 0.13 | 0.25 |
Tstart (C) | 60. | 60. | 60. | 50. | 40. |
Tend (C) | 250. | 250. | 250. | 230. | 220. |
Heat rate (K/min) | 2. | 2. | 2. | 3. | 4. |
Initial hold (min) | 4. | 4. | 2. | 5. | |
Final hold (min) | 30. | 120. | 30. | 10. | |
I | 878. | 872. | 872. | 887. | 874. |
Reference | Castel, Fernandez, et al., 2006 | Castel, Fernandez, et al., 2006, 2 | Castel, Fernandez, et al., 2006, 2 | Fons, Rapior, et al., 2006 | Jiménez, Aguilera, et al., 2006 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | Ultra-2 | FSOT-RSL-200 | HP-5 | HP-1 | HP-5 |
Column length (m) | 50. | 30. | 30. | 50. | 60. |
Carrier gas | He | Hydrogen | He | He | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.32 | 0.25 | 0.2 | 0.32 |
Phase thickness (μm) | 0.32 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 50. | 40. | 60. | 60. | 30. |
Tend (C) | 270. | 280. | 250. | 250. | 260. |
Heat rate (K/min) | 2. | 6. | 10. | 2. | 2. |
Initial hold (min) | 5. | 2. | 60. | 2. | |
Final hold (min) | 5. | 10. | 28. | ||
I | 895. | 897. | 895. | 878. | 891.4 |
Reference | Schlumpberger B.O., Clery R.A., et al., 2006 | Schmidt, Jirovetz, et al., 2006 | Wang, Yang, et al., 2006 | Fernandez, Lizzani-Cuvelier, et al., 2005 | Leffingwell and Alford, 2005 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | MDN-5 | SPB-5 | DB-5 | HP-1 | SPB-5 |
Column length (m) | 60. | 30. | 30. | 50. | 30. |
Carrier gas | He | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.2 | 0.32 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.5 | 0.25 |
Tstart (C) | 40. | 60. | 60. | 60. | 40. |
Tend (C) | 270. | 250. | 240. | 220. | 220. |
Heat rate (K/min) | 4. | 4. | 3. | 2. | 5. |
Initial hold (min) | 4. | 2. | 1. | ||
Final hold (min) | 5. | 20. | 45. | 20. | |
I | 893. | 880. | 889. | 876. | 895. |
Reference | van Loon, Linssen, et al., 2005 | Pino, Marbot, et al., 2005 | Tellez, Khan, et al., 2004 | Fernandez, Lizzani-Cuvelier, et al., 2003 | Ledauphin, Guichard, et al., 2003 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5 | SPB-1 | HP-5 | BP-1 | Methyl Silicone |
Column length (m) | 30. | 30. | 60. | 50. | 60. |
Carrier gas | H2 | He | He | He | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.32 | 0.22 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 1. | 0.75 | 0.25 |
Tstart (C) | 60. | 40. | 40. | 50. | 40. |
Tend (C) | 280. | 200. | 240. | 200. | 220. |
Heat rate (K/min) | 4. | 3. | 3. | 5. | 5. |
Initial hold (min) | 10. | 10. | 10. | ||
Final hold (min) | 40. | ||||
I | 891. | 870. | 897. | 881. | 873.29 |
Reference | Pino, Marbot, et al., 2003 | Vichi, Pizzale, et al., 2003 | García, Martín, et al., 2000 | Health Safety Executive, 2000 | Baraldi, Rapparini, et al., 1999 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5 | OV-1 | OV-1 | OV-101 | DB-5 |
Column length (m) | 30. | 50. | 60. | ||
Carrier gas | Helium | ||||
Substrate | |||||
Column diameter (mm) | 0.32 | 0.20 | 0.32 | ||
Phase thickness (μm) | 1. | 0.50 | 1. | ||
Tstart (C) | 40. | 50. | 50. | 30. | 40. |
Tend (C) | 200. | 160. | 160. | 100. | 200. |
Heat rate (K/min) | 3. | 2. | 2. | 1. | 3. |
Initial hold (min) | 5. | 6. | 5. | ||
Final hold (min) | 2. | ||||
I | 892. | 875. | 877. | 875. | 893. |
Reference | Meynier, Novelli, et al., 1999 | Orav, Kailas, et al., 1999 | Orav, Kailas, et al., 1999 | Orav, Kailas, et al., 1999, 2 | Kondjoyan, Viallon, et al., 1997 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5 | SPB-1 | HP-5 | SP-2100 | DB-1 |
Column length (m) | 60. | 50. | 30. | 30. | |
Carrier gas | He | He | He | ||
Substrate | |||||
Column diameter (mm) | 0.32 | 0.2 | 0.25 | 0.25 | |
Phase thickness (μm) | 1. | 0.33 | 0.25 | ||
Tstart (C) | 40. | 40. | 35. | 40. | 50. |
Tend (C) | 200. | 200. | 200. | 280. | 240. |
Heat rate (K/min) | 3. | 3. | 6. | 5. | 5. |
Initial hold (min) | 5. | 3. | 2. | 3. | 3. |
Final hold (min) | 2. | 30. | |||
I | 895. | 872. | 895. | 877. | 873. |
Reference | Kondjoyan, Viallon, et al., 1997 | Wong and Lai, 1996 | Larsen and Frisvad, 1995 | Fischer and Kusch, 1993 | Shiota, 1993 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-1 | OV-101 | DB-1 | DB-1 | DB-1 |
Column length (m) | 30. | 54. | 60. | 60. | 60. |
Carrier gas | He | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.26 | 0.32 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 1.2 | 0.25 | 0.25 | |
Tstart (C) | 50. | 50. | 30. | 50. | 50. |
Tend (C) | 240. | 230. | 240. | 240. | 240. |
Heat rate (K/min) | 5. | 3. | 3. | 3. | 3. |
Initial hold (min) | 3. | 10. | |||
Final hold (min) | |||||
I | 880. | 875. | 878. | 878. | 880. |
Reference | Shiota, 1993 | Zenkevich and Kulikova, 1993 | Ciccioli, Cecinato, et al., 1992 | Shiota, 1991 | Shiota, 1991 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | OV-101 | HP-5 | HP-5 | BP-1 | SE-30 |
Column length (m) | 54. | 50. | 50. | 25. | 50. |
Carrier gas | Helium | H2 | H2 | Nitrogen | He |
Substrate | |||||
Column diameter (mm) | 0.26 | 0.3 | 0.3 | 0.33 | 0.5 |
Phase thickness (μm) | 1.00 | ||||
Tstart (C) | 50. | 80. | 80. | 30. | 40. |
Tend (C) | 240. | 250. | 250. | 150. | 170. |
Heat rate (K/min) | 5. | 16. | 16. | 5. | 3. |
Initial hold (min) | 0. | 4. | 3. | ||
Final hold (min) | 0. | ||||
I | 883. | 874. | 893. | 866. | 869. |
Reference | Zenkevich and Ventura, 1991 | Spadone, Takeoka, et al., 1990 | Spadone, Takeoka, et al., 1990 | Wilkins and Scholl, 1989 | Heydanek and McGorrin, 1981 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bramston-Cook, 2013
Bramston-Cook, R.,
Kovats indices for C2-C13 hydrocarbons and selected oxygenated/halocarbons with 100 % dimethylpolysiloxane columns, 2013, retrieved from http://lotusinstruments.com/monographs/List .... [all data]
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Volatile constituents of the giant pufball mushroom (Calvatia gigantea),
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Composition of peaks used in the preparation of malt for Scotch Whisky production - influence of geographical source and extraction depth,
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Volatile constituents from the fruits of four Syzygium species grown in Malaysia,
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Shiota, H.,
New esteric components in the volatiles of banana fruit (Musa sapientum L.),
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Zenkevich, I.G.; Kulikova, S.N.,
GC-MS Analysis of Products of Reactions of Unsaturated Compounds with Dimethyl Disulfide for Determination of Position of Double Bonds C=C,
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Ciccioli, Cecinato, et al., 1992
Ciccioli, P.; Cecinato, A.; Brancaleoni, E.; Frattoni, M.; Liberti, A.,
Use of carbon adsorption traps combined with high resolution gas chromatography - mass spectrometry for the analysis of polar and non-polar C4-C14 hydrocarbons involved in photochemical smog formation,
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Shiota, 1991
Shiota, H.,
Volatile components of pawpaw fruit (Asimina triloba Dunal.),
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Zenkevich and Ventura, 1991
Zenkevich, I.G.; Ventura, K.,
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Notes
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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